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Behavior of carboxylic acids and carboxylic anhydrides in sulfuric acid
Canadian Journal of Chemistry, 1967The behavior of some carboxylic acids and anhydrides in sulfuric acid has been investigated by cryoscopic and conductimetric measurements in 100% H2SO4, cryoscopic measurements in aqueous H2SO4, and conductimetric titrations in dilute oleum.The previously established behavior of acetic anhydride in dehydrating sulfuric acid, [Formula: see text]is ...
S. A. A. Quadri, E. A. Robinson
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ChemInform Abstract: Synthetic Receptors for Carboxylic Acids and Carboxylates
ChemInform, 2002AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Fitzmaurice, Richard J.+3 more
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1983
Publisher Summary Laboratory methods for the synthesis of carboxylic acids are oxidation, oxidation-reduction reactions, carbonation of organometallics, condensation reactions, and hydrolysis reactions. This chapter discusses the haloform reaction that is used for the oxidation of aliphatic methyl ketones or of methyl carbinols to carboxylic acids ...
Stanley R. Sandler, Wolf Karo
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Publisher Summary Laboratory methods for the synthesis of carboxylic acids are oxidation, oxidation-reduction reactions, carbonation of organometallics, condensation reactions, and hydrolysis reactions. This chapter discusses the haloform reaction that is used for the oxidation of aliphatic methyl ketones or of methyl carbinols to carboxylic acids ...
Stanley R. Sandler, Wolf Karo
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Acidity of Carboxylic Acids: A Rebuttal and Redefinition
Journal of the American Chemical Society, 2001A recent theory of ionization of carboxylic acids divided the process of ionization into two steps and attributed the main importance to the electrostatic potential of the acid molecule. The origin of the acidity was thus seen in the high energy of the acid molecule and not in the stabilization of the anion by resonance.
Otto Exner, Petr Čársky
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Journal of the American Chemical Society, 2020
We found that in situ generated cerium(IV) carboxylate generated by mixing the precursor Ce(OtBu)4 with the corresponding carboxylic acids served as efficient photocatalysts for the direct formation of carboxyl radicals from carboxylic acids under blue light-emitting diodes (blue LEDs) irradiation and air, resulting in catalytic decarboxylative ...
Satoru Shirase+6 more
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We found that in situ generated cerium(IV) carboxylate generated by mixing the precursor Ce(OtBu)4 with the corresponding carboxylic acids served as efficient photocatalysts for the direct formation of carboxyl radicals from carboxylic acids under blue light-emitting diodes (blue LEDs) irradiation and air, resulting in catalytic decarboxylative ...
Satoru Shirase+6 more
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2022
A carboxylic acid is an organic acid that contains a carboxyl group (C(=O)OH) attached to an R-group. The general formula of a carboxylic acid is R−COOH or R−CO2H, with R referring to the alkyl, alkenyl, aryl, or other group. Carboxylic acids occur widely. Important examples include the amino acids and fatty acids.
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A carboxylic acid is an organic acid that contains a carboxyl group (C(=O)OH) attached to an R-group. The general formula of a carboxylic acid is R−COOH or R−CO2H, with R referring to the alkyl, alkenyl, aryl, or other group. Carboxylic acids occur widely. Important examples include the amino acids and fatty acids.
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Phenanthrene-4-carboxylic Acid and 1,2-Dihydrophenanthrene-4-carboxylic Acid
Acta Crystallographica Section C Crystal Structure Communications, 1998Phenanthrene-4-carboxylic acid, C15H10O2, crystallized in the centrosymmetric space group P2(1)/n, while 1,2-dihydrophenanthrene-4-carboxylic acid, C15H12O2, crystallized in the centrosymmetric space group Pbca. In each structure, there is a single type of hydrogen bond: it is of the cyclic dimer type about a center of symmetry.
L. J. Fitzgerald, R. E. Gerkin
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ChemInform Abstract: Carboxylic Acids and Esters
ChemInform, 1996AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
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