Results 31 to 40 of about 2,089,289 (186)

Diels–Alder reactions in confined spaces: the influence of catalyst structure and the nature of active sites for the retro-Diels–Alder reaction

open access: yesBeilstein Journal of Organic Chemistry, 2016
Diels–Alder cycloaddition between cyclopentadiene and p-benzoquinone has been studied in the confined space of a pure silica zeolite Beta and the impact on reaction rate due to the concentration effect within the pore and diffusion limitations are ...
Ángel Cantín   +2 more
doaj   +1 more source

Cycloaddition Reaction

open access: yes, 2020
1,3-Dipolar cycloaddition reaction between organic azide and metal carbyne is a useful strategy to construct metallacycles. However, the electronic behavior of organic azide in 1,3-dipolar cycloaddition reactions is less explored.
Zhenyang Lin   +9 more
core   +1 more source

Incorporation of Spin Labels and Paramagnetic Tags for Magnetic Resonance Studies Using Cycloaddition Reactions as a Tool

open access: yesReactions
The cycloaddition reaction is one of the most common reactions in organic chemistry. It has been applied in various fields. Herein, we focus on the application of cycloaddition reactions in investigating biological molecules and materials using magnetic ...
Amarendra Nath Maity   +2 more
doaj   +1 more source

Enantioselective cycloaddition reactions

open access: yesChemInform, 1991
Publisher Summary This chapter reviews the cycloadditions reactions because they are popular, widely used, and also constitutes enormous body of chemistry. The chapter focuses on the landmark achievements as well as state-of-the-art examples of relevant chemistry.
openaire   +2 more sources

1,2,4-Oxadiazoles from cycloreversions of oxadiazabicyclo[3.2.0]heptenes: 1-azetines as thiocyanate equivalents [PDF]

open access: yes, 2013
1,3-Dipolar cycloaddition of nitrile oxides to 4-aryl-2-alkylthio-1-azetines gave a series of oxadiazabicyclo[3.2.0]heptenes as single diastereoisomers. Heating these cycloadducts in toluene resulted in an overall [2+2]-cycloreversion to give 5-alkylthio-
Khan, Musharraf   +5 more
core   +1 more source

Unveiling the Chemistry of Higher-Order Cycloaddition Reactions within the Molecular Electron Density Theory

open access: yesChemistry, 2022
The higher-order cycloaddition (HOCA) reaction of tropone with cyclopentadiene (Cp) has been studied within the Molecular Electron Density Theory.
Luis R. Domingo   +2 more
doaj   +1 more source

Promotion mechanism of hydroxyl groups in catalyzing CO2 cycloaddition

open access: yesJournal of CO2 Utilization
In this study, a series of hydroxy-functionalized quaternary ammonium salt catalysts, i.e., NEt3(HE)Br, NEt2(HE)2Br, NEt1(HE)3Br, and N(HE)4Br, were successfully prepared by quantitatively grafting hydrogen-bond donors (HBDs) as electrophilic sites on ...
Yiming Wang   +5 more
doaj   +1 more source

[2+2+2] Cycloaddition Reactions of Macrocyclic Systems Catalyzed by Transition Metals. A Review

open access: yesMolecules, 2010
Polyalkyne and enediyne azamacrocycles are prepared from arenesulfonamides and various alkyne and alkene derivatives either under basic or neutral conditions.
Anna Roglans, Anna Pla-Quintana
doaj   +1 more source

Microwave-Assisted Regioselective Synthesis and 2D-NMR Studies of New 1,2,3-Triazole Compounds Derived from Acridone

open access: yesJournal of Chemistry, 2021
A simple and mild protocol towards the synthesis of new 1,2,3-triazole compounds derived from acridone has been developed via regiospecific 1,3-dipolar cycloaddition reaction between 10-(prop-2-yn-1-yl)acridone derivatives and aromatic azides using CuI ...
Mohammed Aarjane   +3 more
doaj   +1 more source

The Puzzle of the New Type of Intermediate in the Course of [2 + 2] Cycloaddition with the Participation of Conjugated Nitroalkenes: MEDT Computational Study

open access: yesMolecules
The phenomena of regio- and stereoselectivity and the molecular mechanism of the [2 + 2] cycloaddition reaction between (E)-2-arylnitroethenes and the ynamine molecular system were analyzed using wb97xd/6-311 + G(d) (PCM) quantumchemical calculations. It
Radomir Jasiński, Agnieszka Kącka-Zych
doaj   +1 more source

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