Results 171 to 180 of about 4,737 (260)
Origin of Single-Molecule Reaction Chirality. [PDF]
Yang C +10 more
europepmc +1 more source
Stokes‐Based 3D Polarimetric Analysis of Dipolar Near‐Fields
Characterizing the near‐field polarization of dipolar emitters is of growing importance in nanophotonics, since many subwavelength systems resemble their emission. In this work, we apply the 3D Stokes formalism and its intrinsic reference frame to analyze the polarization properties of various dipole emitters from the near‐ to the far‐field, allowing a
Guillermo Serrera +3 more
wiley +1 more source
Systematic anion engineering from halide to pseudohalide (Cl− → Br− → I− → NCS−) in a family of cadmium(II)‐based organic‐inorganic hybrids drives a progressive transition from centrosymmetric to polar structure, depresses melting point, reduces fragility index, and enhances glass‐forming ability, ultimately affording a polar hybrid glass‐ceramic with ...
Ding‐Chong Han +11 more
wiley +1 more source
Chiral Nonlinear Enhancement with Opposite Circular Dichroism Empowered by Dual Bound States in the Continuum. [PDF]
Liu X, Wang L, Meng H.
europepmc +1 more source
Photochemistry of N‐Substituted, N′‐Tosyl Diphenyl Sulfondiimines
The irradiation of N‐substituted, N′‐tosyl diphenyl sulfondiimines with UV light induces the sequential photorelease of two different nitrenes. ABSTRACT Sulfondiimines are an emerging sulfur(VI) functional group with increasing use in synthesis and medicinal chemistry, yet their photochemical behavior has remained largely unexplored.
Bashar Aziz +3 more
wiley +1 more source
Superconductivity in kagome metals due to soft loop-current fluctuations. [PDF]
Schultz DJ +5 more
europepmc +1 more source
Hydrocarbon α,ω‐dienes are mainly produced from steam‐cracking derivatives, but high costs, complexity, and environmental impact limit their use. This review highlights sustainable paths from biomass and plastic upcycling, and surveys catalytic transformations into carbocycles and specialty polymers, emphasizing their role as modular building blocks ...
Rosa Villaccio, Giuseppe Leone
wiley +1 more source
Enzyme‐Like Synthetic Cleft for Light‐Driven Water‐Oxidation Catalysis Via an Oxide Relay Pathway
A carboxylic acid group introduced into the second coordination sphere of a Ru(bda) water oxidation catalyst forms a defined hydrogen bond within the catalytic cleft. This interaction locks the group in place and enables an intramolecular oxide relay pathway between Ru(V)═O and the carboxylate group, providing a distinct and efficient route for O─O ...
Daniel A. P. Friedewald +7 more
wiley +2 more sources
Vertical chiral emission from an intrinsically achiral metasurface enabled with anisotropic continuum. [PDF]
Sun Y +9 more
europepmc +1 more source
A planar chiral plasmonic nanoantenna is shown to translate the changing handedness of circularly polarized excitation into deterministic switching of a nanoscale hot spot with maximal dissymmetry and complete modulation depth. Coupling an achiral quantum emitter to the nanogap simultaneously enables circularly polarized emission of near‐maximal purity,
Abhik Chakraborty +7 more
wiley +1 more source

