Results 11 to 20 of about 765 (180)
Carborane photochromism: a fatigue resistant carborane switch
A dithienylethene molecule involving carborane clusters shows remarkable fatigue resistance and high contrast visual colour changes when irradiated with alternating ultraviolet and visible light.
Chong Li +6 more
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Synthesis and Crystal Structure of 9,12-Dibromo-ortho-Carborane
Synthesis, NMR spectral data and crystal structure of 9,12-dibromo derivative of ortho-carborane are reported.
Olga B. Zhidkova +5 more
doaj +1 more source
A Simple Way to Obtain a Decachloro Derivative of Cobalt Bis(dicarbollide)
A simple synthetic way to obtain a decachloro derivative of cobalt bis(dicarbollide) has been found. The reaction of cesium salt of cobalt bis(dicarbollide) anion with aluminum chloride in chloroform under reflux conditions results in Cs[3,3′-Co(4,7,8,9 ...
Sergey A. Anufriev +2 more
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Citation: 'carboranes' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.C00849 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
Zuowei, Xie, Guo-Xin, Jin
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A set of mesomorphic materials in which the o-carborane cluster is covalently bonded to a cholesteryl benzoate moiety (mesogen group) through a suitably designed linker is described.
Albert Ferrer-Ugalde +6 more
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Synthesis and X-ray characterization of 15- and 16-vertex closo-carboranes
The synthesis of closo-carboranes with more than 14 vertexes is challenging, and no examples have been reported to date. Herein, the authors present the long-sought 15- and 16-vertex closo-carboranes, in which the introduction of silyl groups to the two ...
Fangrui Zheng +3 more
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Chiral-at-cage o-carboranes are clusters of carbon and boron atoms that, when functionalized, can lower the symmetry of the cluster. Here the authors present a method to alkenylate B–H bonds on ocarboranes enantioselectively via iridium catalysis.
Ruofei Cheng +4 more
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Towards the Application of Purely Inorganic Icosahedral Boron Clusters in Emerging Nanomedicine
Traditionally, drugs were obtained by extraction from medicinal plants, but more recently also by organic synthesis. Today, medicinal chemistry continues to focus on organic compounds and the majority of commercially available drugs are organic molecules,
Francesc Teixidor +2 more
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Carborane Nanomembranes. [PDF]
We report on the fabrication of a boron-based two-dimensional (2D) material via electron irradiation-induced cross-linking of carborane self-assembled monolayers (SAMs) on crystalline silver substrates. The SAMs of 1,2-dicarba-closo-dodecarborane-9,12-dithiol (O9,12) were prepared on flat crystalline silver substrates and irradiated with low-energy ...
Frey M +8 more
europepmc +4 more sources
Iridium-catalysed regioselective borylation of carboranes via direct B–H activation
Functionalization of the multiple, similar, boron-hydrogen bonds in carboranes is difficult to achieve with selectivity. Here the authors report an iridium-catalysed borylation ofo-carboranes with high yields and regioselectivities.
Ruofei Cheng, Zaozao Qiu, Zuowei Xie
doaj +1 more source

