Results 81 to 90 of about 7,042 (282)

Investigations of the Evolved Molecular Basis for Terpenoid Biosynthesis in Marine Sponges

Advanced Science, EarlyView.
Confirming and extending a previous observation in another Bubarida sponge, genomic and functional analyses of A. cavernosa reveal that sponges retain the mevalonate pathway and employ single α‐domain T1TSs and UbiA‐type TSs for terpenoid biosynthesis. The absence of T1TSs clustering with other biosynthetic genes tentatively suggests, based on limited ...
Fangyan Chen, Bao Chen, Wenhui Zhang, Guifang Sun, Yao Zhao, Jianpeng Zhang, Baofu Xu   +6 more
wiley   +1 more source

Microorganisms and cyanide

Bacteriological Reviews, 1976
The susceptibility of cytochrome oxidases to cyanide means that cyanide is toxic to living cells and cyanide pollution causes great damage to microbial and other ecosystems. Cyanide pollution comes from both industrial wastes and a number of plants, many of agricultural importance, which are cyanogenic and release cyanide into the soil.
openaire   +2 more sources

A Biofabricated Human Acinus‐on‐a‐Chip Unveils Mechanotransductive Drivers of Ventilator‐Induced Lung Injury via Decoupling Volutrauma and Barotrauma

Advanced Science, EarlyView.
This bioinspired acinus‐on‐a‐chip recapitulates VILI pathology, revealing that volutrauma drives P53/NF‐κB pathways while barotrauma triggers mitochondrial‐Wnt dysregulation. A fibrotic transitional cell cluster was identified. Pharmacological interventions targeting these pathways significantly ameliorated injury, establishing a mechanobiological ...
Heng Lu, Liansheng Liu, Zengyong Hu, Shuxian Fang, Ruohan Ren, Sidi Liu, Meng Zhao, Zhiting Luo, Ziyue Zhang, Wenlong Shao, Qian Liu   +10 more
wiley   +1 more source

A Mechanistic Investigation of the Carbon−Carbon Bond Cleavage of Aryl and Alkyl Cyanides Using a Cationic Rh(III) Silyl Complex

, 2016
Cationic Rh(III) complex [Cp*(PMe3)Rh(SiPh3)(CH2Cl2)]BAr4‘ (1) activates the carbon−carbon bond of aryl and alkyl cyanides (R−CN, where R = Ph, (4-(CF3)C6H4), (4-(OMe)C6H4), Me, iPr, tBu) to produce complexes of the general formula [Cp*(PMe3)Rh(R ...
Robert G. Bergman (1323120), Felicia L. Taw (2707234), Alexander H. Mueller (2110360), Maurice Brookhart (1502638)   +3 more
core   +2 more sources

A Dispersant‐Driven Carbon‐Binder Domains Homogeneity in High‐Energy‐Density Electrodes for Lithium‐Ion Batteries

Advanced Science, EarlyView.
A polar dispersant, aromatic‐functionalized polyacrylate (AFPA), enables the formation of a uniform CBD network by enhancing miscibility with PVDF and suppressing phase separation. This leads to α‐phase crystallization of PVDF and aligned CNT networks within the CBD, resulting in well‐connected structures that improve cohesion, electron/ion transport ...
Da‐Sol Kwon, Min Young Seo, Jinho Ahn, Yea‐Ji Jeong, Woohyeon Shin, Wonseok Ko, Min Jeong Kim, Jiny Lee, Won‐Yong Jeon, Min‐Jae Choi, Kwang In Kim, Jin Ju Eom, Sang Yeop Oh, Honghee Lee, Joona Bang, Jongsoon Kim, YongJoo Kim, Jung‐Keun Yoo   +17 more
wiley   +1 more source

Anharmonic Properties of Alkali Halides and Cyanides [PDF]

, 1996
Anharmonic properties of 16 alkali halides and 4 alkali cyanides are investigated using long-range Coulomb and short-range Born-Mayer potentials starting from the nearest-neighbour distance and repulsive parameter.
Kailash, -
core   +1 more source

Natural‐Inspired Engineered Microalgae With Selenium Enrichment Enabled Potent Anti‐Tumor Immunity

Advanced Science, EarlyView.
Se‐Ssp was engineered as a potent immunomodulator for activating innate immunity via the TLR and cGAS‐STING pathways, therefore converting “cold” tumors into “hot” tumors to achieve high efficacy and long‐term therapeutic outcomes. ABSTRACT Immunotherapy has shed light on clinical oncology for several decades.
Yuqi Yang, Xiaowei Cai, Xiaoyan Zhong, Tian Qiu, Qinwei Lu, Jiahao Qin, Fei Gong, Yecheng Huang, Chenyu Jiang, Youdong Chen, Yuan Cheng, Liang Cheng   +11 more
wiley   +1 more source

Dual Nickel/Photoredox‐Catalyzed Regio‐ and Enantioselective Alkenylation of Epoxides

Advanced Science, EarlyView.
Ni/photoredox‐catalyzed stereoconvergent cross‐electrophile coupling of racemic epoxides with alkenyl bromides is described, affording β‐alkenyl products with up to 95% ee, excellent E‐selectivity, and complete regiocontrol. These versatile intermediates enable diverse chiral synthons; mechanistic studies suggest a halide ring‐opening followed by ...
Hongyan Lan, Shengzhou Jin, Zhao‐Dong Xu, Guigen Li, Dingyi Wang   +4 more
wiley   +1 more source

2,6-Dibromo-4-chlorophenyl isocyanide

IUCrData, 2018
Molecules of the title compound, C7H2Br2ClN (RNC), are bisected by a mirror plane that passes through the chloro and isocyano groups. The isocyano C atom is bisected by two NC...Br contacts, one per Br atom.
Wayland E. Noland, Kenneth J. Tritch
doaj   +1 more source

Electrocatalytic C─C Bond Formation Via Cyanide Interception of CO2 Reduction Intermediates

Advanced Science, EarlyView.
ABSTRACT Electrochemical CO2 reduction offers a sustainable route to convert greenhouse gas into high‐value‐added chemicals, yet product distributions remain largely limited to simple C1‐C3 molecules. Here, we report a new reaction in which CO2 reduction intermediates undergo direct C‐C coupling with an external carbon nucleophile under electrochemical
Gongbo Liu, Liuru Fang, Dayu Zhu, Aimin Li, Haoming Yu, Chunlu Ding, Yuen‐Leong Chow, Mengjie Liu, Jianqi Geng, San H. Thang, Jie Zhang   +10 more
wiley   +1 more source