Results 101 to 110 of about 4,145 (241)

Stacking the Deck to Make Materials With Atypically Short Heterometallic d8 M(II)···Au(III) Bonds

Angewandte Chemie, EarlyView.
Tetracyanoplatinate(II) and tetracyanoaurate(III), through self‐assembly in the presence of KCl, crystallize from water to form a one‐dimensional chain featuring the first reported PtII···AuIII metallophilic interaction with a very short distance of ∼3.0 Å between the metal centers.
Leanna M. Karn, Samyadeb Mahato, Adlih Britton, Mojtaba Abbasi, Scott Kroeker, Tim Storr, Daniel B. Leznoff   +6 more
wiley   +2 more sources

Nullwertige Nickelatome stabilisiert in oberflächengestützten metallorganischen Ketten

Angewandte Chemie, EarlyView.
Mit 9,10‐Dicyanoanthracen koordinierte nullwertige Ni(0) d10‐Zentren auf Ag(100), die eine metallorganische Kette mit quasi‐eindimensionaler Metall‐Ligand‐Wechselwirkung bilden. ZUSAMMENFASSUNG Die Stabilisierung von nullwertigen Ni(0)‐Zentren in ausgedehnten Koordinationsnetzwerken bleibt aufgrund ihrer ausgeprägten Reaktivität und Anfälligkeit für ...
Simone Mearini, Dominik Brandstetter, Mira S. Arndt, Olga Resel, Daniel Baranowski, Yan Yan Grisan Qiu, Peter Puschnig, Martin Sterrer, Giovanni Zamborlini, Vitaliy Feyer, Claus M. Schneider   +10 more
wiley   +1 more source

Defect‐Rich CoNi Prussian Blue Analogues Enable Highly Selective Electrochemical Hydrogen Peroxide Production

Angewandte Chemie, EarlyView.
Introducing [Co(CN)6]3− defects into CoNi Prussian Blue analogues exposes square‐planar Ni–N4 active sites, leading to remarkable H2O2 selectivity during the electrochemical oxygen reduction reaction in alkaline media. ABSTRACT Decentralized electrosynthesis of hydrogen peroxide (H2O2) via the two‐electron oxygen reduction reaction (2e− ORR) offers a ...
Kai Sun, Yu Mao, Yongfang Zhou, Ziyun Wang, Geoffrey I. N. Waterhouse   +4 more
wiley   +2 more sources

Simple cyanides and formylium ion isotopologues in early star-forming molecular cores

Astronomy & Astrophysics
Aims. Understanding the chemistry related to the early stages of star formation is of great importance, as it is linked to the beginnings of the most complex chemistry in the interstellar medium.
Taboada R. D., Paron S., Martinez N. C., Ortega M. E.   +3 more
doaj   +1 more source

Flavin Catalysts in Organic Synthesis

Angewandte Chemie, EarlyView.
Flavins and their congeners are potent catalysts for organic synthesis inspired by enzymatic transformations. In addition to catalysis in the flavin ground state via covalent intermediates, the excited singlet and triplet states unlock applications including photooxidation, photoreduction, and energy transfer via sensitization.
Jan Freudenberg, Golo Storch
wiley   +2 more sources

N‐Alkoxysulfurdiimide Reagents for the One‐Step Modular Synthesis of Primary Sulfonimidamides

Angewandte Chemie, EarlyView.
N‐Alkoxysulfurdiimide reagents when combined with organometallic reagents lead directly to primary sulfonimidamide products. The reactions are broad in scope, encompassing aryl, heteroaryl, and alkyl carbon substituents. The reactivity of the N‐alkoxysulfurdiimide reagents can be correlated with the electron‐withdrawing ability of the N‐substituent ...
Suzanne E. Davison, Jonathan A. Andrews, Agamemnon E. Crumpton, Mireia Sidera Portela, Michael A. Clegg, Damien Valette, Michael C. Willis   +6 more
wiley   +2 more sources

Dyotropic Rearrangement of Hypervalent Iodine Species: Migrative Heterofunctionalization of Quaternary Carbons

Angewandte Chemie, EarlyView.
1,2‐Aryl migration involving in situ‐generated alkyl iodine(III) species proceeds through a previously unrecognized 1,2‐C/I(III) dyotropic rearrangement. Migratory aryl fluorination, acetoxylation, and alkoxylation of 2‐alkyl‐2‐aryl‐3‐iodopropanoates provide α‐heterofunctionalized products, accompanied by aryl migration from the α‐ to the β‐position ...
Chen‐Xu Liu, Qian Wang, Matthew D. Wodrich, Jieping Zhu   +3 more
wiley   +2 more sources

Technical and political concerns of site remediation: a German case

Revista Águas Subterrâneas, 2011
On a site in Northern Germany the groundwater is contaminated with cyanides. The source is the embankment of a road constructed with slag material in the 70’s.
Fernando Mazo D´Affonseca, Michael Finkel   +1 more
doaj  

Photochemical Ring Opening of Cyclopropyl Silyl Ethers Enables β–β Coupling, Radical‐Polar Crossover and Annulation

Angewandte Chemie, EarlyView.
A photochemical platform enables β–β coupling of cyclopropyl silyl ethers with electron‐deficient alkenes. The resulting adducts serve as entry points into annulative and radical–polar crossover pathways, providing rapid access to fused, bridged, and spirocyclic architectures, including late‐stage scaffold diversification to diterpene‐like carbocyclic ...
Jacop Rydén, Eilidh Young, Wilma Olsson, Eskil Flodén, Mattias Tan, Sebastian Clementson   +5 more
wiley   +2 more sources

Borylcyclopropanes: Synthetic Strategies and Applications

Angewandte Chemie, EarlyView.
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley   +2 more sources