Results 211 to 220 of about 2,064,816 (279)

Concise Total Syntheses of Leuconoxine‐Type Alkaloids Enabled by Palladium/Norbornene‐Catalyzed Pyrrole Difunctionalization

open access: yesAngewandte Chemie, EarlyView.
Concise total syntheses of five leuconoxine alkaloids have been achieved using a pyrrole‐centered strategy, which features a newly developed palladium/norbornene‐catalyzed pyrrole double C─H functionalization method, a divergent late‐stage oxidative dearomatization tactic, and no use of protecting groups.
Xin Liu   +5 more
wiley   +2 more sources

A Phenazine‐Based Two‐Dimensional Covalent Organic Framework for Photochemical CO2 Reduction with Increased Selectivity for Two‐Carbon Products

open access: yesAngewandte Chemie, EarlyView.
The catalytic advantages of covalent organic frameworks (COFs) for sustainable CO₂ utilization have been demonstrated by the photocatalytic reduction of CO₂ by a redox‐active, phenazine‐based COF (Phen‐COF). Phen‐COF efficiently converts CO₂ into formate, oxalate, and carbon monoxide under light irradiation, achieving significantly higher yields than a
Zoheb Hirani   +3 more
wiley   +1 more source

Crystal structure of 2,5-di-5-benzyl(1-thia-3,4-diazacyclopenta-2,5-diene), C16H14N2S3

open access: yesZeitschrift für Kristallographie - New Crystal Structures, 2000
Tarafder M. T. H.   +6 more
doaj   +1 more source

Imino‐Pyrrole Zn(II) Complexes for the Rapid and Selective Chemical Recycling of Commodity Polymers

open access: yesAngewandte Chemie, EarlyView.
Three imino‐pyrrole zinc (II) catalysts were prepared and applied to the chemical recycling of PLA, PET, and BPA‐PC. Rapid PLA degradation was accomplished in solution and under solvent‐free conditions, the latter giving full conversion at relatively mild temperatures after 11 min.
Jack A. Stewart   +5 more
wiley   +1 more source

Routes to Pt Derivatives of High‐Valent Sulfur Oxofluorides S(═O)2F, S(═O)F2, and S(═O)F3 by Fluorination and Oxygenation

open access: yesAngewandte Chemie, EarlyView.
This study demonstrates the controlled functionalization of a SOF ligand at a platinum center, achieving the selective formation of SO2F and SOF2 complexes by fluorination or oxygenation. Further fluorination of the SOF2 ligand resulted in an unprecedented SOF3 metal derivative, which is a unique example of a high‐valent fluorinated sulfur atom ...
Ruben Jaeger   +5 more
wiley   +1 more source

Crystal structure of 2-S-benzyl-5-phenyl-1-(1-thia-3,4-diazacyclopenta-2,4-diene), C15H12N2S2

open access: yesZeitschrift für Kristallographie - New Crystal Structures, 2000
Tarafder M. T. H.   +6 more
doaj   +1 more source

Low‐Symmetry Face‐Capped Fe(II) Tetrahedra Through Anisotropic Ligand Extension

open access: yesAngewandte Chemie, EarlyView.
A strategy for the formation of low‐symmetry face‐capped Fe(II) tetrahedra using anisotropic ligand extension is reported. The degree of distortion in the resulting tetrahedra correlates to the stability of the assemblies and the oxidation potentials of their metal ions. Abstract Low‐symmetry cages are attractive metallo‐supramolecular targets, as they
Jacob A. Gome   +7 more
wiley   +1 more source

Polyphosphorus Ligand Complexes of Coinage Metals for Multiple Capturing of Intact P4 Tetrahedra

open access: yesAngewandte Chemie, EarlyView.
Self‐assembly reactions of [CpRFe(η5‐P5)] (CpR = C5(CH3)5 and C5(4‐EtC6H4)5) with coinage metal salts and white phosphorus afforded an unprecedented novel class of mixed polyphosphorus ligand complexes in which metal ions multiply coordinate intact P4 tetrahedra.
Claudia Göschl   +5 more
wiley   +1 more source

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