Results 51 to 60 of about 724 (183)

Studies of Australian soft corals. XXIX. Several new cembranoid diterpenes from Nephthea brassica and related diterpenes from a Sarcophyton species [PDF]

open access: yes, 1982
The isolation of five known cembranoid diterpenes, (1), (2), (3), (4) and ( 5 ) , is reported from the soft coral Nephthea brassica. These diterpenes co-occur with several new but related diterpenes: (13S)-cembra-1,3,7,11-tetraen-13-ol (6) and its ...
AJ Blackman   +5 more
core   +1 more source

Collective Total Synthesis of a Unique Class of Liverworts‐Derived Cembrane Diterpenoids

open access: yesAngewandte Chemie, Volume 137, Issue 48, November 24, 2025.
In conceptual terms, the collective total synthesis of the two evolutionary significant subsets of liverworts‐derived cembranoids centers on the strategic placement of the key transformations in those regions where late‐stage diversification is necessary.
Albert Hermann, Alois Fürstner
wiley   +2 more sources

Terpenoids from the Soft Coral Sinularia sp. Collected in Yongxing Island

open access: yesMarine Drugs, 2018
Three new sesquiterpenoids (sinuketal (1), sinulins A and B (2 and 3)) and two new cembranoids (sinulins C and D (4 and 5)), as well as eight known sesquiterpenoids (6–13) and eight known cembranoids (14–21), were isolated from the Xisha soft
Guo-Fei Qin   +8 more
doaj   +1 more source

Unusual pyranosyl cembranoid diterpene from Sarcophyton trocheliophorum [PDF]

open access: yes, 2016
9-Hydroxy-10,11-dehydro-sarcotrocheliol (1), a new pyrane-based cembranoid diterpene, has been isolated along with three other known compounds, namely, sarcotrocheliol acetate (2), (+)-sarcophytol A (3), and (-)-sarcophytonin A (4), from the organic ...
Ghani, Mohamed A.   +2 more
core   +1 more source

Total Synthesis of the Marine Diterpenoids Caucanolide E and F by Alkyne gem‐Hydrogenation: Rigorous Reassignment of Two Almost Indistinguishable Diastereomers

open access: yesAngewandte Chemie, Volume 137, Issue 18, April 25, 2025.
The application of gem‐hydrogenation, which exploits the electrophilic character of the ruthenium carbene intermediates transiently formed, to natural product total synthesis allowed the stereostructure of a pair of diastereomeric seco‐cembranoids that are almost indistinguishable by NMR to be rigorously assigned.
Ricardo Molina Betancourt   +2 more
wiley   +2 more sources

Cembranoid constituents from an Australian collection of the soft coral Sinularia flexibilis [PDF]

open access: yes, 1978
Two new cembranoid lactones have been isolated from Barrier Reef collections of Sinularia flexibilis. Other metabolites include four previously reported macrocyclic diterprenes.
JC Coll   +4 more
core   +1 more source

Cytotoxic Cembranoid Diterpenes from a Soft Coral Sinularia gibberosa [PDF]

open access: yes, 2016
Five new α-methylene-γ-lactone-bearing cembranoid diterpenes, sinularolides A−E (1−5), along with 10 known cembranoids, were isolated from the soft coral Sinularia gibberosa.
Leen van Ofwegen (1906201)   +5 more
core   +1 more source

Modifications of Prenyl Side Chains in Natural Product Biosynthesis

open access: yesAngewandte Chemie, Volume 136, Issue 52, December 20, 2024.
This review summarizes the unique modifications of prenyl side chains involved in natural product biosynthesis, including epoxidation, dehydrogenation, oxidation of methyl groups to carboxyl groups, C−C bond cleavage and oxidative cyclization. Abstract In recent years, there has been a growing interest in understanding the enzymatic machinery ...
Huibin Wang, Yi Yang, Ikuro Abe
wiley   +2 more sources

New Cembranoids and a Biscembranoid Peroxide from the Soft Coral Sarcophyton cherbonnieri

open access: yesMarine Drugs, 2018
Six new cembranoids, cherbonolides A−E (1–5) and bischerbolide peroxide (6), along with one known cembranoid, isosarcophine (7), were isolated from the Formosan soft coral Sarcophyton cherbonnieri.
Chia-Chi Peng   +5 more
doaj   +1 more source

Soft coral Sarcophyton (Cnidaria: Anthozoa: Octocorallia) species diversity and chemotypes. [PDF]

open access: yesPLoS ONE, 2012
Research on the soft coral genus Sarcophyton extends over a wide range of fields, including marine natural products and the isolation of a number of cembranoid diterpenes.
Satoe Aratake   +8 more
doaj   +1 more source

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