Results 41 to 50 of about 73,410 (278)

Orthogonal, metal-free surface modification by strain-promoted azide–alkyne and nitrile oxide–alkene/alkyne cycloadditions [PDF]

, 2012
In this article we present a fast and efficient methodology for biochemical surface patterning under extremely mild conditions. Micropatterned azide/benzaldoxime-surfaces were prepared by microcontact printing of a heterobifunctional cyclooctyne oxime ...
Arlinghaus, Heinrich F, Burley, Glenn A, Ravoo, Bart Jan, Rinnen, Stefan, Schulz, Christian, Singh, Ishwar, Wendeln, Christian   +6 more
core   +1 more source

Enantioselective cycloaddition reactions

ChemInform, 1991
Publisher Summary This chapter reviews the cycloadditions reactions because they are popular, widely used, and also constitutes enormous body of chemistry. The chapter focuses on the landmark achievements as well as state-of-the-art examples of relevant chemistry.
openaire   +2 more sources

Bio‐Orthogonally Crosslinked Supramolecular Polymer Bottlebrush Hydrogels for Long‐Term 3D Cell Culture

Advanced Functional Materials, EarlyView.
Fibrous benzenetrispeptide (BTP) hydrogels, fabricated via strain‐promoted azide‐alkyne cycloaddition (SPAAC) crosslinking, form robust, bioinert networks. These hydrogels can support 3D cell culture, where cell viability and colony growth depend on the fiber content.
Ceren C. Pihlamagi, David Pretzel, Peer Nölte, Kourosh Rezaei, Ulrich S. Schubert, Johannes C. Brendel   +5 more
wiley   +1 more source

Design of Amine-Modified Zr–Mg Mixed Oxide Aerogel Nanoarchitectonics with Dual Lewis Acidic and Basic Sites for CO₂/Propylene Oxide Cycloaddition Reactions

Nanomaterials, 2022
The utilization of CO2 attracts much research attention because of global warming. The CO2/epoxide cycloaddition reaction is one technique of CO2 utilization. However, homogeneous catalysts with both Lewis acidic and basic and toxic solvents, such as DMF,
Yi-Feng Lin, Yu-Rou Lai, Hsiang-Ling Sung, Tsair-Wang Chung, Kun-Yi Andrew Lin   +4 more
doaj   +1 more source

Diels−Alder Topochemistry via Charge-Transfer Crystals:  Novel (Thermal) Single-Crystal-to-Single-Crystal Transformations [PDF]

, 2001
The solid-state [4+2] cycloaddition of anthracene to bis(N-ethylimino)-1,4-dithiin occurs via a unique single-phase topochemical reaction in the intermolecular (1:1) charge-transfer crystal.
Hubig, S. M., Kim, J. H., Kochi, Jay K., Lindeman, Sergey V.   +3 more
core   +1 more source

Chemoenzymatic Synthesis of Triazololactams Structurally Related to Pancratistatin [PDF]

, 2017
Four tricyclic lactams that structurally resemble alkaloids with the pancratistatin skeleton were synthetized from bromobenzene by a chemoenzymatic strategy.
Bastida, Bellomo, Bellomo, Bellomo, Bellomo, Bellomo, Brovetto, Brovetto, Cao, Carless, Carrau, Carrera, Carrera, Chrétien, Desjardins, Ghavre, Gibson, Gibson, Goietsenoven, Griffen, Griffin, He, Hudlicky, Hudlicky, Hudlicky, Hudlicky, Kolb, Kornienko, la Sovera, la Sovera, la Sovera, Labora, Lamoral-Theys, Ma, Ma, Ma, McNulty, Plietker, Rinner, Staudinger, Thevenet, Tian, Vila, Vshyvenko, Vshyvenko, Vshyvenko, Vshyvenko, Wu, Yadav   +48 more
core   +1 more source

Selective cyclodimerization of epichlorohydrin to dioxane derivatives over MOFs [PDF]

, 2020
Glycerol can be converted to valuable products such as epichlorohydrin which is an important intermediate applied in various industries. For example, dioxane derivatives, which are important pharmaceuticals, can be obtained from epichlorohydrin.
Chaemchuen, Somboon, Chen, Cheng, Ganguly, Rakesh, Mousavi, Bibimaryam, Phatanasri, Suphot, Verpoort, Francis, Zeng, Cheng, Zhuiykov, Serge   +7 more
core   +2 more sources

Covalent Organic Frameworks for Photocatalytic CO2 Reduction: Metal Integration Principles, Strategies and Functions

Advanced Functional Materials, EarlyView.
Covalent organic frameworks (COFs) with metals have been recognized as versatile platforms for photocatalytic CO2 reduction (CO2PRR). Herein, an overview of metal integration strategies for COFs is systematically summarized. Regulatory mechanisms and structure–activity relationships between metal integration and COF‐based CO2PRR are emphasized.
Jie He, Minxian Zhang, Jinqiang Zhang, Hongqi Sun, Shaobin Wang, Xiaoguang Duan   +5 more
wiley   +1 more source

Huisgen [3 + 2] Dipolar Cycloadditions of Phthalazinium Ylides to Activated Symmetric and Non-Symmetric Alkynes

Molecules, 2020
We present herein a straightforward and efficient pathway for the synthesis of pyrrolophthalazine cycloadducts via Huisgen [3 + 2] dipolar cycloaddition reactions of phthalazinium ylides to methyl propiolate or dimethyl acetylenedicarboxylate (DMAD).
Vasilichia Antoci, Costel Moldoveanu, Ramona Danac, Violeta Mangalagiu, Gheorghita Zbancioc   +4 more
doaj   +1 more source

An update on the synthesis and reactivity of spiro-fused β-lactams [PDF]

, 2018
Beta-Lactam ring-containing compounds play a pivotal role in drug design and synthetic chemistry. Spirocyclic beta-lactams, representing an important beta-lactam subclass, have recently attracted considerable interest with respect to new synthetic ...
D'hooghe, Matthias, Dao Thi, Hang
core   +1 more source