Multiscale simulations reveal an inversed cation size effect (Li+ > Na+ > K+ > Cs+) in immobilized cobalt phthalocyanine ‐catalyzed CO2 reduction to methanol. Smaller cations like Li+ effectively stabilize the rate‐limiting proton‐transfer transition state through intimate coordination, whereas their disruption of the local hydrogen‐bond network ...
Ke Ye +3 more
wiley +2 more sources
Terminal groups on Cu porphyrins modulate the electronic states of single‐atom Cu centers through a long‐range electronic effect, without altering the Cu coordination geometry. Meanwhile, a multi‐descriptor framework is established that incorporates porphyrin regulation, hybrid catalyst properties, and CO2 photoreduction capabilities.
Yi Zhang +13 more
wiley +1 more source
Biodegradable Zn‐Based Implants: Progress, Challenges, and Pathways toward Clinical Translation
Exploring biodegradable Zn‐based implants offers a promising pathway to next‐generation biomedical devices with balanced degradation and biocompatibility. A comprehensive overview of biodegradable Zn‐based implants, covering their biological significance, material design principles, and advanced engineering strategies is provided.
Panfeng Zhao +10 more
wiley +1 more source
Isotopic Fractionation and Masking Effects during Biotransformation of Chlorinated Ethanes. [PDF]
Phillips E +8 more
europepmc +1 more source
Recent production rates of cosmogenic nuclides in the igneous rocks of Jezero crater floor, Mars. [PDF]
Zorzano M- +2 more
europepmc +1 more source
129Xe Nuclear Magnetic Resonance Spectroscopy of Metal–Organic Frameworks
129Xe NMR spectroscopy is a powerful technique to study porous materials. Properties such as pore sizes, pore connectivity, and dynamic switching processes associated with adsorption can be investigated. With its inertness and highly polarizable electron cloud, Xe allows for sensitive monitoring of small changes in the surface chemistry of materials ...
Tobias Bode, Eike Brunner
wiley +1 more source
Monte Carlo prediction and experimental characterisation of long-lived waste byproducts arising from cyclotron production of zirconium-89 utilising a commercially available yttrium foil. [PDF]
Chacon A +7 more
europepmc +1 more source
Recent Advances in Benzannulation Approaches to Aromatic Frameworks
This review summarizes benzannulation strategies reported over the past 5 years, highlighting recent advances that enable efficient access to structurally diverse and highly substituted arenes through both transition‐metal‐catalyzed and metal‐free approaches.
Heeeun Kim, Yonghoon Kwon
wiley +1 more source
Chemical Kinetic and Mechanistic Investigation of Cobalt and Manganese Recovery from Aqueous Solutions by Ozone Oxidative Precipitation. [PDF]
Shekarian Y, Rezaee M, Pisupati SV.
europepmc +1 more source
Steric modulation of nitric oxide photodissociation kinetics in iron–nitrosyl complexes
Subtle steric modification within a pyridinophane ligand framework modulates nitric oxide photodissociation kinetics in iron–nitrosyl complexes. Structural and electrochemical analyses reveal that modest ligand‐environment variations are reflected in differences in NO photoreactivity.
Jisu Choe, Jaeheung Cho
wiley +1 more source

