Results 51 to 60 of about 3,194 (256)

Rapid transformation of sulfinate salts into sulfonates promoted by a hypervalent iodine(III) reagent

open access: yesBeilstein Journal of Organic Chemistry, 2018
An alternative method for forming sulfonates through hypervalent iodine(III) reagent-mediated oxidation of sodium sulfinates has been developed. This transformation involves trapping reactive sulfonium species using alcohols. With additional optimization
Elsa Deruer   +3 more
doaj   +1 more source

Difluoromethanesulfonyl hypervalent iodonium ylides for electrophilic difluoromethylthiolation reactions under copper catalysis [PDF]

open access: yesRoyal Society Open Science, 2016
Difluoromethanesulfonyl hypervalent iodonium ylides 2 were developed as electrophilic difluoromethylthiolation reagents for a wide range of nucleophiles.
Sadayuki Arimori   +4 more
doaj   +1 more source

An Ab Initio RRKM-Based Master Equation Study for Kinetics of OH-Initiated Oxidation of 2-Methyltetrahydrofuran and Its Implications in Kinetic Modeling

open access: yesEnergies, 2023
Cyclic ethers (CEs) can be promising future biofuel candidates. Most CEs possess physico-chemical and combustion indicators comparable to conventional fuels, making them suitable for internal combustion engines. This work computationally investigates the
Tam V.-T. Mai   +7 more
doaj   +1 more source

3D Printing Innovations in Polymeric Porous and Patterned Architecture

open access: yesAdvanced Functional Materials, EarlyView.
Polymeric foams occupy a unique structural space between dense solids and open networks, where engineered void fraction governs mechanical compliance, thermal resistance, and mass transport. Additive manufacturing now enables precise spatial control over cellular architecture, unlocking designer foam structures across applications spanning crash ...
Dhanush Patil   +13 more
wiley   +1 more source

The Cationic Ring-Opening Polymerization of Tetrahydrofuran with 12-Tungstophosphoric Acid

open access: yesMolecules, 2010
The cationic ring-opening polymerization reaction of tetrahydrofuran at 20 ºC was catalyzed by H3PW12O40·13H2O as solid acid catalyst. The effect of the proportions of acetic anhydride and catalyst, reaction time and support on the polymerization ...
Hassan Al-Shahri   +2 more
doaj   +1 more source

Synthesis of cyclic ethers by cyclodehydration of 1,n-diols using heteropoly acids as catalysts [PDF]

open access: yesRoyal Society Open Science, 2018
Heteropoly acids were used as catalysts for cyclodehydration of various 1,n-diols. Cyclodehydration of butane-1,4-diol, pentane-1,5-diol and hexane-1,6-diol catalysed by H3PW12O40 gave tetrahydrofuran, tetrahydropyran and oxepane, respectively ...
Yufeng Sun   +5 more
doaj   +1 more source

Mild One-step Synthesis of Dibromo Compounds from Cyclic Ethers

open access: yes, 2016
A novel one-step method for mildly converting cyclic ethers into dibromo compounds is reported. Alcohols, oximes, aldehydes, and ketones are known to react under Appel or Corey–Fuchs reaction conditions, but apparently these have never been applied to ...
Udo H. Brinker (1470559)   +1 more
core   +1 more source

Spectroscopic Investigation of Polysulfide Redox Evolution in Catholyte Solutions for Potassium–Sulfur Batteries

open access: yesAdvanced Functional Materials, EarlyView.
Potassium–sulfur batteries are investigated using UV–vis spectroscopy to track the evolution of potassium polysulfide species at elevated temperature. The study reveals sulfur radical anions as key intermediates and shows how solvent composition and cell design influence polysulfide stability, redox behavior, and cycling performance, providing insights
Chiara Morini   +7 more
wiley   +1 more source

Metal-Free Regioselective Cross Dehydrogenative Coupling of Cyclic Ethers and Aryl Carbonyls

open access: yes, 2019
A highly regioselective, efficient, and metal-free oxidative cross dehydrogenative coupling (CDC) of aryl carbonyls with cyclic ethers has been developed. This method offers easy access to substituted α-arylated cyclic ethers with a high functional group
Kumar Vanka (1378884)   +3 more
core   +2 more sources

Oxidative cyclization of alkenols with Oxone using a miniflow reactor

open access: yesBeilstein Journal of Organic Chemistry, 2009
A miniflow system for oxidative cyclization of alkenols with Oxone was developed. Thus, the oxidative cyclization of (Z)- and (E)-alkenols in i-PrOH with an aqueous solution of Oxone proceeded smoothly and safely in a PTFE tube without any exogenous ...
Yoichi M. A. Yamada   +2 more
doaj   +1 more source

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