Results 71 to 80 of about 267,449 (298)
Crystal structure of (R)-2′-benzyloxy-[1,1′-binaphthalen]-2-yl trifluoromethanesulfonate
Acta Crystallographica Section E, 2014 In the title compound, C28H19F3O4S, a new 2′-benzyloxy (R)-BINOL derivative containing a trifluoromethanesulfonate group in the 2-position, the planes of the two naphthyl ring systems (r.m.s. deviations = 0.012 and 0.019 Å) are at an angle of 73.36 (2)°,
Rui M. B. Carrilho +4 more
doaj +1 more source
Chiral and Chirality Discrimination on Helical Polyacetylenes
Analytical Sciences, 2002 Synthesis and function of helical polyphenylacetylenes are briefly reviewed. Optically active helical polyphenylacetylenes were synthesized by polymerization of the corresponding chiral phenylacetylene monomers and their chiral recognition abilities were evaluated as a chiral stationary phase for HPLC.
openaire +2 more sources
Donor‐Engineered Chiral Indium–Salen Complexes for Tunable Circularly Polarized Luminescence
Advanced Functional Materials, EarlyView.Chiral indium–salen complexes bearing electronically and structurally diverse donor substituents are presented as modular main‐group luminophores exhibiting tunable blue‐to‐green circularly polarized luminescence. Donor engineering systematically controls frontier‐orbital distribution, intraligand charge transfer, and excited‐state relaxation ...
Haein Kim +14 more
wiley +1 more source
Phosphated cyclodextrins as water-soluble chiral NMR solvating agents for cationic compounds
Beilstein Journal of Organic Chemistry, 2017 The utility of phosphated α-, β- and γ-cyclodextrins as water-soluble chiral NMR solvating agents for cationic substrates is described. Two sets of phosphated cyclodextrins, one with degrees of substitution in the 2–6 range, the other with degrees of ...
Cira Mollings Puentes, Thomas J. Wenzel
doaj +1 more source
Acta Crystallographica Section E: Crystallographic Communications, 2015 The title compounds, catena-poly[[[bis[(R)-propane-1,2-diamine-κ2N,N′]copper(II)]-μ-cyanido-κ2N:C-[tris(cyanido-κC)(nitroso-κN)iron(III)]-μ-cyanido-κ2C:N] monohydrate], {[Cu(Lpn)2][Fe(CN)5(NO)]·H2O}n, (I), and poly[[hexa-μ-cyanido-κ12C:N-hexacyanido-κ6C ...
Olha Sereda, Helen Stoeckli-Evans
doaj +1 more source
Chiral-induced angular momentum radiation in single molecular junctions
, 2023 We study angular momentum radiation from electrically-biased chiral single molecular junctions using the nonequilibrium Green's function method. Using single and double helical chains as examples, we make connections between the ability of a chiral ...
Zu-Quan Zhang (9442580) +3 more
core +1 more source
Nanoconfinement‐Induced Second‐Harmonic Circular Dichroism via Chirality–Ferroelectric Coupling
Advanced Functional Materials, EarlyView.Nanoconfinement of a ferroelectric nematic liquid crystal within a chiral nanoporous sponge yields an enhanced second‐harmonic generation circular dichroism (|gSHG–CD| ≈ 1.1). Polarization‐resolved analysis suggests an additional magnetic‐dipole‐associated nonlinear contribution under nanoconfinement, highlighting chirality–ferroelectric coupling as a ...
Jae‐Jin Lee +5 more
wiley +1 more source
Inorganics, 2018 The present article reports the application of vibrational circular dichroism (VCD) and temperature-dependent electronic circular dichroism (ECD) methods to reveal the dynamical aspects of a star-burst tetranuclear metal complex with a labile central ...
Hisako Sato +2 more
doaj +1 more source
International Journal of Modern Physics A, 2002 An overview of the field of Chiral Lagrangians is given. This includes Chiral Perturbation Theory and resummations to extend it to higher energies, applications to the muon anomalous magnetic moment, ∊′/∊ and others.
openaire +2 more sources
Advanced Functional Materials, EarlyView.The analysis of optical eigenmodes in chiral liquid crystal with perpendicular or tilted helical axis, and their correspondence with the external medium, leads to an intuitive understanding of the angle and wavelength dependency of transmissive and reflective diffraction.
Ke Xu +5 more
wiley +1 more source