Geophysical Monograph Series, Page 341-349., 2020 This book is Open Access. A digital copy can be downloaded for free from Wiley Online Library.
Explores the behavior of carbon in minerals, melts, and fluids under extreme conditions
Carbon trapped in diamonds and carbonate-bearing rocks in subduction zones are examples of the continuing exchange of substantial carbon ...
Sulgiye Park, Yu Lin, Wendy L. Mao
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Molecules, 2021 A synthetic strategy for obtaining structurally flexible hybrid iron(II) carboranoclatrochelates functionalized with biorelevant groups, based on a combination of a 1,3-dipolar cycloaddition reaction with nucleophilic substitution of an appropriate ...
Genrikh E. Zelinskii +9 more
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, 2023 Luminochromic behaviors regarding mechanochromic luminescence (MCL) of o-carborane-modified anthracene derivatives are reported. We have previously synthesized bis-o-carborane-substituted anthracene and found that its crystal polymorphs show dual ...
Yuhara, Kazuhiro +3 more
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Molecules, 2021 Bis(carboranyl)amides 1,1′-μ-(CH2NH(O)C(CH2)n-1,2-C2B10H11)2 (n = 0, 1) were prepared by the reactions of the corresponding carboranyl acyl chlorides with ethylenediamine.
Yasunobu Asawa +7 more
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Substituent Effects on the Fluorescence Properties of ortho-Carboranes: Unusual Emission Behaviour in C-(2 '-Pyridyl)-ortho-carboranes [PDF]
, 2016 Böhling L, Brockhinke A, Kahlert J, et al. Substituent Effects on the Fluorescence Properties of ortho-Carboranes: Unusual Emission Behaviour in C-(2 '-Pyridyl)-ortho-carboranes. European Journal of Inorganic Chemistry.
Howard, Judith A. K. +17 more
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A Mesoionic Platform for Persistent Anionic Nitrogen‐Centered Radicals
Angewandte Chemie, EarlyView.Charge did not meet spin: Mesoionic 1,2,3‐triazines undergo reversible one‐electron reduction to persistent anionic nitrogen‐centered radicals. Electron paramagnetic resonance, single‐crystal x‐ray diffraction, and calculations reveal nitrogen‐localized spin and structural reorganization, while crystalline salts show clean redox cycling.
Deepak Ranolia +8 more
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Carborane-Based Analog of Rev-5901 Attenuates Growth of Colon Carcinoma In Vivo
Molecules, 2022 Lipoxygenases convert polyunsaturated fatty acids into biologically active metabolites such as inflammatory mediators—prostaglandins and leukotrienes. The inhibition of lipoxygenases is increasingly employed in the treatment of cancer.
Svetlana Paskaš +5 more
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Photoswitchable Ambiphilicity: Light‐Gated Frustrated Lewis Pair Reactivity and Z‐Type Interaction
Angewandte Chemie, EarlyView.Light‐controlled ambiphilicity is realized in photoswitchable intramolecular phosphorus/boron Lewis pairs. Reversible switching modulates both the thermodynamics and kinetics of frustrated Lewis‐pair reactivity, enabling light‐gated CO2 binding and release.
Lennart Stoess +3 more
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Angewandte Chemie, EarlyView.Single‐atom growth from [Zr@Sb12]2− to [Zr@Sb13]3− disrupts the closed‐shell S2P6 superatomic configuration and markedly attenuates three‐dimensional (3D) aromaticity. Ultrafast spectroscopy further links stronger spherical aromaticity to slower excited‐state relaxation, establishing an atom‐resolved structure‐aromaticity‐dynamics relationship ...
Yun Zhang +7 more
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Definitive crystal structure of 1,1′-bis[1,2-dicarba-closo-dodecaborane(11)]
Acta Crystallographica Section E, 2014 In the title compound, C4H22B20, the two {1,2-closo-C2B10H11} cages are linked across a centre of inversion with a C—C distance of 1.5339 (11) Å.
Wing Y. Man +2 more
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