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Carborane-Decorated Siloles with Highly Efficient Solid-State Emissions - What Drives the Photophysical Properties? [PDF]

Chemistry
Szathmári B, Hessz D, Zámbó D, Bruhn C, Pietschnig R, Udvardy A, Szabó P, Holczbauer T, Balogh MJ, Kelemen Z.   +9 more
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A Pd-catalyzed route to carborane-fused boron heterocycles. [PDF]

Chem Sci
Zhu M, Wang P, Wu Z, Zhong Y, Su L, Xin Y, Spokoyny AM, Zou C, Mu X.   +8 more
europepmc   +1 more source

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The Mechanochemistry of Carboranes

Angewandte Chemie International Edition, 2022
AbstractWe developed o‐carborane as a new mechanophore by showing that the o‐carborane cluster is the preferred scission site in chain‐centered polymers through ultrasonication mechanochemistry. Mechanistic studies are consistent with a predominately homolytic mechanism of chain scission.
Ye Sha, Zhou Zhou, Miao Zhu, Zhenyang Luo, Enhua Xu, Xiang Li, Hong Yan   +6 more
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CARBORANES AND METALLOCARBORANES*

Annals of the New York Academy of Sciences, 1974
Abstract : One of the most significant developments in modern boron chemistry was the discovery of the carboranes. The substitution of CH(3+) vertices for BH(2+) units in boron hydride polyhedra opened up an entire new field of chemical endeavor.
Kenneth P, Callahan, William J, Evans, M Frederick, Hawthorne   +2 more
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Carborane polymers. III. Vinyl carboranes

Journal of Polymer Science Part A: General Papers, 1965
AbstractIsopropenylcarborane could not be polymerized by conventional radical and ionic methods. A low molecular weight polymer of DP = 10 was obtained by the use of aluminum chloride as catalyst at 150–170°C. Carboranylmethyl acrylate was homopolymerized and copolymerized with fluoroacrylates by using benzoyl peroxide as catalyst.
Joseph Green, Nathan Mayes, Murray S. Cohen   +2 more
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Carborane

Zeitschrift für Chemie, 1966
AbstractDas Gebiet der Borwasserstoff‐ und Bororganoverbindungen ist nach den grundlegenden Arbeiten A. Stocks über Borwasserstoffe (1912 bis 1936) erst in jüngster Zeit vor allem aus zwei Gründen wieder in den Blickpunkt des Interesses gerückt. So waren es einmal die Suche nach energiereichen Raketentreibstoffen, wobei Borwasserstoff‐Verbindungen eine
Kurt Issleib, Rolf Lindner, Alfred Tzschach   +2 more
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Icosahedral carboranes. XIII. Halogenation of p-carborane

Inorganic Chemistry, 1969
Abstract : A method for the preparation and purification of substantial amounts of p-carborane is described. Chloro-, bromo- and iodo-p-carboranes were obtained via direct halogenation. The various halogenated species were separated by either column or vapor phase chromatography.
John Francis Sieckhaus, Nick S. Semenuk, Thomas A. Knowles, Hansjuergen Schroeder   +3 more
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Supraicosahedral (Metalla) Carboranes

ChemInform, 2004
AbstractFor Abstract see ChemInform Abstract in Full Text.
Alan S. F. Boyd, Anthony Burke, David Ellis, Daniel Ferrer, Barry T. Giles, Miguel A. Laguna, Ruaraidh McIntosh, Stuart A. MacGregor, Daniel L. Ormsby, Georgina M. Rosair, et al. et al.   +10 more
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Development of carborane synthons: synthesis and chemistry of (aminoalkyl)carboranes

Inorganic Chemistry, 1992
A number of (aminoalkyl)-1,2-closo-dodecaboranes have been synthesized to provide carboranes with a functional group for covalent incorporation into structures of potential use in the treatment of cancer by boron neutron capture therapy (BNCT). (Phthalimidoalkyl)acetylenes reacted with decaborane to give the corresponding carboranes; removal of the ...
J. Gerald Wilson, A. K. M. Anisuzzaman, F. Alam, A. H. Soloway   +3 more
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