Results 91 to 100 of about 277,971 (217)

Cobalt-ligand bond lengths from crystallography, EXAFS, and DFT.

open access: yes, 2016
Cobalt-ligand bond lengths from crystallography, EXAFS, and DFT.
Stefan Mebs (1455724)   +6 more
core   +1 more source

Nonthermal Plasma–Enabled Cascade N2 Activation and Electroreduction

open access: yesEcoEnergy, EarlyView.
Integrating plasma‐assisted NOx synthesis with subsequent electrochemical reduction enables the sustainable synthesis of high‐value N‐containing chemicals under ambient conditions. ABSTRACT The development of sustainable nitrogen fixation technologies operating under ambient conditions is critical for reducing the energy intensity and carbon footprint ...
Shijia Li, Wei Gao, Ziyun Wang
wiley   +1 more source

Cobalt-Catalyzed Cyclotrimerization of Alkynes in Aqueous Solution

open access: yes, 2016
Cobalt-Catalyzed Cyclotrimerization of Alkynes in Aqueous ...
Bruce E. Eaton (235791)   +2 more
core   +1 more source

Multidimensional Engineering Enabling Rate‐Matched C−N Coupling for Efficient Organonitrogen Electrosynthesis

open access: yesEcoEnergy, EarlyView.
This review introduces rate matching as a unifying design principle for efficient electrochemical C−N coupling and highlights multidimensional engineering of catalysts, interfaces, and reactors to synchronize the generation of carbon‐ and nitrogen‐containing intermediates, balance their surface coverages, maximize C−N bond formation, and enable ...
Kaixing Cai   +4 more
wiley   +1 more source

π‐Extended Silyl Enolates as Emerging Platforms in Radical Chemistry

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
This review covers the emerging role of π‐extended silyl polyenol ethers in radical chemistry. It highlights their versatile roles as electron‐rich SOMOphiles, silyl radical cation precursors, and nucleophilic partners in radical–polar crossover manifolds, while considering recent advances in photoredox catalysis, electrochemistry, and transition metal‐
Debora Guazzetti   +3 more
wiley   +1 more source

Bifunctional Electrocatalysts in Rechargeable Lithium‐Gas Batteries: Material Evolution and Mechanistic Insights from Metal‐Free Carbons to Carbon‐Supported Single‐Atom Sites

open access: yesSmall, EarlyView.
This review charts the material evolution of bifunctional electrocatalysts for rechargeable lithium‐gas batteries. It highlights the journey from heteroatom‐doped, metal‐free carbon architectures to precision‐engineered carbon‐supported single‐atom sites. The discussion focuses on mechanistic insights into how these catalysts govern reversible O2, CO2,
Daming Ren   +5 more
wiley   +1 more source

Downsize Effect on Photocatalytic Syngas Production of a 2D Metal Organic Framework—Tuning the Selectivity From HER to CO2RR via Dimensional Modulation and Mechanical Exfoliation of 2D Metal‐Organic Layers

open access: yesSmall Methods, EarlyView.
A cobalt(II) 2D MOF (2D) has been downsized by covalent bond breaking to form a 1D MOF (1D) and by sonication, to form a 2D exfoliated MOF (2D‐ex). Photocatalytic CO2 reduction shows that 2D and 1D lead to H2‐enriched syngas, whereas 2D‐ex leads to CO‐enriched syngas.
Rajat Saha   +10 more
wiley   +1 more source

Criteria for controlling occupational exposure to cobalt [PDF]

open access: yes
"The toxic effects of cobalt (7440484) and the extent of occupational exposures are reviewed in a NIOSH criteria document. The health effects of cobalt exposure on workers in various industries are described, and the findings of various experimental ...

core  

Distinct Skin Penetration and Immune Responses to Ionic and Nanoparticulate Cobalt in Allergic Contact Dermatitis

open access: yesAllergy, EarlyView.
Cobalt chloride (CoCl2) and cobalt nanoparticles (CoNPs) induce a shared, severity‐dependent inflammatory response in cobalt‐sensitized skin characterized by activation of interferon signaling, inflammatory pathways (TNF/NF‐κβ, IL6‐STAT3), apoptosis/UPR, cell cycle programs, and glycolysis.
Paulina Werner   +8 more
wiley   +1 more source

Borylcyclopropanes: Synthetic Strategies and Applications

open access: yesAngewandte Chemie, Volume 138, Issue 37, 7 September 2026.
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley   +2 more sources

Home - About - Disclaimer - Privacy