Results 111 to 120 of about 14,851 (247)

Concepts of Heterogeneously Catalyzed Liquid‐Phase Oxidation of Cyclohexene with tert‐Butyl Hydroperoxide, Hydrogen Peroxide and Molecular Oxygen

open access: yesChemCatChem, Volume 15, Issue 1, January 9, 2023., 2023
Cyclohexene oxidation: This concept article provides a broad overview of the recent advances in the selective cyclohexene oxidation over heterogeneous transition metal‐based catalysts using the environmentally benign oxidants tert‐butyl hydroperoxide, H2O2 and molecular O2.
Julia Büker   +2 more
wiley   +1 more source

Aza‐Diphosphazenanes: Inorganic Cyclohexane‐like Connectors with Stereochemically Tunable Exit Vectors for Molecular and Macromolecular Chemistry

open access: yesAngewandte Chemie, EarlyView.
New aza‐diphosphinanes have been prepared and a model has been developed to explain their cis/trans isomerization. Two‐fold oxidation leads to new aza‐diphosphazenanes as robust inorganic connectors with selectable stereochemistry. Polycondensation reactions results in the first inorganic cyclo‐linear polyphosphazenes which have high‐molecular weights ...
Michael A. Land   +4 more
wiley   +2 more sources

Controlled Catalysis Delivering High Molecular Weight Polyesters as Recyclable Alternatives to Polystyrenes

open access: yesAngewandte Chemie, EarlyView.
This work exemplifies how to make high molar mass ring opening copolymerization (ROCOP) polyesters as engineering plastics, informing upon their thermal and mechanical properties. Leading polyesters, prepared by epoxide/anhydride ROCOP, show high glass transition temperatures and tensile and flexural strengths, matching or exceeding polystyrene ...
Nora Jannsen   +4 more
wiley   +2 more sources

Computational studies of Brønsted acid-catalyzed transannular cycloadditions of cycloalkenone hydrazones. [PDF]

open access: yesBeilstein J Org Chem, 2023
Pedrón M   +5 more
europepmc   +1 more source

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