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Superconformal Electrodeposition of Copper
Electrochemical and Solid-State Letters, 2001A model of superconformal electrodeposition is presented based on a local growth velocity that is proportional to coverage of a catalytic species at the metal/electrolyte interface. The catalyst accumulates at the interface through reaction with the electrolyte.
T. P. Moffat +3 more
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Self-affine growth of copper electrodeposits
Physical Review B, 1993We have studied the static surface roughness of 50-μm-thick copper electrodeposits on length scales between 5 and 10 4 nm using scanning tunneling and atomic force microscopy. The surface roughness depends strongly on the concentration of organic additives in the plating solution.
, Iwasaki, , Yoshinobu
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Improving copper electrodeposition in the microelectronics industry
2008 58th Electronic Components and Technology Conference, 2008Sporadic voiding within the interfacial Cu3Sn intermetallic compound (IMC) layer-sometimes referred to as ?Kirkendall voiding?-has been found to lead to degradation of solder joint reliability in board level, mechanical shock testing. It has been suggested that the voiding phenomenon is a result of the incorporation of organic impurities in the copper (
null Yihua Liu +9 more
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Electrical resistance of planar copper electrodeposits
Physical Review A, 1989Mesure directe, en courant alternatif, de la variation de la resistance electrique de depots electrolytiques de cuivre dans un support en papier, en fonction de la tension de depot.
, Melrose, , Hibbert
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Nitrate Reduction at Electrodeposited Copper on Copper Cathode
ECS Transactions, 2014We report on the synthesis and characterization of low-cost copper electrodeposited on a copper substrate (Cu/Cu), and its applicability towards nitrate reduction. The surface area of Cu was increased by the electrodeposition of Cu, and at a chosen deposition potential and pH, optimum electrodeposition parameters corresponding to better catalytic ...
Kunjuvaikarar Soundararajan Rajmohan +1 more
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Selective Copper Electrodeposition to a 3D Copper Nanostructure
ECS Meeting Abstracts, 2016Introduction Three-dimensional (3D) copper nanostructures are expected to be applied as current collectors for lithium ion battery anodes due to their high electrical conductivity and large specific surface area. The production of 3D copper nanostructures usually requires complicated fabrication steps; however, we have developed a ...
Yuma Kobayashi, Susumu Arai
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Electrochemical and Solid-State Letters, 2001
Copper was electrodeposited from sulfate bath onto copper substrate over silicon wafer with titanium adhesive film and the resistivity was measured using a four-point probe method. The measured resistivities increased as thiourea concentration increased from to and as the current density was increased from 1 to 50 mA/cm2.
V. S. Donepudi +4 more
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Copper was electrodeposited from sulfate bath onto copper substrate over silicon wafer with titanium adhesive film and the resistivity was measured using a four-point probe method. The measured resistivities increased as thiourea concentration increased from to and as the current density was increased from 1 to 50 mA/cm2.
V. S. Donepudi +4 more
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Characterization of dislocations in copper electrodeposits
Journal of Materials Science, 2000Copper electrodeposits with the [111] orientation were obtained from a copper sulfate bath consisting of 280 g/l CuSO45H2O and 80 g/l H2SO4 at 30°C. The cathode current density was 900 to 1300 A/m2. Dislocations in the electrodeposits were characterized using transmission electron microscopy. Dislocations in each of the (111) grains could be classified
Y.-S. Lee, D. N. Lee
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The stabilization of electrodeposited copper powder
Surface and Coatings Technology, 1986Abstract Copper powder was electrodeposited from a solution containing copper sulphate and sulphuric acid. The stability of the powder, as measured by the resistance to oxidation, was assessed over a range of temperatures using a thermal balance. Similar powder was treated with an aqueous solution of benzotriazole, a specific corrosion inhibitor for ...
R. Walker, S.J. Duncan
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Fractal electrodeposits of zinc and copper
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1990Abstract Experiments on the electrodeposition of zinc and copper from aqueous solutions of ZnSO 4 and CuSO 4 are reported. The two-dimensional deposits were grown from a line electrode at small ionic concentration (≅0.1 M) and low voltages (10 V). They show fractal characteristics similar to those of diffusion-limited aggregation (DLA) patterns. In
Francesc Sagués +3 more
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