Results 111 to 120 of about 60,162 (254)

A NEAT Approach to Evolving Neural‐Network‐Based Optimization of Chiral Photonic Metasurfaces: Application of a NeuroEvolution‐of‐Augmenting‐Topologies Pipeline

Advanced Intelligent Systems, EarlyView.
Neuro‐evolution can boost machine‐learning optimization of chiral metasurfaces. By integrating the NEAT algorithm into a deep‐learning framework, we enable the efficient design of visible‐spectrum chiroptical responses. NEAT autonomously evolves neural‐network architectures and weights, reducing manual tuning.
Davide Filippozzi, Arash Rahimi‐Iman
wiley   +1 more source

Divergent Synthesis of Möbius and Hückel N‐Heterocycloarenes From a Common Macrocyclic Backbone

Angewandte Chemie, EarlyView.
In the divergent synthesis of Möbius and Hückel N‐heterocycloarenes from a common macrocyclic precursor, the annulation reaction dictates topology: Scholl reaction gives Möbius topology, while InCl3‐mediated alkyne annulation gives Hückel topology. The Möbius N‐heterocycloarene is unevenly contorted as revealed by crystal structure, and the Hückel N ...
Han Chen, Huishu Ma, Daiyue Yang, Zheng Zhou, Xiao Chen, Zhifeng Huang, Qian Miao   +6 more
wiley   +2 more sources

Circular Dichroism

YAKUGAKU ZASSHI, 1964
openaire   +3 more sources

Nanostructured Deep Eutectic Systems in Healthcare: From Bioactive Solvents to Intelligent Biointerfaces, Wearables, and AI‐Driven Design

Advanced NanoBiomed Research, EarlyView.
Beyond the green solvent paradigm, this review redefines Deep Eutectic Systems (DES) as programmable supramolecular nanoassemblies. We survey their biomedical convergence: stabilizing thermolabile mRNA to enable cold chain‐free logistics, reshaping transdermal microneedle delivery, enabling long‐term wearables via eutectogels, and utilizing Generative ...
Jeesu Moon, Min Seo Kim, Jae‐Seung Lee
wiley   +1 more source

Protonation‐Gated Orthogonal Control of Highly Efficient Molecular Motors With Broad Visible‐Light Responsiveness

Angewandte Chemie, EarlyView.
Reversible protonation gates coumarin‐based overcrowded‐alkene molecular motors by dynamically reshaping their conjugation topology. This strategy enables efficient, near‐quantitative unidirectional photoisomerization from blue–green to red‐shifted visible light up to 600 nm, while preserving motor function and allowing orthogonal light, heat, and acid/
Jinghao Wang, Alexander Ryabchun, Ben L. Feringa   +2 more
wiley   +2 more sources

Oxygen‐Tolerant Photo‐Induced Miniaturized Accelerated Atom Transfer Radical Polymerization (OPTIMA‐ATRP) for High‐Throughput Synthesis of Polymer Bioconjugates

Angewandte Chemie, EarlyView.
Oxygen‐tolerant photo‐induced miniaturized accelerated atom transfer radical polymerization (OPTIMA‐ATRP) in water was developed for the polymerization of hydrophilic (meth)acrylate monomers under ambient or sub‐ambient (4°C) temperature and atmospheric conditions, without prior degassing, in less than 10 min, at an ultra‐small scale (< 50 µL) in ...
Arman Moini Jazani, Roksana Wygoda, Hironobu Murata, Mozhdeh Madadi, Grzegorz Przesławski, Krzysztof Matyjaszewski   +5 more
wiley   +2 more sources

Spectroscopy and Conformer-Selective Photoelectron Circular Dichroism of Chiral Molecules. [PDF]

Chem Asian J
Nahon L, Zehnacker A.
europepmc   +1 more source

Electrochemically Triggered Supramolecular Polymerization Under Kinetic Control

Angewandte Chemie, EarlyView.
Chemical and electrochemical stimuli enable controlled supramolecular polymerization of perylene diimide–histidine (PDI–His). Redox processes mediate the transformation of kinetically trapped aggregates into thermodynamically stable nanofibers, thereby supporting seeded growth. This approach provides a strategy for regulating self‐assembly pathways and
Eun Gyu Lee, Jeongse Yun, Hyoung Wook Kang, Daeun Jung, Seung‐Ryong Kwon, Jong Hwa Jung, Sung Ho Jung   +6 more
wiley   +2 more sources

Guidelines for Comparing Circular Dichroism Spectroscopy and Molecular Dynamics Simulations for Biomolecules. [PDF]

Chemphyschem
Campus C, Roldo M, Chen CH, Hadianamrei R, Gavini E, Jorgensen C.   +5 more
europepmc   +1 more source

Induction and Stabilization of Peptide Alpha‐Helices on Silica Nanoparticles

Angewandte Chemie, EarlyView.
Covalent docking turns silica nanoparticles (SNPs) into α‐helix‐stabilizing surfaces. Dynamic imine formation allows peptides with lysine residues aligned on one helical face to adapt to the surface before reduction locks the structure in place, while preserving the opposite face for functional recognition.
Fidel Lozano‐Elena, Seyed Amirabbas Nazemi, Patrick Shahgaldian, Sebastian Wendeborn   +3 more
wiley   +2 more sources