Results 11 to 20 of about 2,463 (211)

Carborane: Dedicated to the Work of Professor Alan Welch [PDF]

open access: yes, 2022
This Special Issue on carboranes is dedicated to Prof. Alan Welch on the occasion of his retirement and his outstanding contributions to the field of carborane chemistry. Polyhedral carboranes lie at the interface of organic and inorganic chemistry. One

core   +2 more sources

The Photophysics and Electrochemistry of Carboranes [PDF]

open access: yes, 2013
This thesis describes research carried out on compounds containing icosahedral carborane moieties (ortho/meta/para-CB10H10C-), investigating their photophysical and electrochemical properties.
Harder, Rachel Abigail
core   +6 more sources

B–N, B–O, and B–CN Bond Formation via Palladium-Catalyzed Cross-Coupling of B‑Bromo-Carboranes [PDF]

open access: yes, 2016
Carboranes are boron-rich molecules that can be functionalized through metal-catalyzed cross-coupling. Here, for the first time, we report the use of bromo-carboranes in palladium-catalyzed cross-coupling for efficient B–N, B–O, and unprecedented B–CN ...
Simone L. Stevens (2878427)   +7 more
core   +2 more sources

DFT Surface Infers Ten-Vertex Cationic Carboranes from the Corresponding Neutral closo Ten-Vertex Family: The Computed Background Confirming Their Experimental Availability

open access: yesMolecules, 2023
Modern computational protocols based on the density functional theory (DFT) infer that polyhedral closo ten-vertex carboranes are key starting stationary states in obtaining ten-vertex cationic carboranes.
Michael L. McKee   +4 more
doaj   +1 more source

Synthesis and Crystal Structure of 9,12-Dibromo-ortho-Carborane

open access: yesMolbank, 2022
Synthesis, NMR spectral data and crystal structure of 9,12-dibromo derivative of ortho-carborane are reported.
Olga B. Zhidkova   +5 more
doaj   +1 more source

Pd-Catalyzed Selective B(6)–H Phosphorization of nido-Carboranes via Cascade Deboronation/B–H Activation from closo-Carboranes

open access: yes, 2022
Efficient Pd-catalyzed regioselective B(6)–H phosphorization of nido-carboranes via cascade deboronation/B–H activation of readily available C-substituted o-carboranes with various phosphines using 3-methylpyridine or isoquinoline as a directing group in
Jian Lu (51707)   +2 more
core   +1 more source

A Simple Way to Obtain a Decachloro Derivative of Cobalt Bis(dicarbollide)

open access: yesReactions, 2023
A simple synthetic way to obtain a decachloro derivative of cobalt bis(dicarbollide) has been found. The reaction of cesium salt of cobalt bis(dicarbollide) anion with aluminum chloride in chloroform under reflux conditions results in Cs[3,3′-Co(4,7,8,9 ...
Sergey A. Anufriev   +2 more
doaj   +1 more source

Carboranes

open access: yesDalton Transactions, 2014
Citation: 'carboranes' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.C00849 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
Zuowei, Xie, Guo-Xin, Jin
openaire   +3 more sources

Tuning the Liquid Crystallinity of Cholesteryl-o-Carborane Dyads: Synthesis, Structure, Photoluminescence, and Mesomorphic Properties

open access: yesCrystals, 2021
A set of mesomorphic materials in which the o-carborane cluster is covalently bonded to a cholesteryl benzoate moiety (mesogen group) through a suitably designed linker is described.
Albert Ferrer-Ugalde   +6 more
doaj   +1 more source

Synthesis and X-ray characterization of 15- and 16-vertex closo-carboranes

open access: yesNature Communications, 2020
The synthesis of closo-carboranes with more than 14 vertexes is challenging, and no examples have been reported to date. Herein, the authors present the long-sought 15- and 16-vertex closo-carboranes, in which the introduction of silyl groups to the two ...
Fangrui Zheng   +3 more
doaj   +1 more source

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