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Asymmetric Synthesis of Griffipavixanthone Employing a Chiral Phosphoric Acid-Catalyzed Cycloaddition. [PDF]
Smith MJ +6 more
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General and versatile synthesis of highly recyclable chiral phosphoric acid organocatalysts.
Maestro A, Ötvös SB, Auer G, Kappe CO.
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Recent Breakthroughs in Cyclizations of <i>Ortho</i>-Quinone Methides. [PDF]
Wang D +5 more
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Recent developments in the organocatalytic asymmetric cycloaddition/annulation reactions involving indolylmethanols. [PDF]
Patel A, Harshit, Iype E, Kumar I.
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Which Is the Actual Catalyst: Chiral Phosphoric Acid or Chiral Calcium Phosphate?
Angewandte Chemie - International Edition, 2010A highly enantioselective direct Mannich-type reaction of aldimines with a broad range of 1,3-dicarbonyl compounds with the use of a chiral phosphoric acid in the presence or absence of Ca(II) is demonstrated.
Manabu Hatano +2 more
exaly +3 more sources
Chiral phosphoric acids: a chiral lobby for enantioselective C–H activation
Chemical Communications, 2023Chiral phosphoric acids can interact in different ways with the substrate to induce chirality into the system. This review summarizes the use of chiral phosphoric acids in the exciting field of enantioselective C–H activation.
null Sumit +2 more
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Construction of Axially Chiral Styrenes Linking an Indole Moiety by Chiral Phosphoric Acid
The Journal of Organic Chemistry, 2022Herein we report a chiral phosphoric acid-catalyzed intermolecular C2 Friedel-Crafts alkylation reaction between ortho-alkynylnaphthols and various 3-substituted indoles, affording axially chiral alkenes with up to 93% yields (E/Z > 20:1) and up to 98% ee under mild reaction condition.
Wenxuan Zhang +3 more
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Reactions of Chiral Phosphorous Acid Diamides
Phosphorus, Sulfur, and Silicon and the Related Elements, 1993Abstract Chiral phosphorous acid diamides were prepared from chiral C2 diamines via the sequential addition of PCl3 and H2O. Alternatively, addition of PCI3 and hydrogen sulfide yieded the analogous thiophosphorous acid diamides. Deprotonation of the phosphorous acids under a variety of conditions gave the anions which reacted smoothly with alkyl ...
Vincent Blazis +3 more
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