Regioselective Three-Component Reaction of Pyridine N-Oxides, Acyl Chlorides, and Cyclic Ethers [PDF]
A novel three-component reaction of pyridine N-oxides, acyl chlorides, and cyclic ethers is described. Treatment of an electron-deficient pyridine N-oxide with an acyl chloride in the presence of a cyclic ether at 25-50 °C leads to a substituted pyridine as a single regioisomer in up to 58% isolated yield.
Jones, D. Heulyn +4 more
openaire +6 more sources
New Conjugated Benzothiazole-N-oxides: Synthesis and Biological Activity [PDF]
Eleven new 2-styrylbenzothiazole-N-oxides have been prepared by aldol – type condensation reactions between 2-methylbenzothiazole–N-oxide and para-substituted benzaldehydes.
Pavlína Foltínová +3 more
doaj +2 more sources
Iodine-Catalyzed Radical C–H Amination of Nonaromatic Imidazole Oxides: Access to Cyclic α‑Aminonitrones [PDF]
A straightforward cross-dehydrogenative coupling approach to incorporate alicyclic amino residues into the structure of model cyclic aldonitrones, 2H-imidazole oxides, is reported. The elaborated C(sp2)–H functionalization is achieved by employing cyclic
Oleg N. Chupakhin (1489117) +7 more
core +1 more source
A rhodium(II)-catalyzed reaction of cyclic nitronates (5,6-dihydro-4H-1,2-oxazine N-oxides) with vinyl diazoacetates proceeds as a [3+3]-annulation producing bicyclic unsaturated nitroso acetals (4a,5,6,7-tetrahydro-2H-[1,2]oxazino[2,3-b][1,2]oxazines ...
Yulia A. Antonova +3 more
doaj +1 more source
Sulfonamide−Pyridine-N-oxide Cocrystals [PDF]
Hydrogen-bond motifs for the supramolecular synthesis of sulfonamide−pyridine-N-oxide complexes were derived from the analysis of cocrystal structures of aryl sulfonamides and pyridine-N-oxides.
N. Rajesh Goud (1395406) +2 more
core +13 more sources
Electrochemical behavior of indolone-N-oxides: Relationship to structure and antiplasmodial activity [PDF]
Indolone-N-oxides exert high parasiticidal activity at the nanomolar level in vitro against Plasmodiumfalciparum, the parasite responsible for malaria.
Perio, Pierre +6 more
core +1 more source
Rhodium-Based Catalysts: An Impact of the Support Nature on the Catalytic Cyclohexane Ring Opening
Because of the growing demand for high-quality fuels, the light cycle oil fraction improvement including cetane number improvement is important. The main way to reach this improvement is the ring opening of cyclic hydrocarbons, and a highly effective ...
Kristina E. Kartavova +10 more
doaj +1 more source
Nanolayered manganese oxides: insights from inorganic electrochemistry [PDF]
Nanolayered Mn oxides are among the important Mn-based catalysts for water oxidation. Mn(II), (III) and (IV) ions are present in the structure, and, thus, the electrochemistry of the solid is very complicated.
Mohammad Mahdi Najafpour +15 more
core +1 more source
Study Reactions of acetylenic amine N-Oxidewith reactive Halides [PDF]
new acetylenic amine derived from cyclic secondary amines such as piperidine were synthesized , these amine were oxidized with m-chloroper benzoic acid to the corresponding N-Oxides.
Omar H. Shehab
doaj +1 more source
Cyclic cohomology after the excision theorem of Cuntz and Quillen [PDF]
The excision theorem of Cuntz and Quillen established the existence of a six term exact sequence in the bivariant periodic cyclic cohomology HP*(–,–) associated with an arbitrary algebra extension 0 ? S ? P ? Q ? 0.
Jacek Brodzki, Brodzki, Jacek
core +1 more source

