Results 11 to 20 of about 9,771 (260)

Direct Synthesis of Bicyclic Acetals via Visible Light Catalysis

open access: yesiScience, 2020
Summary: Polysubstituted bicyclic acetals are a class of privileged pharmacophores with a unique 3D structure and an adjacent pair of hydrogen bond acceptors.
Fengjin Wu   +7 more
doaj   +1 more source

Modeling of Living Cationic Ring-Opening Polymerization of Cyclic Ethers: Active Chain End versus Activated Monomer Mechanism [PDF]

open access: yesIranian Journal of Chemistry & Chemical Engineering, 2020
Living cationic ring-opening polymerization of cyclic ethers in the presence of diol was modeled using the method of moments. A widespread kinetic model was developed based on previous experimental studies.
Mehdi Mahmoudian   +5 more
doaj   +1 more source

Herstellung von Polyestern durch ringöffnende, ionische Copolymerisation von Dicarbonsäureanhydriden und Ringäthern

open access: yesCHIMIA, 1975
For the preparation of polyesters an ionically initiated ring-opening copolymerization reaction of dicarboxylic acid anhydrides and cyclic ethers can be used beside the conventional polycondensation technique. The main advantage of this copolymerization
Karl-Heinz W. Reichert
doaj   +1 more source

Synthesis and desulfurization-decarboxylation of cyclic thionocarbonates of glycerol 1-ethers

open access: yesJournal of Lipid Research, 1969
A method is described for the synthesis of cyclic thionocarbonates of 1-O-alkyl glycerols in quantitative yield. These derivatives of glycerol ethers can be quantitated by UV absorbance, analyzed by gas-liquid chromatography, or quantitatively converted ...
S. Ramachandran   +2 more
doaj   +1 more source

Investigation of the stability of azacrown complexes with some transition metal ions [PDF]

open access: yesمجله علوم و فنون هسته‌ای, 2020
The separation of metal ions from nuclear waste is an important issue in the nuclear industry. Cyclic chemical compounds including ether groups are called crown ethers. These compounds strongly bind to certain cations, forming complexes.
M. Arabieh   +3 more
doaj   +1 more source

Electrostatic Potential and a Simple Extended Electric Dipole Model of Hydrogen Fluoride as Probes of Non-Bonding Electron Pairs in the Cyclic Ethers 2,5-Dihydrofuran, Oxetane and Oxirane

open access: yesCrystals, 2017
The electrostatic potential near to the oxygen atom in each of the cyclic ethers 2,5-dihydrofuran, oxetane and oxirane has been calculated by using a distributed multipole analysis (DMA) of each molecule. The electrostatic potential energy V(φ) of a unit
J. Grant Hill, Anthony C. Legon
doaj   +1 more source

Polymerization of Cyclic Ethers Initiated by the Reaction of Cyclic Ether with Hexafluoropropylene Oxide.

open access: yesNIPPON KAGAKU KAISHI, 2002
フッ素含有率の高いヘキサフルオロプロピレンオキシド(HFPO)と環状エーテルとの反応による重合について検討を行った.モノマーとして六員環エーテルであるテトラヒドロピラン(THP)を用いたときには,重合体は得られなかった.四員環エーテルであるオキセタン,および三員環エーテルであるプロピレンオキシド(PO)をモノマーとして用いたときに重合生成物が得られた. モノマーとしてオキセタンを用いたときに,最も高分子量の重合体を得ることができ,その数平均分子量は4.8 × 103であった.これは,オキセタンの開環重合反応性が,環状エーテルの中で最も高いためであると考えられる. モノマーとしてプロピレンオキシド(PO)を用いたときに得られる重合生成物は ...
Yasuyuki MASUBUCHI   +4 more
openaire   +2 more sources

The hydrolysis of geminal ethers: a kinetic appraisal of orthoesters and ketals

open access: yesBeilstein Journal of Organic Chemistry, 2016
A novel approach to protecting jet fuel against the effects of water contamination is predicated upon the coupling of the rapid hydrolysis reactions of lipophilic cyclic geminal ethers, with the concomitant production of a hydrophilic acyclic ...
Sonia L. Repetto   +4 more
doaj   +1 more source

Electrochemical Oxidation of Catechol in the Presence of some Azacrown Ethers and Transition Metal Ions in Acetonitrile

open access: yesInternational Journal of Electrochemical Science, 2009
The electrochemical oxidation of catechol (H2Q) (1) has been studied in the absence and presence of 1,10.diaza-18-crown-6 (DA18C6) (2a), 1,7-diaza-15-crown-5 (DA15C5) (2b) and aza-15-crown-5 (A15C5) (2c) and also, in the presence of some transition metal
Davood Nematollahi   +1 more
doaj   +1 more source

Two-step degradable ABAC-type periodic poly(cyclic acetal)s synthesized by sequence-programmed monomer formation and subsequent polyaddition based on cyclotrimerization of one vinyl monomer and two aldehydes

open access: yesGiant, 2023
ABAC-type periodic poly(cyclic acetal)s were synthesized via a two-step method consisting of the synthesis of a sequence-programmed cyclic trimers from one vinyl monomer and two bifunctional aldehydes (isophthalaldehyde or terephthalaldehyde) and the ...
Tadashi Naito   +2 more
doaj   +1 more source

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