Results 81 to 90 of about 277,971 (217)

Unlocking Thermodynamic‐Kinetic Synergy via Rh/Co Dual Sites and Ordered Interfacial Hydrogen‐Bond Network for Efficient Biomass Electrooxidation

open access: yesCarbon Energy, EarlyView.
An amorphous RhOx‐decorated cobalt‐deficient Co3O4 catalyst is designed for efficient HMF electro‐oxidation to FDCA. This design enables Rh/Co dual sites for enhanced HMF/OH− adsorption thermodynamics while independently ordering interfacial water into a connected hydrogen‐bond network that accelerates proton transfer kinetics, delivering outstanding ...
Dezhao Zhang   +10 more
wiley   +1 more source

Dual‐Function Electrocatalysis: Simultaneous Wastewater Remediation and Hydrogen Evolution—A Comprehensive Review

open access: yesCarbon Energy, EarlyView.
Replacing the oxygen evolution reaction with the electro‐oxidation of pollutants and waste streams offers an energy‐efficient route for simultaneous hydrogen production and pollutant remediation. This review summarizes the reaction mechanisms, catalyst design principles, and emerging paired‐electrolysis strategies that govern activity, selectivity ...
Safa Al‐Yahyaey   +4 more
wiley   +1 more source

Rationales for the Choice of Metals for Super‐Reduced Biological Metal Centers: Cobalt in Cobalamin Versus Nickel in F430

open access: yesChemistry – A European Journal, EarlyView.
DFT calculations on porphyrin, corrin, and corphin complexes of cobalt, rhodium, iron, manganese, or nickel, and QM/MM calculations on enzyme models, explore the factors controlling the availably of super‐reduced metal(I) states. True metal(I) states are seen in corrin only for cobalt, in corphin only for nickel, and not at all in porphyrin.
Radu‐Ioan Onija   +3 more
wiley   +1 more source

Four Station Knee Simulator Wear Testing Comparing Titanium Niobium Nitride with Cobalt Chrome [PDF]

open access: yes, 2013
A new non-destructive method was applied in order to assess bone integrity. The method is based on measurement of bHypersensitivity to an orthopaedic implant was first published in 1966 and since then, in sensitive patients, is known to cause serious ...
Blunn GW, MRM
core  

Experimental methods in chemical engineering: Temperature‐programmed oxidation—TPO

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Temperature‐programmed oxidation (TPO) probes the oxidative capacity and redox properties of solid materials—catalysts, metal oxides, perovskites, and carbonaceous deposits. It identifies coke type, distribution, and reactivity. TPO instruments pass an oxidizing gas (diluted O2$$ {\mathrm{O}}_2 $$, air, or less commonly N2O$$ {\mathrm{N}}_2 ...
Gholamreza Roohollahi   +7 more
wiley   +1 more source

Cobalt-Catalyzed Alkoxycarbonylation of Epoxides to β‑Hydroxyesters

open access: yes, 2019
Herein, we developed a new and practical catalytic system for the carbonylative synthesis of β-hydroxyesters. By using simple, cheap, and air-stable cobalt­(II) bromide as the catalyst, combined with pyrazole and catalytic amount of manganese, active ...
Jian-Xing Xu   +3 more
core   +1 more source

Sustainable Hydrogen Production by Glycerol and Monosaccharides Catalytic Acceptorless Dehydrogenation (AD) in Homogeneous Phase

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
Sustainable hydrogen production can be obtained from hydogen‐rich biomass‐derived organic molecules through Acceptorless Dehydrogenation (AD) reactions. Glycerol and sugars are available in large quantities from industry and can be successfully used as substrates in AD protocols, in the presence of tailored, selective, easily tunable and thermally ...
Sylwia Kostera, Luca Gonsalvi
wiley   +1 more source

Polyoxometalates in Photocatalytic CO2 Reduction: Multielectron Redox Regulation Across Molecular and Hybrid Architectures

open access: yesEcoEnergy, EarlyView.
This review focuses on multielectron redox regulation across molecular and hybrid architectures for photocatalytic CO2 reduction, covering intrinsic POM photocatalysts, photosensitizer‐assisted assemblies, POM–metal–organic complexes, and POM‐integrated semiconductors and MOF/COF heterostructures to link structural motifs with charge transport, product
Bonan Li, Xiaowen Ruan, Sai Kishore Ravi
wiley   +1 more source

Cobalt-Catalyzed Selective Hydrogenation of Nitriles to Secondary Imines

open access: yes, 2018
The first example of cobalt-catalyzed selective hydrogenation of nitriles to secondary imines is reported. The results demonstrate the significantly different selectivity compared with the previously reported cobalt catalytic system during the nitrile ...
Sandeep Suryabhan Gholap (5807666)   +13 more
core   +1 more source

Synergistic Optical Strategies for Enhanced Perovskite Photocatalytic Activity

open access: yesEcoEnergy, EarlyView.
This review addresses bottlenecks of halide perovskites' photoactive components from an optics‐driven perspective and organizes recent advances into four interconnected design principles. This review provides practical design principles and outlines key directions toward efficient, selective, and stable perovskite photocatalysis for CO2 reduction ...
Jaemin Jeong   +3 more
wiley   +1 more source

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