Results 1 to 10 of about 26,473 (143)

Poly(ionic liquid)s for Photo‐Driven CO2 Cycloaddition: Electron Donor–Acceptor Segments Matter

open access: yesAdvanced Science, 2023
CO2 cycloaddition with epoxides is a key catalytic procedure for CO2 utilization. Several metal‐based catalysts with cocatalysts are developed for photo‐driven CO2 cycloaddition, while facing difficulties in product purification and continuous reaction ...
Xu Fang   +12 more
doaj   +1 more source

Pericyclases for cycloaddition

open access: yesNational Science Review, 2022
Focusing on the cycloadditions, which have been widely utilized in total synthesis, this perspective reviews the flourish research of pericyclase for cycloaddition and discusses existing challenges.
Zhang, Bo, Ge, Hui Ming
openaire   +2 more sources

Preparation of an advanced intermediate for the synthesis of leustroducsins and phoslactomycins by heterocycloaddition

open access: yesBeilstein Journal of Organic Chemistry, 2022
A convergent strategy for the synthesis of leustroducsins and phoslactomycins has been designed, relying on the synthesis and the coupling of three main fragments.
Anaïs Rousseau   +2 more
doaj   +1 more source

Synthesis and antitumoral activity of novel biaryl hydroxy-triazole and fluorene-triazole hybrids [PDF]

open access: yesExploration of Drug Science
Aim: The development of selective and potent antitumor agents remains a significant challenge. This study aimed to synthesize and evaluate biaryl hydroxy-1,2,3-triazoles and 9H-fluorene-1,2,3-triazole hybrids, inspired by previously identified bioactive ...
David Chafi Zeitune   +6 more
doaj   +1 more source

Organocatalysis with carbon nitrides

open access: yesScience and Technology of Advanced Materials, 2023
Carbon nitrides, a distinguished class of metal-free catalytic materials, have presented a good potential for chemical transformations and are expected to become prominent materials for organocatalysis.
Sujanya Maria Ruban   +8 more
doaj   +1 more source

An overview of the cycloaddition chemistry of fulvenes and emerging applications

open access: yesBeilstein Journal of Organic Chemistry, 2019
The unusual electronic properties and unique reactivity of fulvenes have interested researchers for over a century. The propensity to form dipolar structures at relatively low temperatures and to participate as various components in cycloaddition ...
Ellen Swan   +2 more
doaj   +1 more source

Donor-Acceptor Substituted Benzo-, Naphtho- and Phenanthro-Fused Norbornadienes

open access: yesMolecules, 2020
The photochromic norbornadiene/quadricyclane (NBD/QC) couple has found interest as a molecular solar thermal energy (MOST) system for storage of solar energy.
Mads Mansø   +4 more
doaj   +1 more source

Synthesis of Functionalized Diethyl(pyrrolidin-2-yl)phosphonate and Diethyl(5-oxopyrrolidin-2-yl)phosphonate

open access: yesMolecules, 2021
Short and efficient syntheses of functionalized (pyrrolidin-2-yl)phosphonate and (5-oxopyrrolidin-2-yl)phosphonate have been developed. The synthetic strategy involved the diastereospecific 1,3-dipolar cycloaddition of N-benzyl-C-(diethoxyphosphoryl ...
Iwona E. Głowacka   +3 more
doaj   +1 more source

Key Mechanistic Features in Palladium-Catalyzed Methylcyclopropanation of Norbornenes With Vinyl Bromides: Insights From DFT Calculations

open access: yesFrontiers in Chemistry, 2019
DFT calculations were performed to elucidate mechanistic details of an unusual palladium-catalyzed methylcyclopropanation from [2 + 1] cycloadditions of (Z)-2-bromovinylbenzene and endo-N-(p-tolyl)-norbornenesuccinimide.
Fang Ying   +6 more
doaj   +1 more source

Synthesis of 5,6-Dihydropyrazolo[5,1-a]isoquinolines through Tandem Reaction of C,N-Cyclic Azomethine Imines with α,β-Unsaturated Ketones

open access: yesMolecules, 2023
An innovative and efficient approach has been developed for the synthesis of 5,6-dihydropyrazolo[5,1-a]isoquinolines. This one-pot tandem reaction involves the reaction of C,N-cyclic azomethine imines with α,β-unsaturated ketones, using K2CO3 as the base
Young Jae Yun, Sung-Gon Kim
doaj   +1 more source

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