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Hydrogenation of Carboxylic Acids, Esters, and Related Compounds over Heterogeneous Catalysts: A Step toward Sustainable and Carbon-Neutral Processes.

Chemical Reviews, 2023
The catalytic hydrogenation of esters and carboxylic acids represents a fundamental and important class of organic transformations, which is widely applied in energy, environmental, agricultural, and pharmaceutical industries.
Ruiyang Qu, K. Junge, M. Beller
semanticscholar   +1 more source

Visible-Light-Induced Decarboxylative Fluorination of Aliphatic Carboxylic Acids Catalyzed by Iron.

Organic Letters, 2022
An efficient and inexpensive protocol for the direct decarboxylative fluorination of aliphatic carboxylic acids catalyzed with iron salts under visible light is presented.
Yu Zhang   +4 more
semanticscholar   +1 more source

Deoxygenative Functionalizations of Aldehydes, Ketones and Carboxylic Acids.

Angewandte Chemie, 2021
Conversion of carbonyl compounds, including aldehydes, ketones and carboxylic acids, into functionalized alkanes via deoxygenation would be highly desirable from a sustainability perspective and very enabling in chemical synthesis. This review covers the
Jianbin Li   +2 more
semanticscholar   +1 more source

CARBOXYLIC ACIDS

1983
This chapter discusses carboxylic acids that generally have high mobilities compared with those of proteins. Carboxylic acids used as model substances for checking both theoretical aspects and correct functioning of the equipment are separated qualitatively and quantitatively by isotachophoresis.
Stanley R. Sandler, Wolf Karo
openaire   +2 more sources

Degradation of Deep-Eutectic Solvents Based on Choline Chloride and Carboxylic Acids

ACS Sustainable Chemistry and Engineering, 2019
Mixtures of carboxylic acids and choline chloride are one of the most commonly used families of deep-eutectic solvents. The thermal and long-term stability of carboxylic acid–choline chloride (ChCl) deep-eutectic solvents was investigated. This family of
Nerea Rodriguez Rodriguez   +4 more
semanticscholar   +1 more source

Direct C(sp3)–H Activation of Carboxylic Acids

Synthesis, 2019
Carboxylic acids are important in a variety of research fields and applications. As a result, substantial efforts have been directed towards the C–H functionalization of such compounds.
A. Uttry, Manuel van Gemmeren
semanticscholar   +1 more source

Deoxygenative Deuteration of Carboxylic Acids with D2 O.

Angewandte Chemie, 2018
We report a general, practical, and scalable means of preparing deuterated aldehydes from aromatic and aliphatic carboxylic acids with D2 O as an inexpensive deuterium source.
Muliang Zhang   +3 more
semanticscholar   +1 more source

Fluorene-1-carboxylic Acid

Acta Crystallographica Section C Crystal Structure Communications, 1996
In fluorene-1-carboxylic acid, C14H10O2, the sole hydrogen bond is of the cyclic dimer type about a center of symmetry. The carboxyl H atom is ordered. Distances in the fluorene core are very similar to those in fluorene itself; the fluorene core dihedral angle is, however, larger than in fluorene.
A C, Blackburn, A J, Dobson, R E, Gerkin
openaire   +2 more sources

Quinoline-4-carboxylic Acid

Acta Crystallographica Section C Crystal Structure Communications, 1998
The title acid, C10H7NO2, crystallized in the centrosymmetric space group P2(1)/c with one molecule in the asymmetric unit. There is a single hydrogen bond. O-H...N, with a donor-acceptor distance of 2.596 (1) A. The carboxylic H atom is ordered. The dihedral angle between the best-fit quinoline core plane and the carboxyl plane is 45.9 (1) degrees ...
Amonette, Allison J., Gerkin, Roger E.
openaire   +3 more sources

Palladium-Catalyzed Decarbonylative Borylation of Carboxylic Acids: Tuning Reaction Selectivity by Computation.

Angewandte Chemie, 2018
Decarbonylative borylation of carboxylic acids is reported. Carbon electrophiles are generated directly after reagent-enabled decarbonylation of the in situ accessible sterically-hindered acyl derivative of a carboxylic acid under catalyst controlled ...
Chengwei Liu   +3 more
semanticscholar   +1 more source

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