Crystal structure of the 4 + 2 cycloadduct of photooxidized anthracene and C60 fullerene
Acta Crystallographica Section E, 2014 The structure of the title compound, 5,6-[(1R,10S)-2,9-dioxatricyclo[8.6.03,8.011,16]hexadecane-1,10-diyl]-(C60–Ih)[5,6]fullerene methanedithione 0.1-solvate, C74H10O2·0.1CS2, has tetragonal (P42/n) symmetry at 100 K. It has a unique eight-membered ring,
Gábor Bortel +3 more
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A Novel Ultra-High Swelling Organogel: An Epoxy Resin Derived Gelator for Alcohols and Polar Organic Liquids [PDF]
علوم و تکنولوژی پلیمر, 2020 Hypothesis: Organogels are hydrophobic macromolecular networks with ability to absorb and retain organic solvents. They have been used in various applications, e.g., production of disinfectant hygienic gels used in medicine and public health. The present
Zeinab Karami +1 more
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Promotion mechanism of hydroxyl groups in catalyzing CO2 cycloaddition
Journal of CO2 UtilizationIn this study, a series of hydroxy-functionalized quaternary ammonium salt catalysts, i.e., NEt3(HE)Br, NEt2(HE)2Br, NEt1(HE)3Br, and N(HE)4Br, were successfully prepared by quantitatively grafting hydrogen-bond donors (HBDs) as electrophilic sites on ...
Yiming Wang +5 more
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Catalytic [4+2]- and [4+4]-cycloaddition using furan-fused cyclobutanone as a privileged C4 synthon
Nature CommunicationsCycloaddition reactions play a pivotal role in synthetic chemistry for the direct assembly of cyclic architectures. However, hurdles remain for extending the C4 synthon to construct diverse heterocycles via programmable [4+n]-cycloaddition.
Kemiao Hong +7 more
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Non-K Region Disubstituted Pyrenes (1,3-, 1,6- and 1,8-) by (Hetero)Aryl Groups—Review
Molecules, 2019 Disubstituted pyrenes at the non-K region by the same or different (hetero)aryl groups have proven to be an increasingly interesting area of research for scientists over the last decade due to their optical and photophysical properties.
Dawid Zych
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Synthesis and Characterization of 1-Hydroxy-5-Methyltetrazole and Its Energetic Salts
MoleculesThe objective of this work was the synthesis and characterization of novel, insensitive high explosives. 1-hydroxy-5-methyltetrazole served as both a scaffold and anion for preparing various nitrogen-rich energetic salts. The compounds were characterized
Lukas J. Eberhardt +3 more
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Ferrocenyl Substituted Stannanethione and Stannaneselone
MoleculesHeavier element analogues of a ketone, a C=O double-bond compound, have been fascinating compounds from the viewpoint of main-group element chemistry because of their unique structural features and reactivity as compared with those of a ketone, which ...
Keisuke Iijima +2 more
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The Theoretical and Experimental Study of DiazomethaneStyrene [3+2]-Cycloadditions
Журнал органічної та фармацевтичної хіміїPyrazolines are an important class of heterocyclic compounds known for their biological activities, making them attractive objects for medicinal chemistry.
Serhii I. Shuvakin, Serhii P. Ivonin
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Molecules, 2021 Diabetes mellitus is a major health problem globally. The management of carbohydrate digestion provides an alternative treatment. Flavonoids constitute the largest group of polyphenolic compounds, produced by plants widely consumed as food and/or used ...
Faisal K. Algethami +6 more
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Thermally Induced Intramolecular Diels–Alder Reaction of Furan-Tethered Methylenecyclopropanes
MoleculesThe substantial ring strain and activated double bonds render methylenecyclopropanes (MCPs) potential substrates for Diels–Alder (DA) reactions. In this work, we present a thermally induced intramolecular Diels–Alder (IMDA) reaction utilizing furan ...
Qi-Yun Huang +3 more
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