Results 141 to 150 of about 205,156 (280)

Converting 1,1‐Bisborylalkanes into 1,2‐Bisborylalkanes Enabled by Iron Ligand‐to‐Metal Charge Transfer (LMCT) Photocatalysis

Angewandte Chemie, EarlyView.
1,2‐Bisborylalkanes are valuable intermediates for chemical synthesis as they could serve as a platform to generate value‐added products with two distinct functional groups at vicinal positions. A novel strategy to synthesize 1,2‐bisborylalkanes via Fe ligand‐to‐metal charge transfer (LMCT) photocatalysis is developed.
Zheye Zhang, George Chen, Michael Li, Carla Slebodnick, Diego Troya, Ming Chen   +5 more
wiley   +2 more sources

Synthesis, Electronic Properties, and X-ray Structural Characterization of Tetrarylbenzo[1,2-\u3cem\u3eb\u3c/em\u3e:4,5-\u3cem\u3eb\u3c/em\u3e′]difuran Cation Radicals [PDF]

, 2008
Electroactive tetraarylbenzo[1,2-b:4,5-b′]difuran (BDF) and model diarylbenzofuran derivatives are synthesized and their structures are established by X-ray crystallography.
Lindeman, Sergey V., Rathore, Rajendra, Shukla, Ruchi, Wadumethrige, Shriya   +3 more
core   +1 more source

DMS‐MaPseq and DREEM Analyses Implicate the Critical Role of RNA Structural Dynamics in Turnip Yellow Mosaic Virus Pathogenicity

Advanced Science, EarlyView.
RNA structural profiling of Turnip Yellow Mosaic Virus by DMS‐MaPseq and DREEM analyses uncover that viral genome‐wide RSS is highly complicated and heterogeneous, with alternative RSSs widely distributed across the genome. Notably, the viral 3’ tRNA‐like structure adopts alternative conformations in vivo.
Jiaying Zhu, Changhao Li, Chisimbily Onyia, Xindi Li, Xingxing Yan, Songxiao Zhong, Taerin Oh, Xiuren Zhang   +7 more
wiley   +1 more source

Nickel‐Catalyzed Enantioconvergent Arylation of Unactivated Cyclic Electrophiles: Asymmetric Synthesis of 3‐Substituted Pyrrolidines

Angewandte Chemie, EarlyView.
Metal‐catalyzed enantioconvergent substitutions of unactivated cyclic electrophiles by organometallic nucleophiles have not previously been reported. Herein, a chiral nickel catalyst is described that achieves this objective, coupling 3‐iodopyrrolidine derivatives with arylzinc nucleophiles.
Ting Hei Matthew Wong, Xiaoyu Tong, Gregory C. Fu   +2 more
wiley   +2 more sources

Coordination Polymers of Vanadium and Selected Metal Ions with N,O-Donor Schiff Base Ligands—Synthesis, Crystal Structure, and Application

Molecules
This review provides an overview of the synthesis, characterization and application of coordination polymers based on N,O-donor Schiff base ligands.
Dariusz Osypiuk, Agata Bartyzel, Beata Cristóvão   +2 more
doaj   +1 more source

Operando X‐Ray Diffraction and Total Scattering Characterization of Battery Materials: Not Just a Pretty Picture

Advanced Energy Materials, EarlyView.
This review focuses on operando studies of battery materials by X‐ray diffraction (XRD) and total X‐ray scattering (TXS). This work highlights potential pitfalls and identify best‐practices for operando studies and reviews some unusual experiments to illustrate how these methods can be applied beyond the evaluation of the early‐stage cycling mechanisms
Amalie Skurtveit, Eira Tiberg North, Izar Capel Berdiell, Wouter Van Beek, David S. Wragg, Alexey Y. Koposov   +5 more
wiley   +1 more source

Exploration of Ruthenium(II/III/VI)–Salen Complexes: From Synthesis to Functional Applications

Molecules
This review provides a comprehensive overview of recent advances in the synthesis, structural characterization, and applications of Ru(II), Ru(III), and Ru(VI) complexes, which bear tetradentate Schiff bases of salen type.
Beata Cristóvão, Dariusz Osypiuk, Agata Bartyzel   +2 more
doaj   +1 more source

Automatic Determination of Quasicrystalline Patterns from Microscopy Images

Advanced Intelligent Discovery, EarlyView.
This work introduces a user‐friendly machine learning tool to automatically extract and visualize quasicrystalline tiling patterns from atomically resolved microscopy images. It uses feature clustering, nearest‐neighbor analysis, and support vector machines. The method is broadly applicable to various quasicrystalline systems and is released as part of
Tano Kim Kender, Marco Corrias, Cesare Franchini   +2 more
wiley   +1 more source

Diazo Transfer From Nitrous Oxide Employing Phosphorus Ylides

Angewandte Chemie, EarlyView.
A phosphorus ylide‐mediated strategy achieves the direct fixation of nitrous oxide (N2O) to access diazo compounds, which after intra‐ or intermolecular trapping, afford N2‐containing organic building blocks. This approach provides an alternative to hazardous diazo‐transfer reagents and establishes N2O fixation as a sustainable methodology.
Jhen‐Kuei Yu, Jan Niclas Ludwig, Patrick Wolf Antoni, David Tymann, Max Martin Hansmann   +4 more
wiley   +2 more sources

Mixed‐Functionalized Acylgermanes Result in Wavelength‐Controlled Fragmentation

Angewandte Chemie, EarlyView.
Selective radical generation from PEG‐acylgermanes is achieved by controlling the used wavelength. Distinct aryl‐carbonyl units undergo wavelength‐dependent α‐cleavage, producing radicals with different reactivities. UV/Vis, TD‐DFT, and photo‐CIDNP spectroscopy confirm that small adjustments in light input directly dictate radical identity and ...
André Culum, Manfred Drusgala, Roland C. Fischer, Anne‐Marie Kelterer, Mario Leypold, Dmytro Neshchadin, Michael Haas   +6 more
wiley   +2 more sources