Assembly drives regioselective azide-alkyne cycloaddition reaction [PDF]
Nature Communications, 2023 Azide-alkyne cycloaddition reaction is a very common organic reaction to synthesize nitrogen-containing heterocycles. Once catalyzed by Cu(I) or Ru(II), it turns out to be a click reaction and thus is widely applied in chemical biology for labeling ...
Qiaochu Jiang +6 more
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The Puzzle of the Regioselectivity and Molecular Mechanism of the (3+2) Cycloaddition Reaction Between E-2-(Trimethylsilyl)-1-Nitroethene and Arylonitrile N-Oxides: Molecular Electron Density Theory (MEDT) Quantumchemical Study [PDF]
MoleculesThe regioselectivity and molecular mechanism of the (3+2) cycloaddition reaction between E-2-(trimethylsilyl)-1-nitroethene and arylonitrile N-oxides were explored on the basis of the ωB97XD/6-311+G(d) (PCM) quantumchemical calculations.
Mikołaj Sadowski +2 more
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Valence-isomer selective cycloaddition reaction of cycloheptatrienes-norcaradienes [PDF]
Nature CommunicationsThe rapid and precise creation of complex molecules while controlling multiple selectivities is the principal objective in synthetic chemistry. Combining data science and organic synthesis to achieve this goal is an emerging trend, but few examples of ...
Shingo Harada +4 more
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MOF-Derived Cu@N-C Catalyst for 1,3-Dipolar Cycloaddition Reaction [PDF]
Nanomaterials, 2022 Cu(im)2-derived Cu@N-C composites were used for the first time as efficient heterogeneous catalysts for one-pot 1,3-dipolar cycloaddition of terminal alkynes, aryl halides, and sodium azide to preparation of 1,4-disubstituted 1,2,3-triazoles with broad ...
Zhuangzhuang Wang +3 more
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The Choice of Rhodium Catalysts in [2+2+2] Cycloaddition Reaction: A Personal Account [PDF]
Molecules, 2022 [2+2+2] Cycloaddition reaction is a captivating process that assembles six-membered rings from three unsaturations with complete atom economy. Of the multiple transition metals that can be used to catalyze this reaction, rhodium offers many advantages ...
Anna Pla-Quintana, Anna Roglans
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HUISGEN AND HIS ADVENTURES IN A PLAYGROUND OF MECHANISMS AND NOVEL REACTIONS [PDF]
Química Nova, 2021 The death of professor Rolf Huisgen (1920-2020) was announced on March 26th 2020, in the midst of the COVID-19 pandemic. Professor Huisgen was professor emeritus at the University of Munich in Germany, and studied in detail the mechanism of the 1,3 ...
Daniel T. G. Gonzaga +5 more
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Catalysis Communications, 2023 The demand for environmental friendly methodologies had shifted the the approach of scientific community for using easy and green reaction conditions instead of using hazardous and harsh reaction conditions.
Vijay Kumar +3 more
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Computational study of a model system of enzyme-mediated [4+2] cycloaddition reaction. [PDF]
PLoS ONE, 2015 A possible mechanistic pathway related to an enzyme-catalyzed [4+2] cycloaddition reaction was studied by theoretical calculations at density functional (B3LYP, O3LYP, M062X) and semiempirical levels (PM6-DH2, PM6) performed on a model system.
Evgeniy G Gordeev, Valentine P Ananikov
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Poly(ionic liquid)s for Photo‐Driven CO2 Cycloaddition: Electron Donor–Acceptor Segments Matter
Advanced Science, 2023 CO2 cycloaddition with epoxides is a key catalytic procedure for CO2 utilization. Several metal‐based catalysts with cocatalysts are developed for photo‐driven CO2 cycloaddition, while facing difficulties in product purification and continuous reaction ...
Xu Fang +12 more
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SynOpen, 2022 The versatility and effectiveness of MnVI-NPs as a catalyst is examined for the generation of nitrile oxides from aldoximes and subsequent 1,3-dipolar cycloaddition reactions.
Yasmin Saima, Saikat Khamarui
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