Results 131 to 140 of about 1,686 (179)
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Chemischer Informationsdienst, 1984
AbstractDie SeO2‐Oxidation der Allyldigitoxine (I) ergibt die Aldehyde (II).
B. STRECKENBACH, K. R. H. REPKE
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AbstractDie SeO2‐Oxidation der Allyldigitoxine (I) ergibt die Aldehyde (II).
B. STRECKENBACH, K. R. H. REPKE
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A novel approach to cardenolides
The Journal of Organic Chemistry, 1985On prepare l'acetoxy-3β card-5α,14α ene-20(22) olide et son isomere-5β a partir de l'acetoxy-3β androstane-5α one-17 et de son isomere ...
Wolfram Harnisch +2 more
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Oximes and nitriles of cardenolides
Chemistry of Natural Compounds, 1983The influence of the oximation of cardenolides and the production of 10-cyanocardenolides on their biological activity has been studied. The prefered conformation of strophanthidin 19-aldoxime has been established; it has chelate fragment as the result of the orientation in the same direction of the nitrogen atom of the oxime group and the hydroxy ...
I. F. Makarevich +7 more
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1998
Saponins are compounds that possess a polycyclic aglycone moiety with either a steroid (typically C27) or triterpenoid (C30) structure attached to a carbohydrate unit (a monosac-charide or oligosaccharide chain) (Fig. 24.1). These sugar units are composed variously of pentoses, hexoses, or uronic acids.
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Saponins are compounds that possess a polycyclic aglycone moiety with either a steroid (typically C27) or triterpenoid (C30) structure attached to a carbohydrate unit (a monosac-charide or oligosaccharide chain) (Fig. 24.1). These sugar units are composed variously of pentoses, hexoses, or uronic acids.
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ChemInform, 1987
AbstractOxidation of the digitoxigenin derivative (I) yields the products (II)‐(IV).
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AbstractOxidation of the digitoxigenin derivative (I) yields the products (II)‐(IV).
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Glycosylation in cardenolide biosynthesis
Plant Cell, Tissue and Organ Culture, 1994The glycosylation and deglycosylation of cardiac glycosides was investigated using cell suspension cultures and shoot cultures, both established from Digitalis lanata EHRH. plants, as well as isolated enzymes. Shoots were capable of glucosylating digitoxigenin, evatromonoside, digiproside, glucodigitoxigenin and digitoxin. Suspension cultured Digitalis
Christoph Theurer +4 more
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Circular Dichroism of Cardenolides
Journal f�r Praktische Chemie/Chemiker-Zeitung, 1998The relationship between structure and circular dichroism was studied for a series of cardenolides including some compounds with saturated lactone ring.
Helmut Ripperger +2 more
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Journal of Fluorine Chemistry, 1985
Abstract For estimation of the influence of fluorination at C21 of the lactone ring of cardenolides on their cardiac activity we have synthesized 21α- and 21β-fluoro-cardenolides by treatment of 21β-bromo-cardenolides with AgF. Prior to allylic bromination of cardenolides their OH- groups are protected by CCl 3 CH 2 OCO- groups and deprotected after ...
R. Megges +5 more
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Abstract For estimation of the influence of fluorination at C21 of the lactone ring of cardenolides on their cardiac activity we have synthesized 21α- and 21β-fluoro-cardenolides by treatment of 21β-bromo-cardenolides with AgF. Prior to allylic bromination of cardenolides their OH- groups are protected by CCl 3 CH 2 OCO- groups and deprotected after ...
R. Megges +5 more
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