Results 21 to 30 of about 39,456 (303)

Investigation of the stability of azacrown complexes with some transition metal ions [PDF]

open access: yesمجله علوم و فنون هسته‌ای, 2020
The separation of metal ions from nuclear waste is an important issue in the nuclear industry. Cyclic chemical compounds including ether groups are called crown ethers. These compounds strongly bind to certain cations, forming complexes.
M. Arabieh   +3 more
doaj   +1 more source

Oxetanes: Recent Advances in Synthesis, Reactivity and Medicinal Chemistry [PDF]

open access: yes, 2016
The 4-membered oxetane ring has been increasingly exploited for its behaviors, i.e. influence on physicochemical properties as a stable motif in medicinal chemistry, and propensity to undergo ring opening reactions as a synthetic intermediate.
Bull, JA   +4 more
core   +1 more source

A TGA/FTIR and Mass Spectral Study on the Thermal Degradation of Bisphenol A Polycarbonate [PDF]

open access: yes, 2004
The thermal degradation of polycarbonate under nitrogen was studied using TGA/FTIR, GC/MS and LC/MS as a function of mass loss. The gases evolved during degradation were inspected by in situ FTIR and then the evolved products were collected and analysed ...
Jang, Bok Nam, Wilkie, Charles A.
core   +2 more sources

Electrochemical Oxidation of Catechol in the Presence of some Azacrown Ethers and Transition Metal Ions in Acetonitrile

open access: yesInternational Journal of Electrochemical Science, 2009
The electrochemical oxidation of catechol (H2Q) (1) has been studied in the absence and presence of 1,10.diaza-18-crown-6 (DA18C6) (2a), 1,7-diaza-15-crown-5 (DA15C5) (2b) and aza-15-crown-5 (A15C5) (2c) and also, in the presence of some transition metal
Davood Nematollahi   +1 more
doaj   +1 more source

The Thermal degradation of Bisphenol A Polycarbonate in Air [PDF]

open access: yes, 2005
The thermal degradation of polycarbonate in air was studied as a function of mass loss using TGA/FTIR, GC/MS and LC/MS. In the main degradation region, 480–560 °C, the assigned structures of smaller molecules and linear molecules that evolved in air were
Jang, Bok Nam, Wilkie, Charles A.
core   +2 more sources

The hydrolysis of geminal ethers: a kinetic appraisal of orthoesters and ketals

open access: yesBeilstein Journal of Organic Chemistry, 2016
A novel approach to protecting jet fuel against the effects of water contamination is predicated upon the coupling of the rapid hydrolysis reactions of lipophilic cyclic geminal ethers, with the concomitant production of a hydrophilic acyclic ...
Sonia L. Repetto   +4 more
doaj   +1 more source

Two-step degradable ABAC-type periodic poly(cyclic acetal)s synthesized by sequence-programmed monomer formation and subsequent polyaddition based on cyclotrimerization of one vinyl monomer and two aldehydes

open access: yesGiant, 2023
ABAC-type periodic poly(cyclic acetal)s were synthesized via a two-step method consisting of the synthesis of a sequence-programmed cyclic trimers from one vinyl monomer and two bifunctional aldehydes (isophthalaldehyde or terephthalaldehyde) and the ...
Tadashi Naito   +2 more
doaj   +1 more source

Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodane

open access: yesMolecules, 2005
Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 °C generates α-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters.
M. Ochiai   +3 more
doaj   +1 more source

Ring-opening polymerization

open access: yesChemistry Teacher International, 2021
Ring-opening polymerization is defined by IUPAC (Penczek, S., Moad, G. (2008). Glossary of the terms related to kinetics, thermodynamics, and mechanisms of polymerization.
Penczek Stanislaw   +2 more
doaj   +1 more source

Mass spectrometry-based fragmentation as an identification tool in lignomics [PDF]

open access: yes, 2010
The ensemble of all phenolics for which the biosynthesis is coregulated with lignin biosynthesis, i.e., metabolites from the general phenylpropanoid, monolignol, and (neo)-lignan biosynthetic pathways and their derivatives, as well as the lignin ...
Akiyama, Takuya   +11 more
core   +2 more sources

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