Stereoselectivity in furfural cation (4+3) cycloadditions [PDF]
, 2016 Catak, Saron +4 more
core +1 more source
Ring Formation in Sesquiterpene Synthesis: Biomimetic vs. Non‐Biomimetic Strategies
European Journal of Organic Chemistry, EarlyView.A short review of cyclase enzyme‐mediated ring formation in sesquiterpene biosynthesis is presented as a prelude to six case studies examining the merits and demerits of biomimetic vs. non‐biomimetic strategies for carbocyclisation in the total synthesis of this iconic natural product class.
Bohan Lin, Chen Dai, Alan C. Spivey
wiley +1 more source
T‐Shaped 8‐Aryl(ethynyl)‐Substituted Psoralens With Tunable Charge‐Transfer Absorption
European Journal of Organic Chemistry, EarlyView.Starting from 8‐methoxypsoralen, new 8‐arylated and 8‐alkynylated psoralen derivatives are accessible by cross‐coupling. These T‐shaped π‐expanded chromophores are luminescent and photophysics reveal a highly polar excited state with tunable charge‐transfer character.
Lena T. Leusch, Thomas J. J. Müller
wiley +1 more source
Chiral sodium complex-catalyzed asymmetric cascade cycloaddition/hydration/1,2-rearrangement. [PDF]
Sci AdvZhang M +8 more
europepmc +1 more source
Helvetica Chimica Acta, EarlyView.Leaving‐group–free electron donor–acceptor (EDA) complexes have emerged as a practical platform for photocatalyst‐free radical generation under visible light. This review highlights recent advances in coupling and cyclization reactions driven by such EDA complexes, emphasizing their atom‐economical and sustainable feature.
Wenheng Liu, Line Næsborg
wiley +1 more source
Influence of intramolecular interactions and transition state energetics on the strain-promoted azide-alkyne cycloaddition of 2-aminobenzenesulfonamide-containing cyclononynes. [PDF]
RSC AdvNakahara K, Kaneda K.
europepmc +1 more source
Sulfur Ylides in Skeletal‐Editing—Ring Expansion Reactions
Helvetica Chimica Acta, EarlyView.Sulfur ylides (S‐ylides) are emergent diazo surrogates that enable skeletal editing and ring expansion with safer handling and broad functional group tolerance. This perspective covers pioneer works and highlights recent advances in the field, while outlining key challenges and future directions that may redefine the role of S‐ylides in modern ...
Arsala Kamal +3 more
wiley +1 more source
Enantioselective Preparation of (<i>N</i>,<i>O</i>)-, (<i>N</i>,<i>N</i>)- and (<i>N</i>,<i>S</i>)-Spiroketal Moieties. [PDF]
MoleculesSow M, Fauran E, Commeiras L.
europepmc +1 more source
1,3-Dipolar Cycloaddition of Nitrile Imines and Nitrile Oxides to Exocyclic C=N Bonds-An Approach to <i>Spiro</i>-N-Heterocycles. [PDF]
Int J Mol SciPetrova JV +2 more
europepmc +1 more source