Results 21 to 30 of about 2,217 (174)
Molecules, 2022 The ditopic halogen-bond (X-bond) donors 1,2-, 1,3-, and 1,4-diiodotetrafluorobenzene (1,2-, 1,3-, and 1,4-di-I-tFb, respectively) form binary cocrystals with the unsymmetrical ditopic X-bond acceptor trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene (2,4-bpe ...
Jay Quentin +2 more
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Angewandte Chemie, EarlyView.A regio‐ and diastereoselective method for strain‐release pentafluorosulfanylation of carbonyl‐containing 1,3‐disubstituted [1.1.0]bicyclobutanes (BCBs) was developed that led to several fortuitous discoveries. For instance, the resultant SF5‐cyclobutanes (SF5‐CBs) exhibit close SF5⋯C═X contacts (X = C, N, O) and provide synthetic access to a new class
Alexander M. Stephens +9 more
wiley +2 more sources
Borylcyclopropanes: Synthetic Strategies and Applications
Angewandte Chemie, EarlyView.Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley +2 more sources
Ring Tension, Hydrocarbon Acidity, and New «Super-Bases»
CHIMIA, 1986 Addition of disodium pinacolate or, particularly, potassium tert-butoxide considerably increases the transmetalating power of pentylsodium. A hexane slurry of such «NACNAOR» or «NACKOR» reagent mixtures readily and selectively converts 3,3-dimenthyl-1 ...
Manfred Schlosser +5 more
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r-1,t-3-Bis[4-(dimethylamino)phenyl]-c-2,t-4-bis(pyridin-4-yl)cyclobutane
Acta Crystallographica Section E, 2014 The title compound, C30H32N4, was synthesized by the photodimerization of trans-4-{2-[4-(dimethylamino)phenyl]ethenyl}pyridine in benzene upon irradiation with UV light.
Shuguang Zhang, Junpeng Zhuang
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Anethole Isomerization and Dimerization Induced by Acid Sites or UV Irradiation
Molecules, 2010 The formation of cis-anethole and various dimers as a result of the exposure of trans-anethole to microporous solid acids (dealuminated HY zeolites), or UV-Vis irradiation was established by means of high resolution gas chromatography coupled to mass ...
Elena Stashenko +2 more
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Beilstein Journal of Organic Chemistry, 2020 It was demonstrated that styrylquinolizinium derivatives may be applied as photoswitchable DNA ligands. At lower ligand:DNA ratios (≤1.5), these compounds bind to duplex DNA by intercalation, with binding constants ranging from Kb = 4.1 × 104 M to 2.6 ...
Sarah Kölsch +4 more
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Advanced Optical Materials, EarlyView.A series of Eu3+, Tb3+, Tm3+ and La3+ formate‐based (mixed)metal‐organic frameworks were synthesized and investigated for energy transfer and white‐light emission. Efficient Tb3+→Eu3+ transfer enabled tuneable luminescence, while Tm3+ incorporation afforded near‐white emission.
Leonardo E. Cruz‐Estrada +5 more
wiley +1 more source
Natural Products and BioprospectingCyclobutanes are distributed widely in a large class of natural products featuring diverse pharmaceutical activities and intricate structural frameworks.
Song-Yu Hou +3 more
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[2+2]-Photocycloadditions of 1,4-Naphthoquinone Under Batch and Continuous-Flow Conditions
MoleculesA series of [2+2]-photocycloadditions of 1,4-naphthoquinone with various alkenes and diphenylacetylene were investigated under batch and continuous-flow conditions.
Madyan A. Yaseen +3 more
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