Results 111 to 120 of about 280,213 (284)

(E)-1-(2,4-Dinitrophenyl)-2-(3-ethoxy-4-hydroxybenzylidene)hydrazine

Acta Crystallographica Section E, 2014
The molecule of the title hydrazine derivative, C15H14N4O6, is essentially planar, the dihedral angle between the substituted benzene rings being 2.25 (9)°. The ethoxy and hydroxy groups are almost coplanar with their bound benzene ring [r.m.s. deviation
Hoong-Kun Fun, Suchada Chantrapromma, Pumsak Ruanwas, Thawanrat Kobkeatthawin, C. S. Chidan Kumar   +4 more
doaj   +1 more source

Secondary Coordination Sphere‐Directed Design of Thermo‐Responsive and Bright Luminescent Manganese(II) Complexes

Advanced Optical Materials, EarlyView.
Luminescent manganese(II) complexes with modified secondary coordination spheres exhibit remarkably high emission quantum yields and distinct chromic behavior. The introduction of steric and functional groups enhances emission efficiency and enables temperature dependent emission color changes through reversible intramolecular interactions in the ...
Masaki Yoshida, Fuwenhan Zhang, Kaito Segawa, Kanon Komoda, Kodai Yuasa, Hiromu Obata, Nobuto Yoshinari, Masako Kato   +7 more
wiley   +1 more source

Synthesis of Polycyclic Oxazolinium Compounds from Aryloxazolines and Alkynes via Dual Photoredox/Gold Catalysis and Rhodium Catalysis

Advanced Synthesis &Catalysis, EarlyView.
A series of polycyclic oxazolinium compounds is synthesized from various aryloxazolines with silyl‐substituted alkynes and internal alkynes via dual photoredox/gold catalysis and Rh‐catalyzed C–H bond functionalization, and affords silyl‐substituted polycyclic oxazoliniums and polycyclic oxazoliniums, respectively.
Lai‐Yi Tsang, Ajcharapan Tantipanjaporn, Karen Ka‐Yan Kung, Hoi‐Yi Sit, Wa‐Yi O, Aries Kwok‐Heung Chan, Nathanael Chun‐Him Lai, Man‐Kin Wong   +7 more
wiley   +1 more source

5,7‐Membered Cyclometallated Gold(III) Complexes with Pyridine‐Phenyl‐Oxazoline N^C^N Ligands as Catalysts for Organic Transformation Reactions Under Silver‐Free Conditions

Advanced Synthesis &Catalysis, EarlyView.
A series of 5,7‐membered cyclometallated gold(III) complexes with N^C^N tridentate ligands are prepared via transmetalation of pyridine‐phenyl‐oxazoline ligand‐containing organomercury compounds with potassium gold(III) chloride (KAuCl4) for catalysis.
Yosephine Tania Limanto, Karen Ka‐Yan Kung, Aries Kwok‐Heung Chan, Nathanael Chun‐Him Lai, Man‐Kin Wong   +4 more
wiley   +1 more source

CO2‐to‐Cyclic Carbonate Transformation at Ambient Pressure Using a Mechanochemically Prepared Ti(III) Catalyst

Advanced Synthesis &Catalysis, EarlyView.
A Ti(III) complex synthesized mechanochemically catalyzes the cycloaddition of CO2 (1 bar) with terminal, internal, and trisubstituted epoxides. Mechanistic studies by density functional theory calculations reveal that the superior activity of Ti(III) compared to Ti(IV) arises from its lower oxophilicity, facilitating CO2 insertion into Ti–O bonds, as ...
Elena Álvarez‐Ruiz, Marta Navarro, Ignacio Sancho, Israel Fernández, Cristina Santamaría, Alberto Hernán‐Gómez   +5 more
wiley   +1 more source

Crystallographic and DFT study of novel dimethoxybenzene derivatives

BMC Chemistry
Dimethoxybenzene derivatives are versatile compounds with significant pharmaceutical applications. This study investigates the synthesis of two dimethoxybenzene derivatives, focusing on their structural, electronic, and intermolecular interaction ...
Nancy N. Elewa, Ahmed F. Mabied
doaj   +1 more source

On the Role of MWCNTs for the Effective Detection of Glucose Using MWCNTs/NiO/MWCNTs Stacks on Carbon Paper Electrodes

Advanced Sensor Research, EarlyView.
This study deciphers the mechanism of enhanced glucose detection using multiwalled carbon nanotubes and nickel oxide stacks (MWCNTs/NiO/MWCNTs) on commercially available carbon paper electrodes. We demonstrate the role of MWCNTs where the defects enrich the electrocatalytic activity when they come in contact with the glucose molecule for its selective ...
Akshay Parab, Methu Dev Nath, Yash Mane, Zainab Godhrawala, Tushar Sant, Rahul Panat, Suhas Jejurikar   +6 more
wiley   +1 more source

Cytokine Engineering Approaches for Regenerative Medicine

Advanced Therapeutics, EarlyView.
Engineered cytokines represent a powerful strategy to promote tissue repair and regeneration by precisely modulating immune responses. This review highlights recent advances in cytokine engineering, including strategies to enhance half‐life, improve tissue and cell targeting, and control receptor signaling.
Shiyi Li, Wenhao You, Mikaël M. Martino
wiley   +1 more source

Human Nervous System‐Based Biohybrid Robot‐On‐A‐Chip with Sensing Function for Toxicity Screening

Advanced Science, EarlyView.
Human nervous system‐based biohybrid robot‐on‐a chip with eye function as sensing system in addition to brain/motor neuron/muscle functions is proposed. Upon light stimulation, the eye assembloid generates electrophysiological signals, which are transmitted through the cerebral organoid and motor neuron spheroid, inducing muscle movement.
Minkyu Shin, Joungpyo Lim, Seewoo Kim, Sangeun Lee, Wei Wen Su, Jinho Yoon, Jeong‐Woo Choi   +6 more
wiley   +1 more source

STING COPII ER Export Trafficking and Signaling Primed by Phosphorylation Switches

Advanced Science, EarlyView.
This schematic outlines STING trafficking and signaling via coat protein II (COPII)‐mediated endoplasmic reticulum (ER) export. Following cyclic GMP‐AMP (cGAMP) stimulation, TANK‐binding kinase 1 (TBK1) activates on COPII vesicles, partially dissociating into the cytosol to phosphorylate ER‐localized STING, creating pSGME/pFS COPII‐sorting motifs ...
Yanan Nan, Dongxiao Cui, Jiajian Guo, Xiaojing Ma, Jiaming Wang, Linyue Guo, Tianyu Li, Mingrui Yang, Guangrui Huang, Anlong Xu, Wenfu Ma   +10 more
wiley   +1 more source