Results 1 to 10 of about 2,370 (198)
Some of the next articles are maybe not open access.
SYNTHETIC CARDENOLIDES AND RELATED PRODUCTS
Pure and Applied Chemistry, 1970Abstract
openaire +2 more sources
Two cardenolides fromCalotropis procera
Magnetic Resonance in Chemistry, 1999Two cardiotonic glycosides were isolated from Calotropois procera; one of them (1) is a new natural product. Their structures were elucidated by extensive application of oneand two-dimensional 1H and 13C NMR spectroscopy. Copyright 1999 John Wiley & Sons, Ltd.
Atef G. Hanna +5 more
openaire +1 more source
A novel approach to cardenolides
The Journal of Organic Chemistry, 1985On prepare l'acetoxy-3β card-5α,14α ene-20(22) olide et son isomere-5β a partir de l'acetoxy-3β androstane-5α one-17 et de son isomere ...
Wolfram Harnisch +2 more
openaire +1 more source
Oximes and nitriles of cardenolides
Chemistry of Natural Compounds, 1983The influence of the oximation of cardenolides and the production of 10-cyanocardenolides on their biological activity has been studied. The prefered conformation of strophanthidin 19-aldoxime has been established; it has chelate fragment as the result of the orientation in the same direction of the nitrogen atom of the oxime group and the hydroxy ...
I. F. Makarevich +7 more
openaire +1 more source
ChemInform, 1987
AbstractOxidation of the digitoxigenin derivative (I) yields the products (II)‐(IV).
openaire +1 more source
AbstractOxidation of the digitoxigenin derivative (I) yields the products (II)‐(IV).
openaire +1 more source
Chemischer Informationsdienst, 1984
AbstractDie SeO2‐Oxidation der Allyldigitoxine (I) ergibt die Aldehyde (II).
B. STRECKENBACH, K. R. H. REPKE
openaire +1 more source
AbstractDie SeO2‐Oxidation der Allyldigitoxine (I) ergibt die Aldehyde (II).
B. STRECKENBACH, K. R. H. REPKE
openaire +1 more source
Glycosylation in cardenolide biosynthesis
Plant Cell, Tissue and Organ Culture, 1994The glycosylation and deglycosylation of cardiac glycosides was investigated using cell suspension cultures and shoot cultures, both established from Digitalis lanata EHRH. plants, as well as isolated enzymes. Shoots were capable of glucosylating digitoxigenin, evatromonoside, digiproside, glucodigitoxigenin and digitoxin. Suspension cultured Digitalis
Christoph Theurer +4 more
openaire +1 more source
1998
Saponins are compounds that possess a polycyclic aglycone moiety with either a steroid (typically C27) or triterpenoid (C30) structure attached to a carbohydrate unit (a monosac-charide or oligosaccharide chain) (Fig. 24.1). These sugar units are composed variously of pentoses, hexoses, or uronic acids.
openaire +1 more source
Saponins are compounds that possess a polycyclic aglycone moiety with either a steroid (typically C27) or triterpenoid (C30) structure attached to a carbohydrate unit (a monosac-charide or oligosaccharide chain) (Fig. 24.1). These sugar units are composed variously of pentoses, hexoses, or uronic acids.
openaire +1 more source
Circular Dichroism of Cardenolides
Journal f�r Praktische Chemie/Chemiker-Zeitung, 1998The relationship between structure and circular dichroism was studied for a series of cardenolides including some compounds with saturated lactone ring.
Helmut Ripperger +2 more
openaire +1 more source
Journal of Fluorine Chemistry, 1985
Abstract For estimation of the influence of fluorination at C21 of the lactone ring of cardenolides on their cardiac activity we have synthesized 21α- and 21β-fluoro-cardenolides by treatment of 21β-bromo-cardenolides with AgF. Prior to allylic bromination of cardenolides their OH- groups are protected by CCl 3 CH 2 OCO- groups and deprotected after ...
R. Megges +5 more
openaire +1 more source
Abstract For estimation of the influence of fluorination at C21 of the lactone ring of cardenolides on their cardiac activity we have synthesized 21α- and 21β-fluoro-cardenolides by treatment of 21β-bromo-cardenolides with AgF. Prior to allylic bromination of cardenolides their OH- groups are protected by CCl 3 CH 2 OCO- groups and deprotected after ...
R. Megges +5 more
openaire +1 more source

