Concise Syntheses of Insect Pheromones Using Z-Selective Cross Metathesis [PDF]
The use of insect sex pheromones to limit specifically targeted pest populations has gained increasing popularity as a viable, safe, and environmentally friendly alternative to insecticides. While broad-spectrum insecticides are toxic compounds that have
Grubbs, Robert H. +3 more
core +1 more source
This review examines bio‐based polyurethanes from renewable feedstocks, focusing on structure‐property relationships governing mechanical performance. It analyzes reinforcement strategies, benchmarks against petrochemical counterparts, and explores future directions, including non‐isocyanate routes and circular economy integration for sustainable high ...
Khaled Chawraba +4 more
wiley +1 more source
Ruthenium-catalysed Z-selective cross metathesis of allylic-substituted olefins [PDF]
The Z-selective cross metathesis of allylic-substituted olefins is explored with recently developed ruthenium-based metathesis catalysts. The reaction proceeds with excellent stereoselectivity for the Z-isomer (typically >95%) and yields of up to 88% for
Grubbs, Robert H., Quigley, Brendan L.
core +1 more source
Preparation of Functionalized α,β-Unsaturated Sulfonamides via Olefin Cross-Metathesis. [PDF]
Woźniak Ł +4 more
europepmc +1 more source
Preparation of Key Intermediates for the Syntheses of Coenzyme Q10 and Derivatives by Cross-Metathesis Reactions. [PDF]
Nguyen T, Mac H, Pham P.
europepmc +1 more source
A Relay Strategy Actuates Pre-Existing Trisubstituted Olefins in Monoterpenoids for Cross-Metathesis with Trisubstituted Alkenes. [PDF]
Bahou KA +5 more
europepmc +1 more source
Synthesis of a Carbon‐Linked Acyldepsipeptide Derivative
The synthesis of a methylene‐linked acyldepsipeptide (ADEP) is reported. Success relied upon an improve method to generate a versatile vinyl glycine methyl ester synthon and a rationally optimized Grubb’s metathesis. NMR and in silico studies revealed an unusual trans–trans proline orientation for this new unnatural ADEP analog, advancing the ...
Katelyn G. Stevens-Davis +6 more
wiley +1 more source
Relay Cross Metathesis for the Iterative Construction of Terpenoids and Synthesis of a Diterpene-Benzoate Macrolide of Biogenetic Relevance to the Bromophycolides. [PDF]
Bahou KA +3 more
europepmc +1 more source
Assembling the prenylneoflavone system through a Pechmann condensation/Mitsunobu reaction/Claisen rearrangement/olefin cross-metathesis sequence. [PDF]
Lozinski OA +4 more
europepmc +1 more source

