Results 101 to 110 of about 153,572 (317)

Solution‐Processable, Ladder‐Branched Polyimides of Intrinsic Microporosity by [4+4] Cycloaddition for Membrane Gas Separation

open access: yesAdvanced Materials, EarlyView.
An effective post‐synthetic modification strategy utilizing [4+4] cycloaddition is demonstrated to fabricate ladder‐branched polyimides of intrinsic microporosity (PIM‐PIs) with significantly enhanced performance characteristics for membrane‐based gas separation.
Tae Hoon Lee   +3 more
wiley   +1 more source

Triazolinediones as highly enabling synthetic tools [PDF]

open access: yes, 2016
Triazolinediones (TADs) are unique reagents in organic synthesis that have also found wide applications in different research disciplines, in spite of their somewhat "exotic" reputation.
Billiet, Stijn   +5 more
core   +1 more source

Azaporphyrinoid‐Based Photo‐ and Electroactive Architectures for Advanced Functional Materials

open access: yesAdvanced Materials, EarlyView.
A long‐standing collaboration between the Torres and Guldi groups has yielded diverse azaporphyrinoid‐based donor‐acceptor nanohybrids with promising applications in solar energy conversion. This conspectus highlights key molecular platforms and structure‐function relationships that govern light and charge management, supporting the rational design of ...
Jorge Labella   +3 more
wiley   +1 more source

Application of chiral 2-isoxazoline for the synthesis of syn-1,3-diol analogs

open access: yesBeilstein Journal of Organic Chemistry, 2019
The asymmetric cycloaddition of TIPS nitronate catalyzed by “Cu(II)-bisoxazoline” gave the 2-isoxazoline product in 95% yield, which was converted into tert-butyl (3S,5R)-6-hydroxy-3,5-O-isopropylidene-3,5-dihydroxyhexanoate in 14 steps through a β ...
Juanjuan Feng   +3 more
doaj   +1 more source

Recent Applications of the Simple Hydrocarbon Cyclooctatetrene as a Starting Material for Complex Molecule Synthesis [PDF]

open access: yes, 2012
Cyclooctatetraene [COT], a simple non-aromatic cyclic polyene, is capable of undergoing a variety of oxidation and cycloaddition reactions to afford polycyclic structures.
Donaldson, William, Glaeske, Kevin W
core   +2 more sources

Site Selective Antibody-Oligonucleotide Conjugation via Microbial Transglutaminase. [PDF]

open access: yes, 2019
Nucleic Acid Therapeutics (NATs), including siRNAs and AntiSense Oligonucleotides (ASOs), have great potential to drug the undruggable genome. Targeting siRNAs and ASOs to specific cell types of interest has driven dramatic improvement in efficacy and ...
Cui, Xianshu   +6 more
core   +1 more source

Enhancing Diamond Biosensors and Photonic Devices: The Interplay of Surface Roughness, Functionalization, and Fluorescence

open access: yesAdvanced Materials Interfaces, EarlyView.
Diamond surfaces with tunable nanoscale roughness (4 vs 14 nm) are orthogonally functionalized via SPAAC, TEMA, TYC, and epoxy ring‑opening click reactions to fabricate protein microarrays. Smoother films markedly enhance fluorescence, and epoxy‑amine/Michael addition routes yield the highest biotin–streptavidin capture.
Seyed Mohammad Mahdi Dadfar   +2 more
wiley   +1 more source

The Search for an Epoxide Precursor in Trimethylenemethane (TMM) Cycloaddition Reactions [PDF]

open access: yes, 2012
Trimethylenemethane (TMM) cycloaddition is a Pd(0)-catalyzed process in which new carbon rings are formed, which can be potentially useful in synthetic organic processes.
Miko, Christopher
core   +2 more sources

An optimised scalable synthesis of H2O@C60and a new synthesis of H2@C60

open access: yes, 2014
New high-yielding synthetic routes to the small-molecule endofullerenes H2O@C60, D2O@C60 and H2@C60 are described. The use of high temperatures and pressures for the endohedral molecule incorporation are avoided.
Krachmalnicoff, A.   +2 more
core   +1 more source

Chemical investigation of light induced DNA bipyrimidine damage and repair [PDF]

open access: yes, 2011
In all organisms, genetic information is stored in DNA and RNA. Both of these macromolecules are damaged by many exogenous and endogenous events, with UV irradiation being one of the major sources of damage.
Carell, Thomas   +2 more
core   +1 more source

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