Results 211 to 220 of about 4,729 (242)
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Cardenolide analogues. 3. A fast thin layer Chromatographic separation of cardenolide diastereomers
Steroids, 1978Cardenolide diasteromeric mixtures may be analytically separated on 2.5 x 6.5 cm x 0.25 mm pre-coated silical gel 60 F-250 (EM) tlc plates (cut from 20 x 20 cm plates). Three successive developments in mixtures of CH2Cl2-EtOAc-MeOH achieve complete separation of diastereomers in less than 15 minutes, and 2--6 micrograms of sample is sufficient.
K, Yoshioka, D S, Fullerton
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Ring-D fragmentation of cardenolides
Biological Mass Spectrometry, 1977The major fragmentation paths typical for the cardenolides system have been elucidated by labelling studies.
E, Flaskamp, H, Budzikiewicz
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Antiproliferative cardenolides from Periploca graeca
Planta Medica, 2007Nine cardiotonic steroids, six 17beta-cardenolides (2, 4, 6-9) and three 17alpha-cardenolides (1, 3, 5) have been identified from the chloroform and chloroform-methanol extracts of Periploca graeca L. (Asclepiadaceae) stems. Among these, compound 5, the 17alpha-isomer of periplocin 6, was identified as a new compound.
D. SPERA +4 more
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Chemischer Informationsdienst, 1981
AbstractDie Ausgangsverbindung zur Synthese der Cardenolid‐Analogen (III) und (IV) bzw. (VI) ist das in hoher Ausb. nach bekannter Methode erhaltene β‐Ketosulfoxid (I).
F. THEIL, C. LINDIG, K. REPKE
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AbstractDie Ausgangsverbindung zur Synthese der Cardenolid‐Analogen (III) und (IV) bzw. (VI) ist das in hoher Ausb. nach bekannter Methode erhaltene β‐Ketosulfoxid (I).
F. THEIL, C. LINDIG, K. REPKE
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Glycosylation in cardenolide biosynthesis
Plant Cell, Tissue and Organ Culture, 1994The glycosylation and deglycosylation of cardiac glycosides was investigated using cell suspension cultures and shoot cultures, both established from Digitalis lanata EHRH. plants, as well as isolated enzymes. Shoots were capable of glucosylating digitoxigenin, evatromonoside, digiproside, glucodigitoxigenin and digitoxin. Suspension cultured Digitalis
Christoph Theurer +4 more
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Alepposides, Cardenolide Oligoglycosides from Adonis aleppica
Journal of Natural Products, 1993The structures of novel oligoglycosidic cardenolides, alepposide A (C55H86O23) [1] and alepposide B (C48H74O20) [2], have been deduced mainly by nmr methods. Based on homonuclear (1H and 13C nmr, 1H COSY) and proton-detected heteronuclear shift correlation experiments [HMQC both for 1J(C,H) and for long-range couplings], alepposide A [1] was shown to ...
G F, Pauli +3 more
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Cardenolides ofSecurigera securidaca. II.
Chemistry of Natural Compounds, 1965The seeds ofSecurigera securidaca have been found to contain a cardiac glycoside securidaside, which is securigenin xyloglucoside. By stepwise enzymatic hydrolysis, securidaside can be decomposed into the monoxyloside securiside or into the aglycone and the sugar component.
V. V. Zamula +2 more
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1998
Saponins are compounds that possess a polycyclic aglycone moiety with either a steroid (typically C27) or triterpenoid (C30) structure attached to a carbohydrate unit (a monosac-charide or oligosaccharide chain) (Fig. 24.1). These sugar units are composed variously of pentoses, hexoses, or uronic acids.
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Saponins are compounds that possess a polycyclic aglycone moiety with either a steroid (typically C27) or triterpenoid (C30) structure attached to a carbohydrate unit (a monosac-charide or oligosaccharide chain) (Fig. 24.1). These sugar units are composed variously of pentoses, hexoses, or uronic acids.
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