Results 211 to 220 of about 415,174 (326)

A Bambusuril Receptor Binds Charge Diffuse Anions in Water at Picomolar Concentrations

open access: yesAngewandte Chemie, EarlyView.
Synthesis of a bambusuril macrocycle with unprecedented binding affinity for several charge diffuse anions, including iodide, perchlorate, nitrate, and perrhenate, in neutral phosphate buffer is reported. The macrocycle exhibits selectivity for charge diffuse over charge dense anions exceeding seven orders of magnitude.
Surbhi Grewal   +2 more
wiley   +2 more sources

Reshaping Protein‐Based Nanoparticles: Innovative Artificial Intelligence‐Driven Strategies for Structural Design and Applications

open access: yesAdvanced NanoBiomed Research, EarlyView.
Artificial Intelligence‐driven advancements in protein‐based nanoparticle design enable exceptional functionalities, overcoming traditional challenges and expanding nanomedicine applications. Nanoparticles (NPs) have become a pivotal technology in biomedical research due to their unique physicochemical properties and nanoscale size, allowing for ...
Mohammad Mahmoudi Gomari   +3 more
wiley   +1 more source

Metastable Macrocyclic Bis‐Meisenheimer Adduct

open access: yesAngewandte Chemie, EarlyView.
A tetranitroazacalixarene captures cyanide reversibly via SNAr to form a metastable dianionic bis‐Meisenheimer complex. Stabilized by intramolecular hydrogen bonding, the dianionic adduct spontaneously regenerates the parent macrocycle under mild conditions. This dynamic, fuel‐driven process can be finely tuned by the counterion, concentration, solvent,
Simon Pascal   +7 more
wiley   +2 more sources

Segmented milli-fluidic crystallisation of paracetamol with <i>in situ</i> single-crystal X-ray diffraction. [PDF]

open access: yesChem Sci
Wayment LE   +10 more
europepmc   +1 more source

Nanostructured Biomaterial‐Based Approaches to Support Induced Pluripotent Stem Cell Differentiation

open access: yesAdvanced NanoBiomed Research, EarlyView.
Induced pluripotent stem cells (iPSCs), reprogrammed from adult somatic cells, represent an innovative approach for regenerative medicine and biomedical applications. This review highlights the importance of nanostructured biomaterials, utilized as delivery systems or scaffolds, in supporting iPSC differentiation and fate through structural and ...
Beatriz A. B. R. Passos   +2 more
wiley   +1 more source

Wacker Oxidation of Trisubstituted Alkenes: Pd(II)‐Catalyzed Oxidative Ring Expansion of Exocyclic α,β‐Unsaturated Carbonyl to 2‐Fluoro‐1,3‐Dicarbonyl Compounds

open access: yesAngewandte Chemie, EarlyView.
First examples of Pd(II)‐catalyzed Wacker oxidation of trisubstituted alkenes, coupled with electrophilic fluorination, enable a one‐carbon ring expansion of exocyclic α,β‐unsaturated carbonyls to 2‐fluoro‐2‐acyl‐cycloalkanones. Abstract The Wacker oxidation is a powerful synthetic method widely employed for the transformation of monosubstituted ...
Vincent Goëlo, Qian Wang, Jieping Zhu
wiley   +2 more sources

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