Synthesis of Sulfur Heterocycles by Palladium‐Catalyzed Cyclization
In spite of the well‐known palladium thiophilicity, sulfur‐containing acyclic substrates may efficiently undergo several different kinds of palladium‐catalyzed cyclization processes leading to highly important sulfur heterocycles in one synthetic step. Advances in this challenging and stimulating field of research are presented in this review.
Bartolo Gabriele
wiley +1 more source
Influence of B'-site vacancy on hydrogen storage, structural, elastic, thermodynamic and optoelectronic attributes of potassium based double perovskite K<sub>2</sub>LiAlH<sub>6</sub>hydride for green energy applications. [PDF]
Murtaza H +7 more
europepmc +1 more source
Organic azides are readily reduced to amines under mild conditions by ammonia borane complex, catalyzed by a low loading level of reusable Au nanoparticles supported on TiO2. We present the first protocol for the chemoselective reduction of organic azides to amines by ammonia borane complex. In the presence of a low catalytic amount of Au nanoparticles
Elisavet‐Maria Zantioti‐Chatzouda +5 more
wiley +1 more source
Thermal Management in Metal Hydride Hydrogen Storage Reactors: Mechanisms, Architectures, and Design Trade-Offs. [PDF]
Hou Q +8 more
europepmc +1 more source
Silyl Rearrangements in Gold‐Catalyzed Transformations
The synergy between the exceptional ability of gold catalysts to activate unsaturated substrates and the inherent tendency of organosilicon reagents to undergo silyl‐group rearrangements has unlocked a range of novel transformations, enabling access to otherwise challenging molecular architectures.
Patricia García‐Martínez +1 more
wiley +1 more source
Probing Hydrogen Activation in a Dimetal Dihydride Complex by Symmetric Exchange with Parahydrogen. [PDF]
Matz JF +8 more
europepmc +1 more source
A sustainable, ligand‐free Pd‐catalyzed borrowing hydrogen protocol in a biodegradable hydrophobic natural deep eutectic solvent (NADES) (thymol/DL‐menthol) enables the N‐alkylation of primary amines with benzylic alcohols under mild, aerobic conditions, allowing efficient reuse of both catalyst and solvent for seven consecutive cycles. The hydrophobic
Maryam Saeb +5 more
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Flash Communication: Well-Defined Paramagnetic Polyhydrido-Bridged Iron-Iridium Clusters. [PDF]
Dubrawski Z +5 more
europepmc +1 more source
Fe‐Ni2P/NiMoO4 heterostructure delivers bifunctional performance for both HER and OER in alkaline solution. During OER, Fe doping suppresses LOM through electronic modulation, which consequently leads to an AEM route with enhanced OH* adsorption. Furthermore, the elimination of oxygen‐loss pathways ensures the structural integrity of the Fe‐Ni2P ...
Wenxin Jin +10 more
wiley +1 more source
Deep learning generative model for conditional crystal structure prediction of sodium amide. [PDF]
Guan R, Liu A, Song Y.
europepmc +1 more source

