Results 91 to 100 of about 12,599 (260)
Chemistry – A European Journal, EarlyView.We report the synthesis and characterization of a sulfated prism[5]arene host (Prism[5]MaxQ). Prism[5]MaxQ displays ultrahigh binding affinity (Ka up to 1012 M−1) toward hydrophobic (di)cations in phosphate‐buffered saline (PBS). The work positions Prism[5]MaxQ as a new member of the family of ultrahigh‐affinity hosts poised for use as a sequestrant in
Emmanuel A. Bazan‐Bergamino +1 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.This research presents a novel 1,4‐π‐functionalized calix[6]arene with enhanced interactions with dialkylammonium axles. We investigate threading behavior in CDCl3, highlighting how exo‐rim π‐functionalization affects binding affinity and stereoselectivity.
Veronica Iuliano +7 more
wiley +1 more source
Carba‐closo‐dodecaborates as Superchaotropic Anions
Chemistry – A European Journal, EarlyView.The singly charged boron cluster anion CB11H12– forms strong inclusion complexes with cyclodextrins, interacts strongly with nonionic polymers, and serves as an effective transmembrane carrier, positioning itself as the smallest superchaotropic anion known to date. .
Andrea Barba‐Bon +8 more
wiley +1 more source
Cyclodextrins’ Internal Cavity Hydration: Insights from Theory and Experiment
InorganicsIn this short review, recent findings from both theory and experiment regarding the process of hydration of α-, β-, and γ-cyclodextrins are summarized and critically assessed.
Silvia Angelova +3 more
doaj +1 more source
Chemistry – A European Journal, EarlyView.Linker length regulates the self‐assembly of rigid sphere–rod amphiphiles. Long linkers enable rigid sphere–rod molecules to undergo solvent‐dependent conformational switching between I‐ and T‐shaped states, driving morphological transitions of the assemblies from striped spherical structures to onion‐like structures.
Jingfan Wei +5 more
wiley +1 more source
N‐Sulfonyl Azalevoglucosan: A Versatile Platform for the Synthesis of Polysubstituted Piperidines
Chemistry – A European Journal, EarlyView.Gain by strain: The synthesis of a levoglucosan analog, in which the pyranose oxygen has been replaced by a nitrogen, allows navigation on the piperidine ring to iteratively install functional groups at C1, C2, C3, C4, and C6 positions using simple experimental protocols with minimal protecting group manipulation.
Dylan Yorga +6 more
wiley +1 more source
Thermophoresis of cyclodextrins and cyclodextrin-drug-complexes
, 2017 The behaviour of biomolecules in a temperature gradient, known as thermodiffusion, changes when a ligand binds. In recent years, this effect has been used to gain detailed information on binding dynamics, although the physicochemical processes are still unclear [1].
Niether, Doreen +6 more
openaire +1 more source
Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis
ChemSusChem, Volume 18, Issue 6, March 15, 2025.The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo +4 more
wiley +1 more source
Cationic Cyclodextrin-Based Carriers for Drug and Nucleic Acid Delivery
PharmaceuticsCyclodextrins can serve as carriers for various payloads, utilizing their capacity to form unique host–guest inclusion complexes within their cavity and their versatile surface functionalization.
Adila Nazli +3 more
doaj +1 more source
EcoEnergy, EarlyView.This review provides a critical comparative analysis of circular and bio‐sourced polymers for energy storage, systematically evaluating natural feedstocks alongside recycling and upcycling strategies for battery components. Key structure–property–performance relationships and inherent trade‐offs between sustainability metrics and electrochemical ...
Priyank Sinha +3 more
wiley +1 more source