Results 71 to 80 of about 3,726 (222)
By strategically incorporating boron/nitrogen multi‐resonance (B/N‐MR) core into the o‐carborane unit, perfect exciton utilization can be achieved as well as exhibiting stimuli‐responsive properties. The resulting DBN‐oCb‐based organic light‐emitting diode (OLED) demonstrated an impressive external quantum efficiency of 22.3%, the highest reported for ...
Jiasen Zhang +8 more
wiley +1 more source
Quantum-mechanical calculations of the stabilities of fluxional isomers of C_4H_7^+ in solution [PDF]
Although numerous quantum calculations have been made over the years of the stabilities of the fluxional isomers of C4H7+, none have been reported for other than the gas phase (which is unrealistic for these ionic species) that exhibit exceptional ...
Casanova, Joseph +3 more
core
Icosahedral metallacarborane/carborane species derived from 1,1′-bis(o-carborane) [PDF]
We thank ORSAS (GS) and the EPSRC (DE and DMcK supported by project EP/E02971X/1, WYM supported by project EP/I031545/1) for funding.Examples of singly-metallated derivatives of 1,1[prime or minute]-bis(o-carborane) have been prepared and ...
Chan, Antony P Y +10 more
core +1 more source
ABSTRACT Boron neutron capture therapy (BNCT) is a targeted radiotherapy that exploits the selective accumulation of the 10B isotope within tumors, followed by irradiation with low‐energy neutrons to induce high linear energy transfer particles with short path lengths, resulting in localized tumor cell destruction while sparing surrounding healthy ...
Christoph Selg +2 more
wiley +1 more source
Insertion of Carbenes into Deprotonated nido-Undecaborane, B11H13(2-)
We have examined the insertion of carbenes carrying leaving groups into the [nido-B11H13]2− dianion to form the [closo-1-CB11H12]− anion. The best procedure uses CF3SiMe3 and LiCl as the source of CF2.
Jacek Pecyna +2 more
doaj +1 more source
Molecular recognition on acoustic wave devices [PDF]
Microporous thin films composed either of zeolite crystals embedded in sol-gel derived glass or of a molecular coupling layer, zeolite crystals and a porous silica overlayer, were formed on the gold electrodes of Quartz Crystal Microbalances (QCM). The
Bein, Thomas +4 more
core +1 more source
Boron‐10 carriers and their applications in boron neutron capture therapy
Summary of different types of boron drugs. Abstract Boron neutron capture therapy (BNCT) has emerged as a promising therapeutic modality in cancer treatment, demonstrating the ability to selectively eliminate cancer cells through the 10B(n,α)7Li nuclear reaction with minimal side effects on normal tissues.
Dachao Tang +7 more
wiley +1 more source
A carboranylporphyrin of A3B-type bearing a single pentafluorophenyl ring was prepared through the regioselective nucleophilic aromatic substitution reaction of the p-fluorine atoms in 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin with 9-mercapto-m ...
Victoria M. Alpatova +3 more
doaj +1 more source
Exopolyhedral Ligand Orientation Controls Diastereoisomer in Mixed-Metal Bis(Carboranes)
Heterobimetallic derivatives of a bis(carborane), [μ7,8-(1′,3′−3′-Cl-3′-PPh3-closo-3′,1′,2′-RhC2B9H10)-2-(p-cymene)-closo-2,1,8-RuC2B9H10] (1) and [μ7,8-(1′,3′−3′-Cl-3 ...
Antony P. Y. Chan +2 more
doaj +1 more source
Funcionalització d'o-carborans iodats per obtenir estructures dendrimèriques útils en aplicacions mèdiques [PDF]
L'1,2-dicarba-closo-dodecaborà, l'o-carborà, és un clúster icosaèdric format per deu vèrtexs de borahidrogen i dos vèrtexs de carbonihidrogen en posició adjacent.
Pepiol, Ariadna +3 more
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