Results 91 to 100 of about 3,726 (222)
Heterolytic H2 activation on a carbene-ligated rhodathiaborane promoted by isonido-nido cage opening [PDF]
, 2015 A new mechanism of H2 activation is reported to occur on a carbene-ligated rhodathiaborane that features metal-thiaborane bifunctional synergistic effects.
Artigas, María José +5 more
core +2 more sources
Dicarba-closo-dodecaborane(12) derivatives of phosphonium salts: easy formation of nido-carborane phosphonium zwitterions [PDF]
, 2007 The first examples of arylphosphonium salts containing a dicarba-closo-dodecaborane(12) (closo-carborane) are reported; in contrast to the 1,12-carborane derivative, the 1,2- and 1,7-isomers undergo a facile deboronation reaction in polar solvents to ...
Adams +41 more
core +1 more source
Фармакофорные соли органических кислот и аминов: синтез, структура, биологическая активность [PDF]
, 2013 АМИНЫФОСФИНЫСОЛИкислоты ...
Дикусар, Е. А. +4 more
core
Amphiphilic COSAN and I2-COSAN crossing synthetic lipid membranes: planar bilayers and liposomes [PDF]
, 2014 The boron-rich cobaltabisdicarbollide (COSAN) and its 8,80-I2 derivative (I2-COSAN), both of purely inorganic nature, are shown to cross through synthetic lipid membranes.
Aguilella, Vicente +7 more
core +2 more sources
Design of Carborane Molecular Architectures via Electronic Structure Computations
International Journal of Photoenergy, 2009 Quantum-mechanical electronic structure computations were employed to explore initial steps towards a comprehensive design of polycarborane architectures through assembly of molecular units.
Josep M. Oliva +4 more
doaj +1 more source
Exploiting the Electronic Tuneability of Carboranes as Supports for Frustrated Lewis Pairs
Molecules, 2018 The first example of a carborane with a catecholborolyl substituent, [1-Bcat-2-Ph-closo-1,2-C2B10H10] (1), has been prepared and characterized and shown to act as the Lewis acid component of an intermolecular frustrated Lewis pair in catalyzing a Michael
Amanda Benton +4 more
doaj +1 more source
Beilstein Journal of Organic Chemistry, 2009 The effect of the phenyl–alkyl connecting group on mesogenic properties of several series of isostructural compounds containing p-carborane (A and B), bicyclo[2.2.2]octane (C), and benzene (D) was investigated using thermal and optical methods.
Aleksandra Jankowiak +6 more
doaj +1 more source
Boron-Based (Nano-)Materials: Fundamentals and Applications
Crystals, 2016 The boron (Z = 5) element is unique. Boron-based (nano-)materials are equally unique. Accordingly, the present special issue is dedicated to crystalline boron-based (nano-)materials and gathers a series of nine review and research articles dealing with ...
Umit B. Demirci +2 more
doaj +1 more source
Dicarba-nido-undecaborates: topological analysis
Тонкие химические технологии, 2011 Calculations of parameters of function of full electron density in molecules of dicarba-nido-undecaborates were carried out by the first order Promega method using MP2(full)/6-311++G(2d,p) level of theory.
S. P. Knyazev +3 more
doaj