European Journal of Organic Chemistry, EarlyView.Bridging the gap. Beyond deck functionalization, the ethylene bridges of [2.2]paracyclophanes offer a largely unexploited reactivity landscape. This review showcases strategies to functionalize these bridges and leverage them to build novel cyclophane architectures.
Rongyu Sun +3 more
wiley +1 more source
Beilstein Journal of Organic Chemistry, 2013 Starting from the conveniently available ex-chiral pool building block (R,R)-hexa-1,5-diene-3,4-diol, the ten-membered ring lactones stagonolide E and curvulide A were synthesized using a bidirectional olefin-metathesis functionalization of the terminal ...
Bernd Schmidt, Oliver Kunz
doaj +1 more source
An Anthracene-Thiolate-Ligated Ruthenium Complex: Computational Insights into Z-Stereoselective Cross Metathesis. [PDF]
J Phys Chem A, 2023 Martínez JP, Trzaskowski B.
europepmc +1 more source
Catalytic, Enantioselective Synthesis of 1,2-anti-Diols by Asymmetric Ring-Opening/Cross-Metathesis [PDF]
, 2014 An enantioselective method for the synthesis of 1,2-anti-diols has been developed. A cyclometalated chiral-at-ruthenium complex catalyzes the asymmetric ring-opening/cross-metathesis of dioxygenated cyclobutenes, thus resulting in functionally rich ...
Grubbs, Robert H., Hartung, John
core +1 more source
Macromolecular Rapid Communications, EarlyView.It is reported the design of biobased sustainable, smart, and functional adhesives achieved dispersing recycled carbon fibers into biobased epoxy monomer. ABSTRACT The development of sustainable, smart, and functional adhesives is crucial in advancing environmentally friendly materials.
Alberto Cellai +6 more
wiley +1 more source
A Convenient, Safe, and Atom-Economical Route to a Large Portfolio of Grubbs-Type Catalysts for Olefin Metathesis via Four-Coordinate Ruthenium Alkylidynes. [PDF]
Angew Chem Int Ed EnglIt may seem counterintuitive to first target a ruthenium alkylidyne when Grubbs‐type ruthenium carbene complexes are the actual goal. In the end, however, this tactic pays valuable dividends in terms of practicality, atom economy, flexibility as well as safety: the new route provides ready access to a large assortment of catalysts for alkene metathesis
Cui M, Fürstner A.
europepmc +3 more sources
Z-Selective Ethenolysis with a Ruthenium Metathesis Catalyst: Experiment and Theory [PDF]
, 2013 The Z-selective ethenolysis activity of chelated ruthenium metathesis catalysts was investigated with experiment and theory. A five-membered chelated catalyst that was successfully employed in Z-selective cross metathesis reactions has now been found to ...
Dong, Xiaofei +9 more
core +2 more sources
Kinetics of anionic polymerization of β‐myrcene in hydrocarbon solvents
Polymer International, EarlyView.The process of anionic polymerization of β‐myrcene in hydrocarbon solvents was examined by kinetic studies and quantum chemical calculations. Abstract The kinetics of anionic polymerization of β‐myrcene initiated by sec‐butyllithium were examined in saturated and unsaturated hydrocarbon solvents, i.e. cyclohexane, cyclohexene, 4‐vinylcyclohexene and dl‐
Alexander Rösler +4 more
wiley +1 more source
Modular synthesis of the pyrimidine core of the manzacidins by divergent Tsuji–Trost coupling
Beilstein Journal of Organic Chemistry, 2016 The design, development and application of an efficient procedure for the concise synthesis of the 1,3-syn- and anti-tetrahydropyrimidine cores of manzacidins are reported.
Sebastian Bretzke +5 more
doaj +1 more source
Z-Trisubstituted α,β-Unsaturated Esters and Acid Fluorides through Stereocontrolled Catalytic Cross-Metathesis. [PDF]
J Am Chem Soc, 2023 Qin C +6 more
europepmc +1 more source