Results 51 to 60 of about 764 (178)

Redox‐Active Bisphosphines Based on a W(II)‐Propargyl Complex Backbone

European Journal of Inorganic Chemistry, Volume 29, Issue 19, 2 July 2026.
Three bisphosphine ligands based on tungsten(II) propargyl‐type alkyne complexes were synthesized and characterized. The methanolate derivative was used as a metalla‐ligand for the preparation of a binuclear bisphosphine‐κ2‐PdCl2 complex. In both cases, IR spectroelectrochemistry (IR‐SEC) measurements revealed a successive process following oxidation ...
Friederike M. Hamann, Dirk Michalik, Martina Beese, Anke Spannenberg, Alexander Villinger, Klaus Neymeyr, Robert Francke, Wolfram W. Seidel   +7 more
wiley   +1 more source

Synthesis of new representatives of A3B-type carboranylporphyrins based on meso-tetra(pentafluorophenyl)porphyrin transformations

Beilstein Journal of Organic Chemistry
A carboranylporphyrin of A3B-type bearing a single pentafluorophenyl ring was prepared through the regioselective nucleophilic aromatic substitution reaction of the p-fluorine atoms in 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin with 9-mercapto-m ...
Victoria M. Alpatova, Evgeny G. Rys, Elena G. Kononova, Valentina A. Ol'shevskaya   +3 more
doaj   +1 more source

Insertion of Carbenes into Deprotonated nido-Undecaborane, B₁₁H₁₃(2-)

Molecules, 2019
We have examined the insertion of carbenes carrying leaving groups into the [nido-B11H13]2− dianion to form the [closo-1-CB11H12]− anion. The best procedure uses CF3SiMe3 and LiCl as the source of CF2.
Jacek Pecyna, Igor Rončević, Josef Michl   +2 more
doaj   +1 more source

Aziridination of a Single Carbon Atom in Alkenes via Energy Transfer Catalysis

Angewandte Chemie International Edition, Volume 65, Issue 26, 22 June 2026.
Contrary to traditional alkene aziridination via (formal) nitrene transfer, we herein report a strategy that achieves intermolecular aziridination of a single alkene carbon atom and installs an additional group at the other. Enabled by metal‐free energy transfer (EnT) catalysis, alkenyl boronates and silanes are transformed into reactive intermediates ...
Fritz Paulus, Corinna Heusel, Felix H. Wessels, Bünyamin Sikora, Maik G. Niedziella, Kilian van der Beck, Constantin G. Daniliuc, Frank Glorius   +7 more
wiley   +1 more source

Bright Solvatochromic Fluorophores With Dual Emission Enabled by a Donor‐Engineering Strategy

Chemistry – A European Journal, Volume 32, Issue 23, 16 June 2026.
We screened tertiary amines for installation on the donor unit of highly emissive donor–acceptor‐type solvatochromic fluorophores based on a 9,9‐dimethyl‐2‐phenyl‐9H‐fluorene scaffold, with the aim of enabling two bright emissive states to coexist. As a result, the azetidine derivative [4] and the azepane derivative [7] exhibited clear dual emission ...
Kensei Konishi, Gen‐ichi Konishi
wiley   +1 more source

Exopolyhedral Ligand Orientation Controls Diastereoisomer in Mixed-Metal Bis(Carboranes)

Molecules, 2020
Heterobimetallic derivatives of a bis(carborane), [μ7,8-(1′,3′−3′-Cl-3′-PPh3-closo-3′,1′,2′-RhC2B9H10)-2-(p-cymene)-closo-2,1,8-RuC2B9H10] (1) and [μ7,8-(1′,3′−3′-Cl-3 ...
Antony P. Y. Chan, Georgina M. Rosair, Alan J. Welch   +2 more
doaj   +1 more source

The results of the toxicity and hazard studies of isopropyl meta-carborane with single administration to laboratory animals

Acta Biomedica Scientifica, 2018
Intensive research on the chemistry of borohydrides and the creation of high-energy fuels led to the discovery of a completely new type of organoboron compounds, which were collectively called carboranes.
G. G. Yushkov, V. V. Igumenshcheva, T. M. Filippova   +2 more
doaj   +1 more source

Highly Active Cu14 Cluster Precisely Activates Autophagy Inhibitor to Amplify Cuproptosis Immunotherapy

Advanced Science, Volume 13, Issue 33, 15 June 2026.
An atomically precise Cu14 cluster‐mediated bond scission reaction pioneers the amplification of the antitumor immune response via synergetic cuproptosis‐associated immunogenic cell death induction and in situ autophagy blockade. ABSTRACT Transition metal‐mediated cleavage mechanisms have emerged as an effective means to mitigate the off‐target ...
Qiu‐Xu Zang, Wei‐Tong Chen, Yu‐Ying Shen, Zhao‐Yang Wang, Kai Li, Xueli Zhao, Yanjuan Sang, Xiaoyuan Chen, Shuang‐Quan Zang   +8 more
wiley   +1 more source

Carborane-based BODIPY dyes: synthesis, structural analysis, photophysics and applications

Frontiers in Chemistry
Icosahedral boron clusters-based BODIPY dyes represent a cutting-edge class of compounds that merge the unique properties of boron clusters with the exceptional fluorescence characteristics of BODIPY dyes.
Javier Ordóñez-Hernández, José Giner Planas, Rosario Núñez   +2 more
doaj   +1 more source

Design of Carborane Molecular Architectures via Electronic Structure Computations

International Journal of Photoenergy, 2009
Quantum-mechanical electronic structure computations were employed to explore initial steps towards a comprehensive design of polycarborane architectures through assembly of molecular units.
Josep M. Oliva, Luis Serrano-Andrés, Douglas J. Klein, Paul von Ragué Schleyer, Josef Michl   +4 more
doaj   +1 more source