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Nickel or Palladium-Catalyzed Decarbonylative Transformation of Carboxylic Acid Derivatives.

Chemistry - An Asian Journal, 2020
Carboxylic acid derivatives containing acyl halides, anhydrides, esters, amides and acyl nitriles are highly appealing electrophiles in transition-metal-catalyzed carbon-carbon bond-forming reactions due to their ready availability and low cost, which ...
Zhenhua Wang, Xiu Wang, Y. Nishihara
semanticscholar   +1 more source

Facile and Time-Efficient Carboxylic Acid Functionalization of PIM-1: Effect on Molecular Packing and Gas Separation Performance

, 2020
An optimized acid hydrolysis method was developed to yield carboxylic acid-functionalized PIM-1 (PIM-COOH) with >89% conversion in 48 h using a postpolymerization reaction of PIM-1.
Katherine Mizrahi Rodriguez   +9 more
semanticscholar   +1 more source

Enantioselective C(sp3 )-H Amidation of Thioamides Catalyzed by a CobaltIII /Chiral Carboxylic Acid Hybrid System.

Angewandte Chemie, 2019
Recent advances in Cpx MIII catalysis (M=Co, Rh, Ir) have enabled a variety of enantioselective C(sp2 )-H functionalization reactions, but enantioselective C(sp3 )-H functionalization is still largely unexplored.
Seiya Fukagawa   +5 more
semanticscholar   +1 more source

Synthesis of Biobased Flame-Retardant Carboxylic Acid Curing Agent and Application in Wood Surface Coating

ACS Sustainable Chemistry and Engineering, 2019
The novel polybasic carboxylic acid (HCPVC) consisting of vanillin and hexachlorocyclotriphosphazene was synthesized successfully by the nucleophilic substitution reaction and the Pinnick oxidation...
Yishuai Huang   +3 more
semanticscholar   +1 more source

Mechanism and Scope of Nickel-Catalyzed Decarbonylative Borylation of Carboxylic Acid Fluorides.

Journal of the American Chemical Society, 2019
This Article describes the development of a base-free, nickel-catalyzed decarbonylative coupling of carboxylic acid fluorides with diboron reagents to selectively afford aryl boronate ester products. Detailed studies were conducted to assess the relative
Christian A. Malapit   +3 more
semanticscholar   +1 more source

Palladium-Catalyzed Direct Synthesis of Various Branched, Carboxylic Acid-Functionalized Polyolefins: Characterization, Derivatization, and Properties

Macromolecules, 2018
Ethylene-co-acrylic acid (E–AA) copolymers are typically produced via high-pressure free radical copolymerization and have great industrial importance because of their many applications.
Shengyu Dai, Changle Chen
semanticscholar   +1 more source

Behavior of carboxylic acids and carboxylic anhydrides in sulfuric acid

Canadian Journal of Chemistry, 1967
The behavior of some carboxylic acids and anhydrides in sulfuric acid has been investigated by cryoscopic and conductimetric measurements in 100% H2SO4, cryoscopic measurements in aqueous H2SO4, and conductimetric titrations in dilute oleum.The previously established behavior of acetic anhydride in dehydrating sulfuric acid, [Formula: see text]is ...
S. A. A. Quadri, E. A. Robinson
openaire   +2 more sources

Cobalt Pincer Complexes for Catalytic Reduction of Carboxylic Acid Esters.

Chemistry, 2018
A selection of cobalt(I) and cobalt(II) pincer type complexes with different substitution patterns was tested in the catalytic reduction of carboxylic acid esters to alcohols. The cobalt pincer type complex 4 is suitable for the hydrogenation of aromatic
K. Junge   +6 more
semanticscholar   +1 more source

ChemInform Abstract: Synthetic Receptors for Carboxylic Acids and Carboxylates

ChemInform, 2002
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Fitzmaurice, Richard J.   +3 more
openaire   +4 more sources

Characterization of Carboxylic Acid Reductases for Biocatalytic Synthesis of Industrial Chemicals

ChemBioChem, 2018
Carboxylic acid reductases (CARs) catalyze the reduction of a broad range of carboxylic acids into aldehydes, which can serve as common biosynthetic precursors to many industrial chemicals.
Levi Kramer   +6 more
semanticscholar   +1 more source

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