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Asymmetric Synthesis of Griffipavixanthone Employing a Chiral Phosphoric Acid-Catalyzed Cycloaddition. [PDF]

open access: yesJ Am Chem Soc, 2019
Smith MJ   +6 more
europepmc   +1 more source
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Chiral phosphoric acids: a chiral lobby for enantioselective C–H activation

Chemical Communications, 2023
Chiral phosphoric acids can interact in different ways with the substrate to induce chirality into the system. This review summarizes the use of chiral phosphoric acids in the exciting field of enantioselective C–H activation.
null Sumit   +2 more
openaire   +2 more sources

Which Is the Actual Catalyst: Chiral Phosphoric Acid or Chiral Calcium Phosphate?

Angewandte Chemie - International Edition, 2010
A highly enantioselective direct Mannich-type reaction of aldimines with a broad range of 1,3-dicarbonyl compounds with the use of a chiral phosphoric acid in the presence or absence of Ca(II) is demonstrated.
Manabu Hatano, Kazuaki Ishihara
exaly   +3 more sources

Reactions of Chiral Phosphorous Acid Diamides

Phosphorus, Sulfur, and Silicon and the Related Elements, 1993
Abstract Chiral phosphorous acid diamides were prepared from chiral C2 diamines via the sequential addition of PCl3 and H2O. Alternatively, addition of PCI3 and hydrogen sulfide yieded the analogous thiophosphorous acid diamides. Deprotonation of the phosphorous acids under a variety of conditions gave the anions which reacted smoothly with alkyl ...
Vincent Blazis   +3 more
openaire   +1 more source

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