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Explores the behavior of carbon in minerals, melts, and fluids under extreme conditions
Carbon trapped in diamonds and carbonate-bearing rocks in subduction zones are examples of the continuing exchange of substantial carbon ...
Sulgiye Park, Yu Lin, Wendy L. Mao
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A synthetic strategy for obtaining structurally flexible hybrid iron(II) carboranoclatrochelates functionalized with biorelevant groups, based on a combination of a 1,3-dipolar cycloaddition reaction with nucleophilic substitution of an appropriate ...
Genrikh E. Zelinskii +9 more
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Unusual cage rearrangements in 10-vertex nido-5,6-dicarbaborane derivatives : An interplay between theory and experiment [PDF]
The reaction between selected X-nido-5,6-C2B8H11 compounds (where X = Cl, Br, I) and "Proton Sponge" [PS; 1,8-bis(dimethylamino)naphthalene], followed by acidification, results in extensive rearrangement of all cage vertices.
Bakardjiev, Mario +6 more
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Bis(carboranyl)amides 1,1′-μ-(CH2NH(O)C(CH2)n-1,2-C2B10H11)2 (n = 0, 1) were prepared by the reactions of the corresponding carboranyl acyl chlorides with ethylenediamine.
Yasunobu Asawa +7 more
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Carborane bis-pyridylalcohols as linkers for coordination polymers : synthesis, crystal structures and guest-framework dependent mechanical properties [PDF]
We report the synthesis and characterization of six novel coordination polymers (CPs) based on M(II) (M: Zn and Co), di-, tri-, and tetracarboxylate linkers and two novel bis-pyridylalcohol 1,7-bis{(pyridin-n'-yl)methanol}-1,7-dicarba-closo-dodecaboranes
Choquesillo-Lazarte, Duane +13 more
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Carborane-Based Analog of Rev-5901 Attenuates Growth of Colon Carcinoma In Vivo
Lipoxygenases convert polyunsaturated fatty acids into biologically active metabolites such as inflammatory mediators—prostaglandins and leukotrienes. The inhibition of lipoxygenases is increasingly employed in the treatment of cancer.
Svetlana Paskaš +5 more
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A light mediated direct regioselective B─H functionalization, via hydrogen atom transfer (HAT), is described. Unexplored xanthyl‐closo‐carboranes as novel bench‐stable and versatile platforms to access sulfur‐containing boron clusters are reported for the first time.
Marco Rusconi +9 more
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The effects of halogen elements on the opening of an icosahedral B12 framework [PDF]
The fully halogenated or hydrogenated B12X12 (X = H, F, Cl, Br and I) clusters are confirmed to be icosahedral. On the other hand, the bare B12 cluster is shown to have a planar structure. A previous study showed that a transformation from an icosahedron
Gong, Liang-Fa +5 more
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Carborane–β-cyclodextrin complexes as a supramolecular connector for bioactive surfaces [PDF]
Supramolecular chemistry provides an attractive entry to generate dynamic and well-controlled bioactive surfaces. Novel host–guest systems are urgently needed to provide a broader affinity and applicability portfolio.
Brunsveld, Luc +6 more
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Reactions of Experimentally Known Closo-C2B8H10 with Bases. A Computational Study
On the basis of the direct transformations of closo-1,2-C2B8H10 with OH(−) and NH3 to arachno-1,6,9-OC2B8H13(−) and arachno-1,6,9-NC2B8H13, respectively, which were experimentally observed, the DFT computational protocol was used to examine the ...
Josef Holub +3 more
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