Results 291 to 300 of about 157,130 (323)
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1994
Die thermische [2+2]Cycloaddition von Alkenen 1 ist nach den Woodward-Hoffmann-Regeln 1) suprafacial symmetrieverboten und kann nur in speziellen Fallen erfolgreich durchgefuhrt werden. Hingegen ist das photochemische Pendant erlaubt und wird als praparativ wertvolle Methode zur Bildung von Vierringsystemen 2 vielfaltig genutzt.2–4)
Thomas Laue, Andreas Plagens
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Die thermische [2+2]Cycloaddition von Alkenen 1 ist nach den Woodward-Hoffmann-Regeln 1) suprafacial symmetrieverboten und kann nur in speziellen Fallen erfolgreich durchgefuhrt werden. Hingegen ist das photochemische Pendant erlaubt und wird als praparativ wertvolle Methode zur Bildung von Vierringsystemen 2 vielfaltig genutzt.2–4)
Thomas Laue, Andreas Plagens
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2010
This chapter deals with enantioselective organocatalytic cycloaddition reactions. Several cinchona alkaloids have been recently demonstrated as efficient chiral organocatalysts for enantioselective Diels−Alder reactions. Thus, excellent results were obtained for the Diels−Alder reaction of 3-vinylindoles with maleimides catalysed by a ...
S. Araki, T. Hirashita
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This chapter deals with enantioselective organocatalytic cycloaddition reactions. Several cinchona alkaloids have been recently demonstrated as efficient chiral organocatalysts for enantioselective Diels−Alder reactions. Thus, excellent results were obtained for the Diels−Alder reaction of 3-vinylindoles with maleimides catalysed by a ...
S. Araki, T. Hirashita
+4 more sources
Cycloadditions and Cycloreversions I. [2+2]-Cycloaddition
1992It was pointed out in the preceding chapter that correlation diagrams can be read from right to left as easily as from left to right. This is certainly true from the formal viewpoint of orbital symmetry, but does not preclude the need to examine the geometric and energetic consequences of the nuclear motions involved.
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