Results 151 to 160 of about 6,725,229 (312)

Regio‐ and Diastereoselective C–C Silylation of Cyclopropyl Acetates Harnessing Fluorinated Poly(pyridyl)Borate Rhodium Catalysts

Chemistry – A European Journal, EarlyView.
Fluorinated poly(pyridyl)borates have been utilized to stabilize rhodium‐diene complexes and as supporting ligands in rhodium‐catalyzed redox‐neutral C–C silylation of cyclopropyl acetates, producing silicon‐containing heterocyclic products, dioxasilolanes.
Vo Quang Huy Phan, Suman Das Adhikary, Junha Jeon, H. V. Rasika Dias   +3 more
wiley   +1 more source

Strong Implications From Small Deviations in Labeling Patterns: The Mechanism of Burkholderia gladioli Pacifigorgiadiene Synthase

Chemistry – A European Journal, EarlyView.
The mechanism of pacifigorgiadiene synthase from Burkholderia gladioli was investigated through isotopic labeling experiments and DFT calculations. The results revealed an unexpected labeling pattern which appeared to be different in the main and the side products, requiring unprecedented mechanistic explanations, including a “break‐flip‐cyclise ...
Zhiyong Yin, Zhehui Hu, Xiyuan He, Juan Xu, Bernd Goldfuss, Jeroen S. Dickschat, Guangkai Bian   +6 more
wiley   +1 more source

Mononuclear Molybdenum and Tungsten Phosphine Complexes for Catalytic Ammonia Synthesis: Development of the pentaPod Concept

ChemPhysChem, EarlyView.
The pentaPod (P5) concept unites tridentate and tripodal fragments to form molybdenum and tungsten catalytic Chatt‐type complexes for N2‐to‐NH3 reduction. Two pentaPod ligands, P5Me and P5Pln, are available with either two dimethylphosphine or phospholano (Pln) groups. The complexes enable the investigation of reactivity differences in N2 reduction and,
Anna‐Marlene Vogt, Tobias Adrian Engesser, Jan Krahmer, Felix Tuczek   +3 more
wiley   +1 more source

Deep Eutectic Solvents Formed by Complex Hydrides: A New Class of Hydrogen-Rich Liquid. [PDF]

Adv Mater
Lombardo L, Nishiguchi T, Pham THM, Züttel A, Horike S.   +4 more
europepmc   +1 more source

Using Additives to Control the Decomposition Temperature of Sodium Borohydride [PDF]

, 2020
Jubert Tomasso, Camille, Mattox, Tracy M, Pham, Anne L, Urban, Jeffrey J   +3 more
core  

Sustainable Hydrogen Production by Glycerol and Monosaccharides Catalytic Acceptorless Dehydrogenation (AD) in Homogeneous Phase

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
Sustainable hydrogen production can be obtained from hydogen‐rich biomass‐derived organic molecules through Acceptorless Dehydrogenation (AD) reactions. Glycerol and sugars are available in large quantities from industry and can be successfully used as substrates in AD protocols, in the presence of tailored, selective, easily tunable and thermally ...
Sylwia Kostera, Luca Gonsalvi
wiley   +1 more source

Sulfur‐Rich μ‐O Diiron Catalyst for Electrochemical Hydrogen Production

European Journal of Inorganic Chemistry, EarlyView.
A diferric μ‐oxido complex supported by a sulfur‐rich scaffold acts as a proton‐reduction electrocatalyst for H2 production via a μ‐hydroxido species. An aminodithiophenolate scaffold with an NS2 donor set supports diiron complex formation. The diferrous precursor activates O2, giving rise to a diferric μ‐oxido species, which acts as a proton‐reduction
Hugo C. Hernández‐Toledo, Víctor E. López‐Guerrero, Alexander Mondragón‐Díaz, Elvis Robles‐Marín, Marcos Flores‐Alamo, José Manuel Guevara‐Vela, Tomás Rocha‐Rinza, Ivan Castillo   +7 more
wiley   +1 more source

Recent Developments in the Field of Air‐Stable Nickel(0) Precatalysts for Cross‐Coupling Reactions

European Journal of Inorganic Chemistry, EarlyView.
The development of bench‐stable Ni(0) sources aims to replace air‐sensitive [Ni(COD)2] (cod = cycloocta‐1,5‐diene) with easy‐to‐handle alternatives. Through a targeted ligand design, using electron‐deficient dienes, carbenes, and fluorophosphines, researchers have achieved air‐ and moisture‐tolerant complexes that show high catalytic activity in cross ...
Franziska Flecken, Schirin Hanf
wiley   +1 more source

Recent advances in improving performances of the lightweight complex hydrides Li-Mg-N-H system

, 2017
Bao-Hua Zhang, Ying Wu
semanticscholar   +1 more source

Dinuclear Rhodium(I)–N‐Heterocyclic Carbene Complexes as Alkyne Hydropyridonation Catalysts

European Journal of Inorganic Chemistry, EarlyView.
Catalyst Improvement by NHC tuning: A series of new RhI–NHC dinuclear complexes has been revealed as efficient alkyne hydropyridonation catalysts. 333053IMes complex displays the highest reactivity of the series, suggesting that a moderate steric demand combined with balanced σ‐donation facilitates precatalyst activation and substrate exchange.
Belinda Español‐Sánchez, Mert Olgun Karataş, Andrea Di Giuseppe, Ulugbek Togaev, Vincenzo Passarelli, Luis A. Oro, Jesús J. Pérez‐Torrente, Ricardo Castarlenas   +7 more
wiley   +1 more source