Results 81 to 90 of about 6,212 (279)

Synthesis of Schiff and Mannich Bases of Isatin Derivatives with 4-Amino-4,5-Dihydro-1H-1,2,4-Triazole-5-Ones

open access: yesMolecules, 2008
Ethyl imidate hydrochlorides 1 were prepared by passing HCl gas through solutions of substituted benzyl cyanides and absolute ethanol. Ethoxycarbonylhydrazones 2 were synthesized from the reaction of compounds 1 with ethyl carbazate.
Hakan Bektas, Olcay Bekircan
doaj   +1 more source

On the hydrolysis of diethyl 2-(perfluorophenyl)malonate

open access: yesBeilstein Journal of Organic Chemistry, 2020
Diethyl 2-(perfluorophenyl)malonate was synthesized in 47% isolated yield by the reaction of sodium diethyl malonate and hexafluorobenzene. The resulting compound was considered as a starting material for synthesizing 2-(perfluorophenyl)malonic acid by ...
Ilya V. Taydakov, Mikhail A. Kiskin
doaj   +1 more source

Selective acylation of hydroxy steroids with acyl cyanides

open access: yes, 1979
A mild acylation method of steroid alcohols with acyl cyanides is described. The high sensitivity of benzoyl cyanide toward steric conditions in the neighbourhood of the hydroxyl group was made use of for the separation of epimeric hydroxy steroids.
Jan Pospíšek   +3 more
core   +1 more source

Substrate‐Affinitive P‐Type Azapolycyclic Photosensitizer for Chemoselective Nitrilization Under Mild Conditions

open access: yesAdvanced Science, EarlyView.
We developed a series of quinoxalinoquinoxaline (QQ) photosensitizers featuring high and tunable excited‐state reduction potentials (E(PC•+/PC*) = –1.76 to –2.05 V vs. SCE). Their hydrogen‐bonding interaction with carbonyl substrates enables selective single‐electron transfer events for selective nitrilization of 1° amides, offering a tunable ...
Seongwoo Bae, Dongwook Kim, Jinwoo Kim
wiley   +1 more source

Biomass burning and urban air pollution over the Central Mexican Plateau [PDF]

open access: yesAtmospheric Chemistry and Physics, 2009
Observations during the 2006 dry season of highly elevated concentrations of cyanides in the atmosphere above Mexico City (MC) and the surrounding plains demonstrate that biomass burning (BB) significantly impacted air quality in the region.
P. O. Wennberg   +11 more
doaj  

Anharmonic Properties of Alkali Halides and Cyanides

open access: yes, 1996
Anharmonic properties of 16 alkali halides and 4 alkali cyanides are investigated using long-range Coulomb and short-range Born-Mayer potentials starting from the nearest-neighbour distance and repulsive parameter.
Kailash, -
core   +1 more source

Zero Thermal Expansion and Local Structure in KxMnxFe2‐xMo3O12‐Based Materials

open access: yesAdvanced Science, EarlyView.
Local structure engineering via ion insertion drives local structural transformation from low‐symmetry P21/a to high‐symmetry R‐3c, enhancing structural flexibility and realizing a transition from positive thermal expansion to wide‐temperature‐range zero thermal expansion in KxMnxFe2‐xMo3O12‐based materials.
Gongsen He   +13 more
wiley   +1 more source

Poly (vinylpyrrolidone)-Grafted Silica as a Polymeric Cosolvent Catalyst for Organic Transformations in Organic and Aqueous Media [PDF]

open access: yesJournal of Sciences, Islamic Republic of Iran, 2015
Poly (vinylpyrrolidone)-grafted silica as an organic-inorganic hybrid material was used as an effective heterogeneous polymeric cosolvent catalyst in organic reactions.
S. Ghasemi   +3 more
doaj  

Prmt6 Deficiency or Inhibition Restores Microglial Homeostasis and Promotes Scar‐Limited Repair in Adult Spinal Cord Injury

open access: yesAdvanced Science, EarlyView.
After spinal cord injury, adult microglia remain persistently activated with chronic PRMT6 (protein arginine methyltransferase 6) upregulation. Prmt6 deficiency or inhibition reestablishes microglial homeostasis and promotes a scar‐limited repairment, enhancing axonal regrowth.
Weilin Peng   +9 more
wiley   +1 more source

Removal of cyanides in wastewater by supported TiO2-based photocatalysts

open access: yes, 2002
Titania supported samples on different types of silica have been prepared through a sol-gel method followed by hydrothermal processing. The photocatalytic activity of the samples was tested for free cyanides photo-oxidation.
Marugán, J.   +3 more
core   +1 more source

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