closo‐Carboranyl Analogs of β‐Arylethylamines: Direct Synthesis from Alkenes via EnT‐Catalysis
closo‐Carboranes are icosahedral carbon‐boron clusters with unique properties and broad applicability. They particularly stand out in the context of drug development as privileged structural motifs for boron neutron capture therapy (BNCT) and as highly hydrophobic bioisosteres for the rotational volume of phenyl rings.
Fritz Paulus+8 more
wiley +1 more source
Aza-[4 + 2]-cycloaddition of benzocyclobutenones into isoquinolinone derivatives enabled by photoinduced regio-specific C-C bond cleavage. [PDF]
Yang L+6 more
europepmc +1 more source
Polymers and light: a love-hate relationship. [PDF]
Weerasinghe MASN+2 more
europepmc +1 more source
Isothiourea-catalysed enantioselective synthesis of phosphonate-functionalised β-lactones. [PDF]
Platt FM+6 more
europepmc +1 more source
Practical Synthesis of Chiral Ferrocenenylphosphino-Gold(I) Catalysts and NEST Analysis of the Enantioinduction. [PDF]
Mora P+4 more
europepmc +1 more source
Reactivity of Pnictaalumenes towards 1,3‐Dipole Molecules
Alkynes undergo 1,3‐dipolar cyclisation reactions with organic azides giving 1,2,3‐triazoles. Pnictaalumenes RPn=AlRˈ are the isoelectronic congeners of alkynes, hence a similar reactivity towards 1,3‐dipole molecules is expected. Herein, we report the reactions of DippTerPn=AlCp* (DippTer = 2,6‑(2,6‐iPr2C6H3)‐C6H3, Cp* = [Me5C5]−, Pn = P, As) towards ...
Tim Wellnitz+7 more
wiley +1 more source
Interplay between Energy and Entropy Mediates Ambimodal Selectivity of Cycloadditions. [PDF]
Shin W, Hou Y, Wang X, Yang ZJ.
europepmc +1 more source
Visible-Light-Mediated Rose Bengal- or [Ru(bpy)<sub>3</sub>]<sup>2+</sup>-Catalyzed Radical [4 + 2] Cycloaddition: An Efficient Route to Tetrahydrocarbazoles. [PDF]
Bishir C, Hubbard A, Mei L.
europepmc +1 more source
Author Correction: Evaluation of antibiofilm properties of dehydroacetic acid (DHA) grafted spiro-oxindolopyrrolidines synthesized via multicomponent 1,3-dipolar cycloaddition reaction. [PDF]
Suresh Babu AR+7 more
europepmc +1 more source