Results 101 to 110 of about 20,135 (183)
Investigation of the composition of the Luna 16 lunar sample [PDF]
The concentrations of aluminum, manganese, sodium, chromium, iron, cobalt, and 12 rare earth elements were determined by neutron activation analysis using slow neutrons. Oxygen and silicon were determined using a fast neutron generator.
Bakos, L. +9 more
core +1 more source
An in‐depth survey dealing with the aromatic C—H bond functionalization of biologically‐relevant scaffolds featuring the indolinone and indanone core is discussed as they are unique aromatic scaffolds that are 1,2‐doubly fused with small five‐membered rings.
Vanessa Delahaye +3 more
wiley +1 more source
Catalytic Autoxidation for Depolymerization of Multilayer Plastic Films
Catalytic autoxidation using a Co/Mn/Br catalyst system depolymerizes diverse polymers in multilayer plastic films, generating oxygenated small molecules such as dicarboxylic acids. The method tolerates additives and disrupters and converts up to 48 mol% polymer carbon into soluble products, enabling chemical recycling of complex plastic waste ...
Ciaran W. Lahive +16 more
wiley +1 more source
Electrochemical CO2RR is a key technology for converting CO2 into chemicals, but there remains a gap between “laboratory science” and “engineering practice” in current research. This review establishes a multi‐scale research framework, encompassing atomic‐level characterization, microenvironment regulation, external field‐assisted optimization, and AI ...
Ping Hong +3 more
wiley +1 more source
A photon phreak digs the LDEF happening [PDF]
A year ago at the First Long Duration Exposure Facility (LDEF) Post-Retrieval Symposium, detailed measurements on trunnion sections, as well as results from 'intentional' samples (Co, Ni, In, Ta, and V) and spacecraft parts were reported. For this year's
Hurley, Donna L., Smith, Alan R.
core +1 more source
Oxygen Evolution Reaction Catalysts for Acidic‐Media CO2 Electrolyzers
Acidic‐media CO2 electroreduction (CO2R) could decarbonize chemical production, despite relying on rare‐earth elements for anodic oxygen evolution reaction (OER). Transferring the learnings from mature sister technologies (water electrolysis) could accelerate technological development.
Mingcheng Huang, Adnan Ozden
wiley +1 more source
Ligand architecture and secondary‐sphere effects in a well‐defined cobalt(IV)–oxo complex
A well‐defined cobalt(IV)–oxo complex supported by a neutral tetraazamacrocyclic ligand is generated and fully characterized. The cobalt(IV)–oxo species exhibits electrophilic oxygen‐atom and hydrogen‐atom transfer reactivity, strongly modulated by protonation and secondary coordination sphere effects, providing new insight into structure–reactivity ...
Ying Xing +3 more
wiley +1 more source
Rhodium(II) Porphyrins: Unusual Transition States and the Quest for Catalytic Turnover
Rh(II) porphyrin metalloradicals can homolytically cleave strong bonds via intriguing multi‐component transition states. Their use in catalysis has been hampered, however, by a tendency to form thermodynamically stable Rh(III) intermediates. This Concept article highlights different strategies that can unlock the latent potential of Rh(II) porphyrin ...
Zihang Qiu, Constanze N. Neumann
wiley +1 more source
Hydrocarbon fuels are widely used because of their high energy density, convenience of use and storage, and beneficial cost structure. Concerns about nonrenewable sources and environmental impact have prompted research into their production. Here, linear hydrocarbons with chain lengths from 1 to 31 carbon atoms were formed from CO2 and water using a ...
Mahesh J. Thalavitiya Acharige +6 more
wiley +1 more source
Recent Advances in Carbonyl–Olefin and Carbonyl–Alkyne Metathesis Reactions
Carbonyl–olefin and carbonyl–alkyne metathesis enable atom‐economic C–C bond formation beyond classical olefin metathesis. This review highlights recent advances in photochemical, Lewis‐acid, Brønsted‐acid, and organocatalytic strategies, mechanistic insights, and synthetic applications, showcasing carbonyl metathesis as a versatile platform for modern
Komal Kalonia +2 more
wiley +1 more source

