Results 71 to 80 of about 2,463 (211)

Synergistic Action of Ascorbic Acid and Readily Accessible NHC^N Ligands for the Oxidation of Gold(I) With Electron‐Rich Aryldiazonium Salts

open access: yesChemistry – A European Journal, Volume 32, Issue 35, 19 September 2026.
The synergic action of ascorbic acid and NHC^N ligands enables Au(I) oxidation with electron‐rich aryldiazonium salts. ABSTRACT The synergistic action of ascorbic acid and NHC^N ligands enables the challenging oxidation of Au(I) with electron‐rich aryldiazonium salts in the absence of a cocatalyst and/or irradiation. EPR, NMR, and x‐ray analyses reveal
Paula G. Cárdenas‐Cárdenas   +7 more
wiley   +1 more source

Photoinduced Selective B–H Activation of nido-Carboranes

open access: yes
The development of new synthetic methods for B–H bond activation has been an important research area in boron cluster chemistry, which may provide opportunities to broaden the application scope of boron clusters.
Xingwei Guo (1744462)   +9 more
core   +1 more source

Exopolyhedral Ligand Orientation Controls Diastereoisomer in Mixed-Metal Bis(Carboranes)

open access: yesMolecules, 2020
Heterobimetallic derivatives of a bis(carborane), [μ7,8-(1′,3′−3′-Cl-3′-PPh3-closo-3′,1′,2′-RhC2B9H10)-2-(p-cymene)-closo-2,1,8-RuC2B9H10] (1) and [μ7,8-(1′,3′−3′-Cl-3 ...
Antony P. Y. Chan   +2 more
doaj   +1 more source

Hypergolic Copper Cluster‐Based Covalent Organic Frameworks

open access: yesAdvanced Science, Volume 13, Issue 53, 24 September 2026.
Hpergolic cluster‐based covalent organic framework (Cu3‐CB‐COF), assembled from aldehyde‐functionalized carborane monomers and trinuclear copper clusters, demonstrates a strong synergy between its catalytic copper nodes and energetic carborane backbones.
Yu‐Zhou Qiao   +5 more
wiley   +1 more source

Electrochemical and spectroelectrochemical studies of C-benzodiazaborolyl-ortho-carboranes [PDF]

open access: yes, 2013
Weber L, Kahlert J, Böhling L, et al. Electrochemical and spectroelectrochemical studies of C-benzodiazaborolyl-ortho-carboranes. Journal of the Chemical Society. Dalton Transactions. 2013;42(6):2266-2281.Fifteen C-diazaborolyl-ortho-carboranes, 1-R'-2-R
Brockhinke, A.   +16 more
core   +1 more source

The results of the toxicity and hazard studies of isopropyl meta-carborane with single administration to laboratory animals

open access: yesActa Biomedica Scientifica, 2018
Intensive research on the chemistry of borohydrides and the creation of high-energy fuels led to the discovery of a completely new type of organoboron compounds, which were collectively called carboranes.
G. G. Yushkov   +2 more
doaj   +1 more source

Metal Battery Anode: Rich in Electrons, Rich in Problems: A Critical Review from Industrial Perspectives

open access: yesAdvanced Science, Volume 13, Issue 49, 3 September 2026.
Metal‐anode batteries using Li, Na, Mg, and Ca offer exceptionally high energy density, but dendrites, unstable interphases, cracking, and pore formation hinder durability and safety. This review shows how careful electrolyte and interphase design can stabilize these reactive metals.
Jian Pan   +3 more
wiley   +1 more source

Atomically precise metal cluster enzymes for pathological tissue regeneration

open access: yesBMEMat, Volume 4, Issue 3, September 2026.
Schematic illustration of atomically precise metal cluster enzymes (MCEs) for pathological tissue regeneration. Atomically precise MCEs can modulate biological processes, such as attenuation of inflammatory responses, eradication of bacterial pathogens, regulation of angiogenesis, and promotion of cell development.
Ziqiang Xiong   +11 more
wiley   +1 more source

Palladium-Catalyzed Regioselective B(9)-Amination of o‑Carboranes and m‑Carboranes in HFIP with Broad Nitrogen Sources

open access: yes, 2022
Amination of carboranes has a good application prospect in organic and pharmaceutical synthesis. However, the current methods used for this transformation suffer from limitations. Herein, we report a practical method for a highly regioselective formation
Yan Gao (93649)   +11 more
core   +1 more source

Carborane-based BODIPY dyes: synthesis, structural analysis, photophysics and applications

open access: yesFrontiers in Chemistry
Icosahedral boron clusters-based BODIPY dyes represent a cutting-edge class of compounds that merge the unique properties of boron clusters with the exceptional fluorescence characteristics of BODIPY dyes.
Javier Ordóñez-Hernández   +2 more
doaj   +1 more source

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