Results 41 to 50 of about 2,217 (174)

Diverse reactivity of maleimides in polymer science and beyond

Polymer International, Volume 74, Issue 4, Page 296-306, April 2025.
This mini‐review provides a thorough overview of maleimide chemistry, highlighting its diverse reactivity in polymer and materials science applications. Abstract Maleimides are remarkably versatile functional groups, capable of participating in homo‐ and copolymerizations, Diels–Alder and (photo)cycloadditions, Michael additions, and other reactions ...
Bruce E Kirkpatrick, Kristi S Anseth, Tayler S Hebner   +2 more
wiley   +1 more source

Curing Behavior and Structure Reactivity‐Property Relationships in Epoxidized Linseed Oil Thermosets Crosslinked With Biobased Eutectic Hardeners

Journal of Polymer Science, EarlyView.
The curing of epoxidized linseed oil with citric, tartaric, and malic acid–based eutectic hardeners is compared to reveal how acid functionality, hydroxyl content, and molecular geometry govern activation energy, reaction rates, and network rigidity.
Mona Jamali Moghadam Siahkali, Nathanael Guigo, Luc Vincent, Nicolas Sbirrazzuoli   +3 more
wiley   +1 more source

A Dual‐Mode Photoconductive Colorimetric Wearable UV‐Dosimeter: Strategies for Tunable UV‐Band Sensitivity

Small, EarlyView.
The harmful ultraviolet component of sunlight necessitates reliable and wavelength‐selective personal UV monitoring technologies. Here, thermally evaporated CuBr thin films enable dual‐mode UV dosimetry through persistent photoconductive and colorimetric responses arising from charge trapping and surface oxide formation.
Suman Kundu, Aneeta Jaggernauth, Robert O'Connor, Rajani K. Vijayaraghavan   +3 more
wiley   +1 more source

Creating a Masterpiece. The Road to (and Beyond) Woodward and Hoffmann's 1969 Angewandte Chemie Treatise

The Chemical Record, EarlyView.
This publication describes how R. B. Woodward and Roald Hoffmann crafted their masterpiece publications. Illustrations include Woodward's first draft of the famous “Violations There are none. Nor can violations be expected of so fundamental a principle of maximum bonding.” Original but discarded text shows the stepwise paths toward the W‐H masterpieces.
Jeffrey I. Seeman
wiley   +1 more source

Therapeutic effect of NEO400, perillyl alcohol conjugated to linoleic acid, in a mouse model of UV‐induced skin damage

Photochemistry and Photobiology, Volume 101, Issue 2, Page 338-349, March/April 2025.
In the present work with mouse models, we demonstrate that a novel compound, NEO400, is able to profoundly protect skin against damage caused by UV radiation (UVR) when it is applied to skin post‐UVR exposure. In comparison, Aloe vera or linoleic acid are unable to achieve a similar level of protection.
Stephen Swenson, Catalina Silva‐Hirschberg, Liliana Freeland, Kristen L. Chen, Nagore I. Marín‐Ramos, Axel H. Schönthal, Thomas C. Chen   +6 more
wiley   +1 more source

Mechanistic Insight Into the Polymorph‐Dependent Photosalient Effect of a White Light or Two‐Photon Activated Photoreactive Molecular Salt

Angewandte Chemie, Volume 138, Issue 30, 20 July 2026.
Photocycloaddition in stilbene‐type salt polymorphs exhibit distinct light‐driven responses: OHT‐TI shows a violent photosalient effect under visible and NIR (two‐photon) irradiation, whereas OHT‐TII reacts statically. Packing and computational analysis reveals that shell‐like structures in OHT‐TI frustrate structural relaxation, accumulating explosive
Emanuela Santagata, Francesco Ambrosio, Amedeo Capobianco, Andrea Peluso, Giorgia Rizzi, Stijn Van Cleuvenbergen, Yovan de Coene, Koen Clays, Paolo Pio Mazzeo, Roberto Centore, Fabio Borbone   +10 more
wiley   +2 more sources

Interventional human ocular safety experiments for 222‐nm far‐ultraviolet‐C lamp irradiation

Photochemistry and Photobiology, Volume 101, Issue 2, Page 517-526, March/April 2025.
To directly assess the ocular safety of 222‐nm far‐ultraviolet‐C (UVC) irradiation in humans, five subjects were exposed to 222‐nm UVC at doses of 22, 50, and 75 mJ/cm2. The findings indicate that far‐UVC irradiation does not cause “clinically significant photokeratitis” or long‐term ocular damage, though it may induce temporary discomfort.
Kazunobu Sugihara, Sachiko Kaidzu, Masahiro Sasaki, Masaki Tanito   +3 more
wiley   +1 more source

Unprecedented visible light-initiated topochemical [2 + 2] cycloaddition in a functionalized bimane dye

Beilstein Journal of Organic Chemistry
Bimanes, a class of molecules based on the 1H,7H-pyrazolo[1,2-a]pyrazole-1,7-dione scaffold, were first introduced by E. M. Kosower in 1978. In this study, we report the topochemical cycloaddition of diethyl 2,6-dichloro-1,7-dioxo-1H,7H-pyrazolo[1,2-a ...
Metodej Dvoracek, Brendan Twamley, Mathias O. Senge, Mikhail A. Filatov   +3 more
doaj   +1 more source

Spectroscopic analysis of bacterial photoreactivation

Photochemistry and Photobiology, Volume 101, Issue 2, Page 494-504, March/April 2025.
This study investigates the effectiveness of fluorescence and Raman spectroscopy in detecting bacterial photoreactivation. Fluorescence spectroscopy shows limitations, because the intense fluorescence of tryptophan and tyrosine masks fluorescence emitted by thymine molecules.
Keyvan Khosh Abady, Negar Karpourazar, Arjun Krishnamoorthi, Runze Li, Peter M. Rentzepis   +4 more
wiley   +1 more source

Enantioselective dearomative ortho-cycloaddition transformation of unactivated arenes by cage-confined visible-light photocatalysis

Nature Communications
Photoinduced dearomatization of arenes is a powerful strategy in organic synthesis to disrupt the stable aromaticity; however, the asymmetric dearomatization photocatalysis of unactivated arenes remains highly challenging and rare.
Jie Yang, Zhongshu Li, Xiantao Wu, Jie Chen, Sisi Huang, Yu-Lin Lu, Zhiwei Jiao, Cheng-Yong Su   +7 more
doaj   +1 more source