Results 51 to 60 of about 1,625,514 (331)

Photoinduced α-C(sp3)–H functionalization of cyclic ethers via synergistic photocatalysis and HAT for efficient C–C bond formation

open access: yesGreen Carbon
The selective transformation of inert C(sp3)–H bonds remains a significant challenge in modern organic synthesis. Herein, we report a photocatalytic strategy for achieving the efficient and selective C–H bond activation under mild conditions.
Ke Liu   +6 more
doaj   +1 more source

Cyclic and Macrocyclic Organic Compounds - a Personal Review in Honor of Professor Leopold Ružička [PDF]

open access: yesKemija u Industriji, 2009
Ružička opened the field of cyclic molecules such as cyclic terpenes and cyclic ketones with up to 17 ring atoms. This work until now was extended in many directions such as cyclic paraffins, crown ethers and cryptands and cyclic ester amides.
Höcker¸, H.
doaj  

Electrospun Wood‐Derived Biopolymers as Electrodes in Electrochemical Energy Storage Technologies

open access: yesAdvanced Functional Materials, EarlyView.
Electrospinning transforms wood‐derived cellulose and lignin into architecturally defined, binder‐free carbon electrodes with tuneable porosity and functionality. This review shows how fibre design enables decoupled charge and mass transport, enhancing performance across battery systems, while identifying key challenges in spinnability, scalability ...
Michael W. Thielke   +3 more
wiley   +1 more source

Semiconducting Polymers Post‐Functionalized With Ureido‐Pyrimidinone for Robust Stretchable Transistors

open access: yesAdvanced Functional Materials, EarlyView.
The design of intrinsically robust stretchable semiconducting polymers was achieved through OTBS‐mediated post‐functionalization of PDPP2T side chains with UPy units, generating dual hydrogen‐bonding motifs comprising weaker urethane linkages and strong quadruple UPy interactions along the long alkyl side chain, which is crucial for achieving desirable
Dinda Bazliah   +7 more
wiley   +1 more source

Recent Advances in Transition-Metal Catalyzed Asymmetric Ring-Opening Reactions of Cyclic Diaryliodoniums

open access: yesSynOpen
This Graphical Review provides an overview of transition-metal catalyzed enantioselective ring-opening reactions of cyclic diaryliodonium salts. These reactions offer unique approaches to axially chiral biaryls, atropisomeric biaryl ethers, and molecules
Shan Yang, Zhenhua Gu
doaj   +1 more source

Ambient gold-catalyzed O-vinylation of cyclic 1,3-diketone: A vinyl ether synthesis

open access: yesBeilstein Journal of Organic Chemistry, 2013
Gold-catalyzed O-vinylation of cyclic 1,3-diketones has been achieved for the first time, which provides direct access to various vinyl ethers.
Yumeng Xi, Boliang Dong, Xiaodong Shi
doaj   +1 more source

Conformational Switching of Proteins on Material Surfaces Enabled by Peptide‐Oriented Adsorption

open access: yesAdvanced Functional Materials, EarlyView.
Responsive biointerfaces could be achieved using conformationally responsive proteins; however, their interconversion can be lost upon surface adsorption. Herein, we demonstrate that the incorporation a Au binding peptide into calmodulin allows for binding control on Au wherein the protein retains conformational switching. This capability was confirmed
Sakthirupini Ramamurthy   +7 more
wiley   +1 more source

Stereoselective alkene syntheses from cyclic enol ethers

open access: yes, 1988
Two novel methods for the stereoselective synthesis of trisubstituted olefins from cyclic enol ethers were investigated. The first utilised the nickel (O)-catalysed coupling reactions of α-alkyl substituted cyclic enol ethers with Grignard reagents.
Wadman, Sjoerd Nicolaas
core   +1 more source

Alternating Cascade Metathesis Polymerization of Enynes and Cyclic Enol Ethers with Active Ruthenium Fischer Carbenes

open access: yesJournal of the American Chemical Society, 2020
Ruthenium alkoxymethylidene complexes have rarely been demonstrated as active species in metathesis reactions and are frequently regarded as inert. Herein, we highlight the ability of these Fischer-type carbenes to participate in cascade alternating ring-
Xuelin Sui   +4 more
semanticscholar   +1 more source

Spatially Regulated Lithium Plating via Li2O‐Rich Interphase Enables Durable Fast‐Charging Hybrid Lithium Batteries

open access: yesAdvanced Functional Materials, EarlyView.
A Li2O‐rich solid electrolyte interphase (SEI) is engineered on graphite through a propylene carbonate‐based electrolyte to spatially regulate Li plating. The homogeneous interphase lowers Li nucleation barriers, promotes conformal Li deposition around graphite particles, and suppresses dendritic accumulation, enabling durable hybrid Li‐ion/Li‐metal ...
Robert Kuphal   +8 more
wiley   +1 more source

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