Results 61 to 70 of about 1,625,514 (331)

Thermochemistry of Solution, Solvation and Hydrogen Bonding of Chloroform in Linear and Cyclic Ethers

open access: yes, 2021
In this work the thermochemistry of solution, solvation and hydrogen bond formation of chloroform in linear and cyclic ethers was studied. The infinite dilution solution enthalpies of chloroform in diethyl ether, diglyme, 1,4-dioxane, tetrahydrofuran, 12-
Semenov K.N.   +6 more
core  

Tribo-electric Charging and Adhesion of Cellulose Ethers and their Mixtures with Flurbiprofen [PDF]

open access: yes, 2014
The pervasiveness of tribo-electric charge during pharmaceutical processing can lead to the exacerbation of a range of problems including segregation, content heterogeneity and particle surface adhesion.
Šupuk, Enes   +2 more
core   +1 more source

Dual‐Layer Conducting and Redox Polymer Bioanodes for Synergistic Enhancement of Microbial Extracellular Electron Transfer

open access: yesAdvanced Functional Materials, EarlyView.
A hybrid PEDOT/Fc‐LPEI conducting/redox polymer bioanode synergistically improves microbial extracellular electron transfer (EET) in Shewanella oneidensis MR‐1. The dual‐layer interface delivers 18‐fold higher current output and 27‐fold greater charge collected than bare carbon felt, highlighting an effective strategy for high‐performance ...
Shenghan Gu   +4 more
wiley   +1 more source

Rapid transformation of sulfinate salts into sulfonates promoted by a hypervalent iodine(III) reagent

open access: yesBeilstein Journal of Organic Chemistry, 2018
An alternative method for forming sulfonates through hypervalent iodine(III) reagent-mediated oxidation of sodium sulfinates has been developed. This transformation involves trapping reactive sulfonium species using alcohols. With additional optimization
Elsa Deruer   +3 more
doaj   +1 more source

Discovery and development of metallocene-based polyolefins with special properties [PDF]

open access: yesPolyolefins Journal, 2015
Beside Ziegler-Natta and Phillips catalysts the development of methylaluminoxane (MAO) as cocatalyst in combination with metallocenes or other transition metal complexes for the polymerization of olefins has widely increased the possibilities in ...
Walter Kaminsky, Mercia Fernandes
doaj   +1 more source

Mechanical Programming of PEGDA‐β‐CD Polyrotaxane‐Based Hydrogels via Host–Guest Molecular Recognition

open access: yesAdvanced Functional Materials, EarlyView.
A mechanically programmable hydrogel for tissue engineering is developed by modulating the molecular threading density of poly(ethylene glycol) diacrylate‐β‐cyclodextrin (PEGDA‐β‐CD) polyrotaxane and combining it with β‐CD‐modified gelatin. The polyrotaxane‐guided transition from disordered pores to laminar microstructures enables precise tuning ...
Shiyi Chen   +10 more
wiley   +1 more source

The Cationic Ring-Opening Polymerization of Tetrahydrofuran with 12-Tungstophosphoric Acid

open access: yesMolecules, 2010
The cationic ring-opening polymerization reaction of tetrahydrofuran at 20 ºC was catalyzed by H3PW12O40·13H2O as solid acid catalyst. The effect of the proportions of acetic anhydride and catalyst, reaction time and support on the polymerization ...
Hassan Al-Shahri   +2 more
doaj   +1 more source

Difluoromethanesulfonyl hypervalent iodonium ylides for electrophilic difluoromethylthiolation reactions under copper catalysis [PDF]

open access: yesRoyal Society Open Science, 2016
Difluoromethanesulfonyl hypervalent iodonium ylides 2 were developed as electrophilic difluoromethylthiolation reagents for a wide range of nucleophiles.
Sadayuki Arimori   +4 more
doaj   +1 more source

Freeze‐Thaw Engineered Dual Conductivity Polymeric Binder Stabilizes Large‐Volume‐Change Lithium–Ion Battery Anodes

open access: yesAdvanced Functional Materials, EarlyView.
This work developed an all‐aqueous freeze‐thaw strategy to create a dual‐conductive PVA/P3KBT binder for high volume‐change lithium–ion battery anodes. The resulting binder system strengthens the electrode structure, supports ion and electron transport, and accommodates repeated volume changes, reducing cracking and improving long‐term cycling ...
Haoze Ren   +17 more
wiley   +1 more source

Oxidative cyclization of alkenols with Oxone using a miniflow reactor

open access: yesBeilstein Journal of Organic Chemistry, 2009
A miniflow system for oxidative cyclization of alkenols with Oxone was developed. Thus, the oxidative cyclization of (Z)- and (E)-alkenols in i-PrOH with an aqueous solution of Oxone proceeded smoothly and safely in a PTFE tube without any exogenous ...
Yoichi M. A. Yamada   +2 more
doaj   +1 more source

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