Copper-catalyzed O-alkenylation of phosphonates
Copper catalysis allows the direct oxygen alkenylation of dialkyl phosphonates with alkenyl(aryl)iodonium salts with selective transfer of the alkenyl group.
Nuria Vázquez-Galiñanes +3 more
doaj +1 more source
Evidence for product-specific active sites on oxide-derived Cu catalysts for electrochemical CO2 reduction [PDF]
Carbon dioxide electroreduction in aqueous media using Cu catalysts can generate many different C2 and C3 products, which leads to the question whether all products are generated from the same types of active sites or if product-specific active sites are
Ager, JW, Lum, Y
core
Enzymatic functionalization of carbon-hydrogen bonds [PDF]
The development of new catalytic methods to functionalize carbon–hydrogen (C–H) bonds continues to progress at a rapid pace due to the significant economic and environmental benefits of these transformations over traditional synthetic methods.
Arnold, Frances H. +2 more
core +1 more source
Operando Temperature Sensing at the Actual Electrocatalytic Interface by Nanodiamond Quantum Sensors
By integrating a wide‐field microscope with a custom‐designed electrolyzer, nanoscale temperature changes can be recorded in situ during the electrolysis process without interfering with ongoing electrochemical reactions. This method establishes a correlation between the interface temperature and specific electrochemical reactions, making the measured ...
Zan Li +7 more
wiley +1 more source
The Sustainable Management of Metals: An Analysis of Global Research [PDF]
The objective of this study was to analyze research trends in the field of sustainable management of metals on a global level between 1993 and 2017. To do so, a bibliometric analysis was carried out on a total of 6967 articles.
Aznar Sánchez, José Ángel +3 more
core +1 more source
SI‐bioATRP in Mesoporous Silica for Size‐Exclusion Driven Local Polymer Placement
An enzyme‐catalyzed surface‐initiated atom transfer radical polymerization (SI‐bioATRP) of an anionic monomer within mesoporous silica particles, using hemoglobin as a catalyst, allows for controlling the location of the formed polymer via size‐exclusion effects between the nanopores and the biomacromolecules, thereby opening routes to functional ...
Oleksandr Wondra +8 more
wiley +1 more source
Bioinspired catalysts: Synthesis, characterisation and some applications [PDF]
Our recent work concerning the synthesis, characterisation and some applications of bioinspired electron-transfer catalysts is reviewed in this contribution.
Pálinkó, István
core
Carbon Monoxide Oxidation Promoted by Surface Polarization Charges in a CuO/Ag Hybrid Catalyst. [PDF]
Composite structures have been widely utilized to improve material performance. Here we report a semiconductor-metal hybrid structure (CuO/Ag) for CO oxidation that possesses very promising activity. Our first-principles calculations demonstrate that the
Jia, Chuanyi +5 more
core
High‐energy electron impact in plasma catalysis often causes excessive dissociation of active intermediates, limiting C2+ product selectivity. To address this challenge, a bio‐inspired stoma‐shell nanoarchitecture is designed to decouple electron impact from catalytic reaction zones.
Nan Zou +5 more
wiley +1 more source
From Single Atoms to Nanoparticles: Pathways Toward Efficient and Durable Pt/TiO2 Photocatalysts
Platinum single atoms on TiO2 nanosheets evolve into clusters and nanoparticles under ethanol photoreforming and thermal treatments. By controlling deposition and post‐treatments, particle size and location on specific facets are modulated. The study reveals how stability pathways determine efficiency, guiding the design of more durable photocatalysts.
Juan José Delgado +6 more
wiley +1 more source

